| Identification | More | [Name]
6-Chloro-2-methyl-3-nitropyridine | [CAS]
22280-60-0 | [Synonyms]
2-CHLORO-3-NITRO-6-METHYL PYRIDINE
2-CHLORO-3-NITRO-6-PICOLINE
2-CHLORO-5-NITRO-6-METHYLPYRIDINE
2-CHLORO-5-NITRO-6-PICOLINE
2-CHLORO-6-METHYL-3-NITROPYRIDINE
2-CHLORO-6-METHYL-5-NITROPYRIDINE
6-CHLORO-2-METHYL-3-NITROPYRIDINE
6-CHLORO-3-NITRO-2-METHYLPYRIDINE
6-CHLORO-3-NITRO-2-PICOLINE
6-CHLORO-5-NITRO-2-PICOLINE
TIMTEC-BB SBB003830
TIMTEC-BB SBB003832
2-CHLORO-5-NITRO-6-PICOLINE (2-CHLORO-6-METHYL-5-NITROPYRIDINE)
2-Chloro-5-Nitro-6-methylpyrdine
6-Chloro-2-methyl-3-nitro-pyridine ,97% | [Molecular Formula]
C6H5ClN2O2 | [MDL Number]
MFCD03085820 | [Molecular Weight]
172.57 | [MOL File]
22280-60-0.mol |
| Chemical Properties | Back Directory | [Appearance]
Light yellow Cryst | [Melting point ]
54-58 °C | [Boiling point ]
200°C (rough estimate) | [density ]
1.5610 (rough estimate) | [refractive index ]
1.5500 (estimate) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [form ]
Powder | [pka]
-3.26±0.10(Predicted) | [color ]
Light beige to brown | [Detection Methods]
HPLC | [InChI]
InChI=1S/C6H5ClN2O2/c1-4-5(9(10)11)2-3-6(7)8-4/h2-3H,1H3 | [InChIKey]
GHSRMSJVYMITDX-UHFFFAOYSA-N | [SMILES]
C1(C)=NC(Cl)=CC=C1[N+]([O-])=O | [CAS DataBase Reference]
22280-60-0(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [Hazard Note ]
Harmful | [HazardClass ]
IRRITANT | [HS Code ]
29333990 |
| Hazard Information | Back Directory | [Chemical Properties]
Light yellow Cryst | [Uses]
6-Chloro-2-methyl-3-nitropyridine has been used as a reactant for the synthesis of fluorine-containing pyridinealdoxime derivatives as treatment of organophosphorus nerve-agent poisoning. | [Preparation]
A mixture of 2-oxo-5-nitro-6-methyl-1,2-dihydropyridine, phosphorous oxychloride, and phosphorous pentachloride was heated at 110° C for 2 hours, whereupon the reaction mixture was charged with an additional portion of phosphorous pentachloride and phosphorous oxychloride. The reaction was stirred for 1 hour and then poured into ice water. The brown solid was filtered and washed with cold water, to give 6-Chloro-2-methyl-3-nitropyridine (94%).
|
|
|