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5-Methylphenaziniummethylsulfat

Phenazine methosulfate Struktur
299-11-6
CAS-Nr.
299-11-6
Bezeichnung:
5-Methylphenaziniummethylsulfat
Englisch Name:
Phenazine methosulfate
Synonyma:
PMS;Phenazine methosuL;5-Methylphenazinium;Phenazine methosulfa;PHENAZINE METHOSULFATE;Phenazine Methoshlphate;PHENAZINE METHOSULPHATE;PHENAZINE METHOLSULPHATE;PHENAZINE METHYL SULFATE;PhenazineMethylSulfate>
CBNumber:
CB4315528
Summenformel:
C14H14N2O4S
Molgewicht:
306.34
MOL-Datei:
299-11-6.mol

5-Methylphenaziniummethylsulfat Eigenschaften

Schmelzpunkt:
158-160 °C (dec.)(lit.)
Dichte
1.3395 (rough estimate)
Brechungsindex
1.6930 (estimate)
storage temp. 
-20°C
L?slichkeit
H2O: 0.2 g/mL at 20 °C, clear, deep orange
Aggregatzustand
Crystalline Powder
Farbe
Dark yellow to brown or khaki
Wasserl?slichkeit
soluble in water (approximately 200 mg/ml).
Sensitive 
Light Sensitive
Merck 
14,6109
BRN 
3898869
Stabilit?t:
Stable. Incompatible with strong oxidizing agents.
CAS Datenbank
299-11-6(CAS DataBase Reference)
EPA chemische Informationen
Phenazinium, 5-methyl-, methyl sulfate (299-11-6)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xi,Xn,T
R-S?tze: 36/37/38-68-46
S-S?tze: 26-36/37/39-53-45
RIDADR  2811
WGK Germany  3
RTECS-Nr. SG1645000
8
TSCA  Yes
HS Code  29339900
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P304+P340 BEI EINATMEN: Die Person an die frische Luft bringen und für ungehinderte Atmung sorgen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.
P405 Unter Verschluss aufbewahren.

5-Methylphenaziniummethylsulfat Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R68:Irreversibler Schaden m?glich.
R46:Kann vererbbare Sch?den verursachen.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S53:Exposition vermeiden - vor Gebrauch besondere Anweisungen einholen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).

Beschreibung

Phenazine is a free radical generator. It has been used as an electron transfer reactant in cell viability assays. Phenazine (10 μM) induces ssDNA break formation in the presence of the reducing agent NADPH in a cell-free plasmid cleavage assay when used at a concentration of 10 μM. It induces oxidative DNA damage in an alkaline comet assay and apoptosis in A375 melanoma cells when used at a concentration of 10 μM. Phenazine (20 nM) oxidizes cysteine-containing proteins in HepG2 cells.

Chemische Eigenschaften

orange to light brown crystals or powder

Verwenden

Phenazine Methosulfate is used in tyrosine transaminase test and for enzymic determination of ethanol in blood by the colorimetric micromethod. Used with ascorbic acid to determine nitric oxide reductase activity. Since the reduced PMS is easily oxidized by oxygen, it is used in assays as an electron carrier between enzymes and oxygen, cytochrome c, indophenols, or tetrazolium salts. The reduced PMS is used as an electron donor to reduce cytochrome c or in photosynthetic experiments. Usage of PMS for detection of specific dehydrogenases has been reported.

Definition

ChEBI: 5-methylphenazinium methyl sulfate is an azaheterocycle sulfate salt and a member of phenazines. It is used as an electron carrier in place of the flavine enzyme of Warburg in the hexosemonophosphate system and also in the preparation of succinic dehydrogenase. Green et al., J. Biol. Chem. 217, 551 (1955).

Application

Phenazine methosulfate is a compound used to determine nitric oxide reductase activity. Phenazine methosulfate has been used:
as a component of succinate dehydrogenase enzyme substrate solution.
to induce superoxide radical generation in red blood cell suspensions and to study its influence on RBC deformability.
as a component of complex II histochemistry media.
Used in the discovery of potent bromophenazine antibacterial agents against Staphylococcus.

