Atrazin
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Atrazin Eigenschaften
- Schmelzpunkt:
- 175°C
- Siedepunkt:
- 200°C
- Dichte
- 1.187
- Dampfdruck
- 0Pa at 25℃
- Brechungsindex
- 1.6110 (estimate)
- Flammpunkt:
- 11 °C
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- L?slichkeit
- DMSO: 83.33 mg/mL (386.36 mM)
- pka
- pKa 1.64 (Uncertain)
- Aggregatzustand
- Crystalline
- Farbe
- Crystals
- Wasserl?slichkeit
- Slightly soluble. 0.007 g/100 mL
- Merck
- 14,871
- BRN
- 612020
- Expositionsgrenzwerte
- OSHA PEL: TWA 5 mg/m3; ACGIH TLV: TWA 5 mg/m3.
- Stabilit?t:
- Stable. Incompatible with strong oxidizing agents.
- LogP
- 2.59 at 20℃ and pH7.31-7.51
- Oberfl?chenspannung
- 57.6mN/m at 30mg/L and 21℃
- Dissoziationskonstante
- 1.56 at 20℃
- CAS Datenbank
- 1912-24-9(CAS DataBase Reference)
- IARC
- 3 (Vol. 53, 73) 1999
- NIST chemische Informationen
- Atrazine(1912-24-9)
- EPA chemische Informationen
- Atrazine (1912-24-9)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher | Xn;N,N,Xn,T,F,Xi | ||
---|---|---|---|
R-S?tze: | 43-48/22-50/53-39/23/24/25-23/24/25-11-38-36/37/38-20/21/22-52/53 | ||
S-S?tze: | 2-36/37-60-61-45-16-7-36-26 | ||
RIDADR | 3077 | ||
OEB | B | ||
OEL | TWA: 5 mg/m3 | ||
WGK Germany | 3 | ||
RTECS-Nr. | XY5600000 | ||
HazardClass | 9 | ||
PackingGroup | III | ||
HS Code | 29336990 | ||
Giftige Stoffe Daten | 1912-24-9(Hazardous Substances Data) | ||
Toxizit?t | LD50 orally in mice: 1750 mg/kg (Dalgaard-Mikkelsen, Poulsen) |
Bildanzeige (GHS) | |||||||||||||||||||||||||||||
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Sicherheit |
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Atrazin Chemische Eigenschaften,Einsatz,Produktion Methoden
ERSCHEINUNGSBILD
FARBLOSE KRISTALLE.CHEMISCHE GEFAHREN
Zersetzung beim Erhitzen unter Bildung giftiger Rauche mit Chlorwasserstoff, Stickstoffoxiden.ARBEITSPLATZGRENZWERTE
TLV: 5 mg/m?(als TWA); Krebskategorie A4 (nicht klassifizierbar als krebserzeugend für den Menschen); (ACGIH 2005).MAK: 2 mg/m?(Einatembare Fraktion); Spitzenbegrenzung: überschreitungsfaktor II(8); (DFG 2005).
AUFNAHMEWEGE
Aufnahme in den K?rper durch Inhalation und durch Verschlucken.INHALATIONSGEFAHREN
Beim Verdampfen bei 20 °C tritt eine gesundheitssch?dliche Kontamination der Luft nicht oder nur sehr langsam ein, viel schneller jedoch beim Versprühen oder Dispergieren.WIRKUNGEN BEI KURZZEITEXPOSITION
WIRKUNGEN BEI KURZZEITEXPOSITION:Die Substanz reizt die Augen.
WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION
Wiederholter oder andauernder Hautkontakt kann zu Hautsensibilisierung führen. M?glich sind Auswirkungen auf Leber und Nieren. M?glicherweise krebserzeugend für den Menschen.LECKAGE
NICHT in die Kanalisation spülen. Verschüttetes Material in Beh?ltern sammeln; falls erforderlich durch Anfeuchten Staubentwicklung verhindern. Reste sorgf?ltig sammeln. An sicheren Ort bringen. Pers?nliche Schutzausrüstung: Atemschutzger?t, P2-Filter für sch?dliche Partikel.R-S?tze Betriebsanweisung:
R43:Sensibilisierung durch Hautkontakt m?glich.R48/22:Gesundheitssch?dlich: Gefahr ernster Gesundheitssch?den bei l?ngerer Exposition durch Verschlucken.
R50/53:Sehr giftig für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.
R39/23/24/25:Giftig: ernste Gefahr irreversiblen Schadens durch Einatmen, Berührung mit der Haut und durch Verschlucken.
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
R11:Leichtentzündlich.
R38:Reizt die Haut.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R20/21/22:Gesundheitssch?dlich beim Einatmen,Verschlucken und Berührung mit der Haut.
