Identification | More | [Name]
4-Methylpiperidine | [CAS]
626-58-4 | [Synonyms]
4-METHYLPIPERIDINE 4-PIPECOLINE 4PPC AKOS BBS-00003666 GAMMA-PIPECOLINE HEXAHYDRO-G-PICOLINE LABOTEST-BB LTBB000596 4-methyl-piperidin 4-pipecoline(gamma-) 4-Methylpiperidine99% PIPECOLINE = 4-METHYLPIPERIDINE Piperidine, 4-methyl- 4-PIPECOLINE 4-METHYL PIPERIDINE 4Me-Pip 4-Methylpiperidine, 98+% γ-Pipecoline, 4-Pipecoline g-Pipecoline | [EINECS(EC#)]
210-954-1 | [Molecular Formula]
C6H13N | [MDL Number]
MFCD00006005 | [Molecular Weight]
99.17 | [MOL File]
626-58-4.mol |
Chemical Properties | Back Directory | [Appearance]
clear slightly yellow liquid | [Melting point ]
4-5 °C
| [Boiling point ]
124 °C(lit.)
| [density ]
0.838 g/mL at 25 °C(lit.) | [vapor pressure ]
16 hPa (20 °C) | [refractive index ]
n20/D 1.446(lit.)
| [Fp ]
45 °F
| [storage temp. ]
Flammables area | [solubility ]
Chloroform | [form ]
Liquid | [pka]
pK1:11.23(+1) (25°C,μ=0.5) | [color ]
Clear slightly yellow | [Specific Gravity]
0.838 | [PH]
13 (100g/l, H2O, 20℃) | [Water Solubility ]
miscible | [BRN ]
1083 | [CAS DataBase Reference]
626-58-4(CAS DataBase Reference) | [NIST Chemistry Reference]
Piperidine, 4-methyl-(626-58-4) | [EPA Substance Registry System]
626-58-4(EPA Substance) |
Safety Data | Back Directory | [Hazard Codes ]
F,Xi | [Risk Statements ]
R11:Highly Flammable. R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . | [RIDADR ]
UN 1993 3/PG 2
| [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29333999 |
Hazard Information | Back Directory | [Chemical Properties]
clear slightly yellow liquid | [Uses]
4-Methylpiperidine is used as a catalyst in the synthesis of stilbene derivatives as anti-malarial agents. It also serves as an anti-corrosive compound for iron. | [Purification Methods]
Purify it via the hydrochloride (m 189o). It is freed from 3-methylpyridine by zone melting. The hydrobromide has m 173o(from butanone/*C6H6). [Beilstein 20 III/IV 1511, 20/4 V 116.] |
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