Allgemeine Beschreibung

Phenazines are heterocyclic compounds produced as secondary metabolites by bacteria.

l?uterung methode

It forms yellow-brown prisms from EtOH (charcoal), or EtOH/Et2O. Its solubility in H2O at 20o is 10%. In the presence of aqueous KI it forms a semiquinone which crystallises as blue leaflets from EtOH. [Wieland & Roseen Chem Ber 48 1117 1913, Voriskova Collect Czech Chem Commun 12 607 1947, Bülow Chem Ber 57 1431 1924, Campbell et al. J Chem Soc 404 1938, Morley J Chem Soc 4008 1952, Beilstein 23 I 59, 23 II 234, 23 III/IV 1658, 23/8 V 395.]

5-Methylphenaziniummethylsulfat Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


5-Methylphenaziniummethylsulfat Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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299-11-6(5-Methylphenaziniummethylsulfat)Verwandte Suche:


  • Phenazinium,5-methyl-,methylsulfate
  • 5-Methylphenazinium
  • 5-Methylphezinium methosulfate
  • 5-methylphenazinium methyl sulphate
  • N-Methylphenazonium methyl sulphate
  • Phenazine Methoshlphate
  • PhenazineMethosulphate~98%
  • PHENAZINE METHOLSULPHATE
  • Phenazinemethosulphate,99%
  • N-Methylphenazonium methosulfate'PMS,phenazine methosulfate
  • PHENAZINEMETHOSULFATE,REAGENT
  • PMS,phenazine methosulfate
  • N- METHYLPHENAZONIUM METHOSULFATE/PHENAZINE METHOSULPHATE(PMS)
  • Methylphenazinium methylsulfate
  • PHENAZONIUM METHOSULPHATE extrapure
  • N-Methylphenazine methylsulfate salt
  • 5-Methylphenazinium methyl sulfate, N-Methylphenazonium methyl sulfate, PMS
  • Phenazine methosulfate ,99%
  • Phenazine Methosulfate,PMS
  • PMS
  • PHENAZINE METHOSULFATE
  • PHENAZINE METHOSULPHATE
  • PHENAZINE METHYL SULFATE
  • N-METHYLDIBENZOPYRAZINE METHYL SULFATE SALT
  • N-METHYLDIBENZYLPYRAZINE METHYL SULFATE SALT
  • N-METHYLPHENAZINIUM METHYLSULFATE
  • N-METHYLPHENAZONIUM METHOSULFATE
  • N-METHYLPHENAZONIUM METHOSULPHATE
  • N-METHYLPHENAZONIUM METHYL SULFATE
  • METHYLPHENAZONIUM METHOSULFATE
  • 5-Methylphenazinium methosulfate
  • Phenazine Methyl Sulfate [for Biochemical Research]
  • PHENAZINE.METHOSULFATEPURE
  • Phenazine methosulfate,5-Methylphenazinium methyl sulfate, N-Methylphenazonium methyl sulfate, PMS
  • Phenazine methosulfate 1g [299-11-6]
  • Phenazine methosulfa
  • 5-METHYLPHENAZINIUM METHYL SULFATE
  • 5-Methylphenazine,methylsulfatesalt
  • 5-methylphenazinemethylsulfate
  • 5-methyl-phenaziniumethylsulfate
  • 5-methylphenaziummethylsulfate
  • 5-n-methylphenazoniummethosulfate
  • N-Methylphenaziniummethylsulf
  • n-methylphenaziummethosulfate
  • Phenazine Methosulfate, 99% 1GR
  • Phenazine Methosulfate, 99% 25GR
  • Phenazine Methosulfate, 98+%
  • N-Methylphenazonium Methosulfate N-Methylphenazonium Methyl Sulfate Phenazine Methosulfate
  • 5-Methylphenazin-5-iuM Methanesulfonate
  • 5-Methylphenazin-5-iuM Methyl sulfate
  • Phenazine methosuL
  • PhenazineMethylSulfate[forBiochemicalResearch]>
  • PhenazineMethylSulfate>
  • 5-Methylphenaziniummethylsulfat
  • 5-Methylphenazinium methosulfater
  • Phenazonium Methosulphate (PMS) extrapure, 99%
  • Phenazonium Methosulphate (PMS) for tissue culture, 99%
  • PHENAZINE METHOLSULPHATE Extra Pure
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