| Identification | More | [Name]
2'-Methoxyacetophenone | [CAS]
579-74-8 | [Synonyms]
1-(2-METHOXYPHENYL)ETHANONE
2-ACETANISOLE
2-ACETOANISOLE
2-ACETYLANISOLE
2'-METHOXYACETOPHENONE
2-METHOXYACETOPHENONE
AKOS BBS-00003280
O-ACETANISOLE
O-ACETYLANISOLE
O-METHOXYACETOPHENONE
1-(2-methoxyphenyl)-ethanon
2-methoxyacetylbenzene
Acetophenone, 2'-methoxy-
Ethanone, 1-(2-methoxyphenyl)-
-Methoxy acetophenone
1-(2-methoxyphenyl)ethan-1-one
2Methoxyacetophenone99%
2’-Methoxyacetophenone 99%
ORTHO-ACETANISOLE
2'-Methoxyacetophenone | [EINECS(EC#)]
209-446-2 | [Molecular Formula]
C9H10O2 | [MDL Number]
MFCD00008725 | [Molecular Weight]
150.17 | [MOL File]
579-74-8.mol |
| Chemical Properties | Back Directory | [Appearance]
clear slightly yellow to orange or slightly | [Melting point ]
117–119°C | [Boiling point ]
131 °C18 mm Hg(lit.) | [density ]
1.09 g/mL at 25 °C(lit.)
| [FEMA ]
4163 | 2-METHOXYACETOPHENONE | [refractive index ]
n20/D 1.5393(lit.)
| [Fp ]
228 °F
| [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
Chloroform (Sparingly), Methanol (Sparingly) | [form ]
Liquid | [color ]
Clear slightly yellow to orange or slightly brown | [Odor]
at 1.00 % in propylene glycol. powdery anisic almond phenolic | [Odor Type]
anisic | [Water Solubility ]
immiscible | [Sensitive ]
Light Sensitive | [JECFA Number]
2042 | [BRN ]
1100602 | [LogP]
1.82 | [CAS DataBase Reference]
579-74-8(CAS DataBase Reference) | [NIST Chemistry Reference]
Ortho-methoxyacetophenone(579-74-8) | [EPA Substance Registry System]
579-74-8(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R22:Harmful if swallowed.
R36/38:Irritating to eyes and skin .
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [TSCA ]
Yes | [HS Code ]
29145000 |
| Hazard Information | Back Directory | [Chemical Properties]
clear slightly yellow to orange or slightly | [Chemical Properties]
Colorless to pale yellow clear liquid; powdery anisic almond phenolic aroma. | [Uses]
2''-Methoxyacetophenone is a useful building block, often used in the preparation of chalcones, such as the chalcones of 3-benzylidene-2-chlorocyclohex-1-enecarbaldehyde for use as potential anti-proliferative agents. | [Preparation]
Preparation by reaction of dimethyl sulfate with o-hydroxyacetophenone in the presence of sodium hydroxide. | [Aroma threshold values]
Anisic-type, medium strength odor; recommend smelling in a 1.00% solution or less. | [Taste threshold values]
Powdery musty anisic almond taste at 30 ppm in water. | [Synthesis Reference(s)]
Tetrahedron Letters, 22, p. 2605, 1981 DOI: 10.1016/S0040-4039(01)90532-5
Journal of the American Chemical Society, 72, p. 5161, 1950 DOI: 10.1021/ja01167a100
The Journal of Organic Chemistry, 52, p. 150, 1987 DOI: 10.1021/jo00377a027 |
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