Dichlorobis(triphenylphosphin)palladium
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- CAS-Nr.
- 13965-03-2
- Bezeichnung:
- Dichlorobis(triphenylphosphin)palladium
- Englisch Name:
- Bis(triphenylphosphine)palladium(II) chloride
- Synonyma:
- DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM;BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) DICHLORIDE;(PPh3)2PdCl2;DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II);BIS(TRIPHENYLPHOSPHINE)PALLADIUM CHLORIDE;Bis(triphenylphosphine)dichloropalladium;BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II);TRIPHENYLPHOSPHINE PALLADIUM CHLORIDE;Bis(triphenylphosphine)palladium(ll) chloride;PALLADIUM BIS(TRIPHENYLPHOSPHINE) DICHLORIDE
- CBNumber:
- CB9364066
- Summenformel:
- C36H30Cl2P2Pd
- Molgewicht:
- 701.9
- MOL-Datei:
- 13965-03-2.mol
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Dichlorobis(triphenylphosphin)palladium Eigenschaften
- Schmelzpunkt:
- 260°C
- Dampfdruck
- 0Pa at 25℃
- RTECS-Nr.
- RT3578000
- storage temp.
- Store below +30°C.
- L?slichkeit
- Chloroform (Slightly), Dichloromethane (Slightly, Heated), Methanol (Slightly,
- Aggregatzustand
- Powder
- Farbe
- Yellow
- Wasserl?slichkeit
- Insoluble in water. Soluble in benzene, and toluene.
- Sensitive
- Hygroscopic
- BRN
- 4935975
- InChI
- InChI=1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
- InChIKey
- ILBDOZRDKNIJBS-UHFFFAOYSA-N
- SMILES
- P(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[Pd](Cl)Cl
- LogP
- 5.69 at 20℃
- CAS Datenbank
- 13965-03-2(CAS DataBase Reference)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| Bildanzeige (GHS) |
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| Alarmwort |
Warnung |
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H317 |
Kann allergische Hautreaktionen verursachen. |
Sensibilisierung der Haut |
Kategorie 1A |
Warnung |
![GHS hazard pictograms]() src="/GHS07.jpg" width="20" height="20" /> |
P261, P272, P280, P302+P352,P333+P313, P321, P363, P501 |
| H413 |
Kann für Wasserorganismen sch?dlich sein, mit langfristiger Wirkung. |
Langfristig (chronisch) gew?ssergef?hrdend |
Kategorie 4 |
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| Sicherheit |
| P261 |
Einatmen von Staub vermeiden. |
| P272 |
Kontaminierte Arbeitskleidung nicht au?erhalb des Arbeitsplatzes tragen. |
| P273 |
Freisetzung in die Umwelt vermeiden. |
| P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
| P302+P352 |
BEI BERüHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckm??ig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen. |
| P333+P313 |
Bei Hautreizung oder -ausschlag: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen. |
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Dichlorobis(triphenylphosphin)palladium Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R22:Gesundheitssch?dlich beim Verschlucken.
S-S?tze Betriebsanweisung:
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
Bis(triphenylphosphine)palladium chloride is a coordination compound of palladium containing two triphenylphosphine and two chloride ligands. This yellow solid is insoluble in water but can dissolve in some organic solvents, such as toluene and benzene, and is slightly soluble in acetone and chloroform. It is used for palladium-catalyzed coupling reactions, e.g. the Sonogashira–Hagihara reaction. The complex adopts a square planar geometry and numerous similar complexes are known, with different phosphine ligands.
Verwenden
Bis(triphenylphosphine)palladium(II) chloride is used primarily in organometallic catalytic reactions due to the palladium content of the compound. It is also involved in crystalized structures of me tallacyclic complexes which show antiinflammatory and antifungal properties.
Synthese
The synthesis of Bis(triphenylphosphine)palladium(II) chloride can be achieved by the reaction of palladium(II) chloride with triphenylphosphine, resulting in the formation of Bis(triphenylphosphine)palladium(II) chloride. This chemical process is represented by the balanced equation: PdCl2 + 2 PPh3 → PdCl2(PPh3)2.
Allgemeine Beschreibung
Bis(triphenylphosphine)palladium(II) dichloride is an organometallic complex. It is an efficient cross-coupling catalyst for C-C coupling reaction, such as Negishi coupling, Suzuki coupling, Sonogashira coupling and Heck coupling reaction. Detection of bis(triphenylphosphine)palladium(II) dichloride by electrospray ionization quadrupole ion trap mass spectrometry using different imidazolium salts as the charge carrier has been reported. It is employed as catalyst for the Heck reaction medium.
Dichlorobis(triphenylphosphin)palladium Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Dichlorobis(triphenylphosphin)palladium Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 646)Lieferanten
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Shaoxin Catsyn Co., Ltd.
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+undefined-0575-82040869 +86-0575-82040869;
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sales@catsyn.com |
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SHANGHAI KEAN TECHNOLOGY CO., LTD.
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+8613817748580
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cooperation@kean-chem.com |
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40066 |
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Hebei Yanxi Chemical Co., Ltd.
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+8617531190177
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peter@yan-xi.com |
China |
5857 |
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Hebei Chuanghai Biotechnology Co,.LTD
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+86-13131129325
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sales1@chuanghaibio.com |
China |
5889 |
58 |
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Henan Fengda Chemical Co., Ltd
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+86-371-86557731 +86-13613820652
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info@fdachem.com |
China |
20284 |
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Springchem New Material Technology Co.,Limited
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+86-021-62885108 +8613917661608
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info@spring-chem.com |
China |
2068 |
57 |
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Capot Chemical Co.,Ltd.
