Identification | More | [Name]
3-Methoxyacetophenone | [CAS]
586-37-8 | [Synonyms]
1-(3-methoxyphenyl)ethanone 3-ACETANISOLE 3-ACETOANISOLE 3-ACETYLANISOLE 3'-METHOXYACETOPHENONE 3-METHOXYACETOPHENONE AKOS BBS-00003224 M-ACETANISOLE M-ACETYLANISOLE M-METHOXYACETOPHENONE 1-Acetyl-3-methoxybenzene Acetophenone, 3'-methoxy- Acetophenone, m-methoxy- Ethanone,1-(3-methoxyphenyl)- meta-Methoxyacetophenone Methyl 3-methoxyphenyl ketone m-Methoxyacetophennone 3'-Methoxyacetophenone m-Acetanisole 3-Acetanisole 3-Methoxyacetophenone,>99% 3-Methoxyacetophenone,97% | [EINECS(EC#)]
209-573-3 | [Molecular Formula]
C9H10O2 | [MDL Number]
MFCD00008736 | [Molecular Weight]
150.17 | [MOL File]
586-37-8.mol |
Chemical Properties | Back Directory | [Appearance]
clear slightly yellow to slightly brown liquid | [Melting point ]
-7 °C
| [Boiling point ]
239-241 °C(lit.)
| [density ]
1.094 g/mL at 25 °C(lit.)
| [vapor pressure ]
2.41-10.665Pa at 20-25℃ | [refractive index ]
n20/D 1.542(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Chloroform (Slightly), Ethyl Acetate (Slightly) | [form ]
Liquid | [color ]
Clear slightly yellow to slightly brown | [Specific Gravity]
1.094 | [Water Solubility ]
Fully miscible in water. Soluble in alcohol. | [Sensitive ]
Light Sensitive | [BRN ]
878552 | [CAS DataBase Reference]
586-37-8(CAS DataBase Reference) | [NIST Chemistry Reference]
Ethanone, 1-(3-methoxyphenyl)-(586-37-8) |
Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R36/38:Irritating to eyes and skin . R22:Harmful if swallowed. R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) . S24/25:Avoid contact with skin and eyes . S37/39:Wear suitable gloves and eye/face protection . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [HS Code ]
29145000 |
Hazard Information | Back Directory | [Chemical Properties]
clear slightly yellow to slightly brown liquid | [Uses]
It is applied in the asymmetric transfer hydrogenation of ketones catalyzed by ruthenium(II) complexes. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 109, p. 7137, 1987 DOI: 10.1021/ja00257a038 Synthesis, p. 406, 1987 DOI: 10.1055/s-1987-27965 | [Flammability and Explosibility]
Nonflammable |
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