S-S?tze Betriebsanweisung:
S2:Darf nicht in die H?nde von Kindern gelangen.S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S60:Dieses Produkt und sein Beh?lter sind als gef?hrlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S16:Von Zündquellen fernhalten - Nicht rauchen.
S7:Beh?lter dicht geschlossen halten.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
Atrazine is a colorless, crystalline solid. Although atrazine is very stable, it is only slightly soluble in water, but soluble in N-pentane, chloroform, dimethyl sulfoxide, ethyl acetate, diethyl ether, and methanol. Atrazine is a broad-spectrum triazine herbicide and is used as a selective herbicide for weed control in corn and asparagus, in the culture of sugarcane and pineapple. Additionally, it is used as a total herbicide on roads and public places as well as on uncultivated ground in combination with amitrol, bromacil, dalapon, and growth promoters. Atrazine inhibits photosynthesis and other metabolic processes in plants. There are no natural sources of atrazine. It is produced from cyanuric acid chloride with ethylamine and isopropylamine. The reaction takes place successively in tetrachloromethane. All atrazine produced is released into the environment. The formulations include granules, water dispersible granules, liquid, suspension concentrate, wettable powder, and a combination with many other herbicides. Atrazine is compatible with various insecticides and fungicides.Atrazine was banned in the European Union (EU) in 2004 because of its persistent groundwater contamination. In the United States, however, atrazine is one of the most widely used herbicides, with 76 million pounds of it applied each year. It is probably the most commonly used herbicide in the world.
Verwenden
Atrazine is widely used as a selective herbicide to control broadleaf and grassy weeds in corn, sorghum, rangeland, sugarcane, orchards, pineapple, and turf grass sod. It is also used for selective weed control in conifer restoration and Christmas tree plantations. It is also used as a nonselective herbicide for vegetation control in noncrop land.Definition
ChEBI: A diamino-1,3,5-triazine that is 1,3,5-triazine-2,4-diamine substituted by a chloro group at position 6 while one of hydrogens of each amino group is replaced respectively by an ethyl and a propan-2-yl group.Vorbereitung Methode
Atrazine is prepared by reacting cyanuric chloride with one equivalent of ethylamine, followed by one equivalent of isopropylamine in the presence of an acid-binding agent.Allgemeine Beschreibung
White crystalline solid. Melting point 173-175°C. Sinks in water. A selective herbicide used for season-long weed control in a variety of crops.Air & Water Reaktionen
Insoluble in water.Reaktivit?t anzeigen
Atrazine undergoes slow hydrolysis at 158° F under neutral conditions. Hydrolysis is more rapid in acidic or alkaline conditions. Forms salts with acids .Hazard
Hematologic, preproductive and develop- mental effects. Questionable carcinogen.Brandgefahr
Special Hazards of Combustion Products: Irritating hydrogen chloride and toxic oxides of nitrogen may be formed.Landwirtschaftliche Anwendung
Atrazine is the generic name for 2-chloro-4-ethylamino- 6-isopropylamino-s-triazine.A trazine is an example of photosynthesis inhibitors and herbicides.Atrazine was the first s-triazine used in maize. The use of this herbicide and others in the same group has expanded to selective application in perennial crops and orchids as well as for non-crop and industrial sites.
Pharmakologie
In plants, themajor pathways of atrazine transformation include hydroxylation, N-dealkylation, and glutathione conjugation. Hydroxylation of atrazine and other s-triazines occurs in a wide range of plants and is considered a detoxification mechanism because hydroxyatrazine is not phytotoxic. Hydroxylation is catalyzed via reaction with the naturally occurring compound, benzoxazinone (127). A hypothetical ether-linked intermediate has been proposed to undergoes hydrolysis to produce hydroxylated triazine and regenerated benzoxazinone. This reaction occurs in many susceptible and resistant plant species, and the rate of this reaction is governed by the amount of benzoxazinone present in the tissue. The hydroxylation reaction predominates in root tissue, whereas GSH conjugation is more prominent in leaf tissue of plants containing a GST that has substrate specificity for atrazine. Because atrazine is a photosystem II (PS II) inhibitor, possession of a rapid detoxification system, such as a specific GST, is paramount to provide tolerance to this compound.Sicherheitsprofil
