Phenoxyacetylchlorid
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Phenoxyacetylchlorid Eigenschaften
- Schmelzpunkt:
- 100-100.5 °C
- Siedepunkt:
- 225-226 °C (lit.)
- Dichte
- 1.235 g/mL at 25 °C (lit.)
- Brechungsindex
- n
20/D 1.534(lit.)
- Flammpunkt:
- 227 °F
- storage temp.
- Store at RT.
- Aggregatzustand
- Liquid
- Farbe
- Clear slightly yellow to brown
- Wasserl?slichkeit
- Reacts with water.
- Sensitive
- Moisture Sensitive
- BRN
- 607585
- CAS Datenbank
- 701-99-5(CAS DataBase Reference)
- NIST chemische Informationen
- Acetyl chloride, phenoxy-(701-99-5)
- EPA chemische Informationen
- Acetyl chloride, phenoxy- (701-99-5)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher | C | ||
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R-S?tze: | 14-34-36/37 | ||
S-S?tze: | 26-36/37/39-45 | ||
RIDADR | UN 3265 8/PG 2 | ||
WGK Germany | 3 | ||
F | 10-19 | ||
TSCA | Yes | ||
HazardClass | 8 | ||
PackingGroup | II | ||
HS Code | 29189090 |
Bildanzeige (GHS) | ||||||||||||||||||||||
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Alarmwort | Achtung | |||||||||||||||||||||
Gefahrenhinweise |
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Sicherheit |
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Phenoxyacetylchlorid Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R14:Reagiert heftig mit Wasser.R34:Verursacht Ver?tzungen.
R36/37:Reizt die Augen und die Atmungsorgane.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
Chemische Eigenschaften
Colorless to brown liquidVerwenden
Acylation of D- and DL-WV with phenoxyacetyl chloride, followed by cleavage of the t-butyl ester,afforded the penultimate penicilloic acids. Phenoxyacetyl chloride was used in the synthesis of series of macrocyclic bis-β-lactams, 5-phenyl-6-epiphenoxymethylpenicillin benzyl ester, N-protected guanosine derivatives, useful in RNA synthesis, phenyloxyketene, for cycloaddition to imines leading to β-lactams. Treatment of iminophosphoranes with phenoxyacetyl chloride afforded respectively the trans- and cis-3-(acylamino)-p-lactams. By the oxidative addition of stannous fluoride to allyliodide, with 1, 2-O-isopropylidene-D-glyceraldehyde and phenoxyacetyl chloride results in the predominant formation of erythro homoallylester, which is in turn converted into 2-deoxy-D-ribose. The 4-disubstituted P-lactams (4a-c and 6a-b) were prepared through the reaction of N,N-diphenylhydrazones and N-methyl-N-phenylhydrazones of ketones with phenoxyacetyl chloride/Et3N in dichloromethane.l?uterung methode
If it has no OH band in the IR then distil it in a vacuum, taking precautions for the moisture-sensitive compound. If it contains free acid (due to hydrolysis, OH bands in the IR), then add an equal volume of redistilled SOCl2, reflux for 2-3hours, evaporate and distil the residue in a vacuum as before. The amide has m 101o. [McElvain & Carney J Am Chem Soc 68 2592 1946, Beilstein 6 III 613.]Phenoxyacetylchlorid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Phenoxyacetylchlorid Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 147)Lieferanten
Firmenname | Telefon | Land | Produktkatalog | Edge Rate | |
---|---|---|---|---|---|
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 |
sales@capot.com | China | 29791 | 60 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49374 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
factory@coreychem.com | China | 29815 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 |
sales@tnjchem.com | China | 34553 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 |
info@dycnchem.com | China | 52849 | 58 |
LEAP CHEM CO., LTD. | +86-852-30606658 |
market18@leapchem.com | China | 24727 | 58 |
Hebei Weibang Biotechnology Co., Ltd | +8617732866630 |
bess@weibangbio.com | China | 18232 | 58 |
GIHI CHEMICALS CO.,LIMITED | +8618058761490 |
info@gihichemicals.com | China | 49979 | 58 |
SUZHOU SENFEIDA CHEMICAL CO.,LTD | +86-0512-83500002 +8615195660023 |
sales@senfeida.com | China | 23046 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 |
info@fdachem.com | China | 20288 | 58 |
701-99-5(Phenoxyacetylchlorid)Verwandte Suche:
Bromacetylchlorid
Ammoniumchlorid
Phenylacetylchlorid
Cholinchlorid
Natriumchlorid
Acetylchlorid
Tamoxifen
Ethylenglykolmonophenylether
Chloracetylchlorid
Ethyl-[2-(4-phenoxyphenoxy)ethyl]carbamat
Phenoxybenzaminhydrochlorid
Benzyloxyacetyl chloride
Benzylchlorid
Calciumchlorid
Phenoxyessigsure
Kaliumchlorid
Polyvinyl chloride
2-Phenoxypropionylchlorid
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- Carbonyl Compounds
- Building Blocks
- Acid Halides
- Organic Building Blocks
- Biochemistry
- Nucleosides, Nucleotides & Related Reagents
- Protecting Agents for Hydroxyl and Amino Groups
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