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+86-（0）57185586718 +86-13336195806
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sales@capot.com |
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29791 |
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Shanghai Daken Advanced Materials Co.,Ltd
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+86-371-66670886
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info@dakenam.com |
China |
18751 |
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Beijing Cooperate Pharmaceutical Co.,Ltd
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010-60279497
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sales01@cooperate-pharm.com |
CHINA |
1803 |
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Henan Tianfu Chemical Co.,Ltd.
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+86-0371-55170693 +86-19937530512
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info@tianfuchem.com |
China |
21634 |
55 |
13965-03-2(Dichlorobis(triphenylphosphin)palladium)Verwandte Suche:
- BIS-(TRIPHENYLPHOSPHINE)-PALLADIUM DICHLORIDE
- BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLORIDE
- TRANS-DICHLOROBIS-(TRIPHENYLPHOSPHINE)-PALLADIUM
- TRANS-BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLORIDE
- Bis(triphenylphosphine)dichloropalladium(II)~Dichlorobis(triphenylphosphine)palladium(II)
- dichlorobis(triphenylphophine) palladium (II)
- Bis(triphenylphosphine)palladium(II) chloride,98%
- Bis(triphenylphosphine)palladium(II) chloride,99% (99.9+%-Pd)
- Palladium(II)bis(triphenylphosphine)
- Bis(triphenylphosphine)palladium(II) chloride, 15% Pd, for analysis
- Bis(triphenylphosphine)palladium(II) dichloride impregnated tablets, ChemDose(R), Bis(triphenylphosphine)palladium(II) dichloride tablets, Dichlorobis(triphenylphosphine)palladium(II) impregnated tablets, PdCl2(PPh3)2 impregnated tablets, Palladium(II) bis(triphenylphosphine) dichloride impregnated tablets
- Bis(triphenylphosphine)palladium(II) dichloride, ChemDose(R) tablets
- Dichlorobis(triphenylphosphine)palladium(II) ,98%
- trans-Dichlorobis(triphenylphosphine)palladium(II), 99.95% trace metals basis
- Bis(triphenylphosphine)palladium(Ⅱ) Dichloride
- is(triphenylphosphine)palladium(II) chloride
- Bis(triphenylphosphine)pa...
- Bis(triphenylphosphine)palladiuM(II) chloride, 98% 2.5GR
- Bis(triphenylphosphine)palladiuM(II) chloride, 98% 5GR
- Bis(triphenylphosphine)palladium(II) dichloride, ChemDose? tablets
- BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) DI&
- trans-Bis(triphenylphosphine)palladium(II)chloride (15% Pd)
- Bis(triphenylphoshine)palladium(II)chloride
- BIS(TRIPHENYLPHOSPHINE) PALLADIUM DICHOLORIDE
- Bis(triphenylphosphine)palladium(II) chloride, 15% Pd
- trans-Dichlorobis(triphenylphosphine)palladium(II),99%(99.9+%-Pd)
- bis(triphenylphosphine)dichloropalladium(ii)
- trans-dichlorobis(triphenylphosphine)palladium(ii), premion
- PALLADIUM(II)CHLORIDE-BIS(TRIPHENYLPHOSPHINE)
- BIS(TRIPHENYLPHOSPHINE)PALLADIUML(II)DICHLORIDE
- BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLO
- BIS (TRIPHENYLPHOSPHANE) PALLADIUM-2-CHLORIDE
- DICHLOROBIS(TRIPHENYLPHOSPHINE)- &
- Dichlorodi(trisphenylphosphine) palladium(II)
- trans-Dichlorobis(triphenylphosphine)palladium(II), Pd 14.0% min
- trans-Dichlorobis(triphenylphosphine)palladium(II), Premion(R), 99.95% (metals basis), Pd 14.7% min
- Dichlorobis(triphenylphosphine)palladium(II), Palladium(II)bis(triphenylphosphine) dichloride
- trans-Dichlorobis(triphenylphosphine)palladium(II), Premion, 99.95% (metals basis), Pd 14.7% min
- Bis(triphenylphosphine)palladiuM(II) chloride, for analysis, 15% Pd
- trans-Dichlorobis(triphenylphosphine)palladiuM(II),98% (PPh3)2PdCl2
- trans-Pd(PPh3)2Cl2
- BIS(TRIPHENYLPHOSPHINE
- Dichlorobis(triphenylphosphine)palladium(Ⅱ)
- Bis(triphenylphospine)palladiuM (II)chloride
- Dichloro bis triphenyl phosphnoPd(II)
- Bis(triphenylphosphine)palladiuM(II) dichloride >=99% trace Metals basis
- Bis(triphenylphosphine)palladium(II) chloride
Dichlorobis(triphenylphosphine)palladium(II)
- Bis(triphenylphosphine)palladium(II) dichloride >=99.99% trace metals basis
- Bis(triphenylphosphine)palladium(II) dichloride, ChemDose(TM) tablets Loading: 1mumol per tablet
- Bis(triphenylphosphine)palladium(II) Dichloride (PdCl2(PPh3)2)
- trans-Dichlorobis(triphenylphosphine)palladium(II),(PPh3)2PdCl2
- Dichlorobis-(triphenylphosphino)-palladium (II)
- Dichlorotris(triphenylphosphine) palladium
- TRIPHENYLPHOSPHINE PALLADIUM CHLORIDETRIPHENYLPHOSPHINE PALLADIUM CHLORIDETRIPHENYLPHOSPHINE PALLADIUM CHLORIDE
- JACS-13965-03-2
- Bis(triphenylphosphine)palladium(II)Dichloride>
- Bis(triphenylphosphine)palladium(II) dichloride>98%,15.2%Pd
- Bis(triphenylphosphine)palladium(II) dichloride, ChemDose(TM) tablets