Poison by intraperitoneal route. Moderately toxic by ingestion. Mildly toxic by inhalation and skin contact. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. A skin and severe eye irritant. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of ClandNOx.m?gliche Exposition
Atrazine is an herbicide and plant growth regulator used for season-long weed control in corn, sorghum, and certain other crops. Banned for use as a pesticide in the EU. US annual use . 75 millon pounds.Carcinogenicity
An increase in mammary adenomas and fibroadenomas was observed in female rats fed 1000 ppm, but not 500 ppm atrazine or less for their lifetime. An increase in the incidence of mammary carcinomas was seen at 70, 500, and 1000 ppm, but not at 10 ppm. The biological significance of these findings is not known but may be related to a hormonally mediated mechanism. Rats fed 375 or 750 ppmatrazine for 2 years showed an increase in mammary tumors in males at 750 ppm. Uterine carcinomas increased in both groups and the incidence of malignant tumors also increased in both sexes.Environmental Fate
Atrazine is highly persistent in soil. In soil and water, atrazine degrades by hydrolysis, followed by biodegradation by soil microorganisms. Hydrolysis is rapid in acidic or basic environments, but is slower around neutral pH. Sunlight and evaporation do not affect its removal rate. Atrazine can persist for longer than 1 year under dry or cold conditions. It is moderately to highly mobile in soils with low clay or low organic matter content. Because it does not adsorb strongly to soil particles and has a lengthy half-life (60 to >100 days), it has a high potential for groundwater contamination despite being only moderately soluble in water. It is frequently detected in drinking water wells.Versand/Shipping
UN2763 Triazine pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.Inkompatibilit?ten
Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.Waste disposal
Atrazine is hydrolyzed by either acid or base. The hydroxy compounds are generally herbicidally inactive, but their complete environmental effects are uncertain. However, the method appears suitable for limited use and quantities of triazine. Atrazine underwent .99% decomposition when burned in a polyethylene bag, and combustion with a hydrocarbon fuel would appear to be a generally suitable method for small quantities. Combustion of larger quantities would probably require the use of a caustic wet scrubber to remove nitrogen oxides and HCl from the product gases.Atrazin Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Natriumhypochlorit
Packed tower
Nitrobenzene
Cyanwasserstoff
Chlorbenzol
Natriumhydroxid
Isopropylamin
2,4,6-Trichlor-1,3,5-triazin
Downstream Produkte
Atrazin Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 415)Lieferanten
Firmenname | Telefon | Land | Produktkatalog | Edge Rate | |
---|---|---|---|---|---|
Qingdao Trust Agri Chemical Co.,Ltd | +8613573296305 |
aroma@qdtrustagri.com | China | 301 | 58 |
Hebei Mojin Biotechnology Co.,Ltd | +86-15028179902 |
angelia@hbmojin.com | China | 1176 | 58 |
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD | +8615350851019 |
admin@86-ss.com | China | 1001 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21634 | 55 |
Hangzhou FandaChem Co.,Ltd. | +8615858145714 |
FandaChem@Gmail.com | China | 9087 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 32957 | 60 |
Shanghai Zheyan Biotech Co., Ltd. | 18017610038 |
zheyansh@163.com | CHINA | 3619 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29880 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28172 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22963 | 58 |
1912-24-9(Atrazin)Verwandte Suche:
Hydroxyethyl Cellulose
2-Piperazin-1-ylethylamin
6-Propyl-2-thiouracil
1,3,5-Triazin
Ethyldiisopropylamin
Ethyl cellulose
Hydroxyethyl starch
3-Ethoxy-4-hydroxybenzaldehyd
2-Ethyl-3-hydroxy-4H-pyran-4-on
4,6-Diamino-1,3,5-triazin-2(1H)-on
2-Chlor-4,6-diamino-1,3,5-triazin
Chlordifluormethan
Atraton
2-Amino-4-ethylamino-6-chlor-1,3,5-triazin
2-Chlor-4-amino-6-isopropylamino-1,3,5-triazin
Atrazin
- Atrazine, >=97%
- CHLORAMPHENICOL - ULTRA PURE GRADE
- Atrazine, Pesticide Mix
- 2-CHLORO-4-ETHYLAMINO-6-ISOPROPYLAMINO-1,3,5-TRIAZINE
- 2-CHLORO-4-ETHYLAMINO-6-ISOPROPYL-AMINO-S-TRIAZINE
- 2-CHLORO-4-ETHYLAMINO-6-ISOPROPYLAMINO-SYM-TRIAZINE
- AKTIKON
- AATREX(R)
- AATREX
- BICEP
- ATRANEXCALLIZINE
- ATRATOL(R)
- ATRAZINE
- G30027
- GESAPRIM
- GESAPRIM(R)
- 'LGC' (1603)
- PRIMAGRAM
- PRIMEXTRA
- N2-ETHYL-N4-ISOPROPYL-6-CHLORO-1,3,5-TRIAZINE-2,4-DIAMINE
- TIMTEC-BB SBB003393
- Atraizine
- Atrazine W.P.
- Atrazine suspensoid
- ATRAZINE, 1X1ML, MTBE, 1000UG/ML
- ATRAZINE, 500MG, NEAT
- ATRAZINE, 100MG, NEAT
- ATRAZIN PESTANAL (2-CHLOR-4-ETHYL-AMINO- 6-ISOPROPYLAMINO-1,3,5-TRI-AZINE), 250
- Atrazine 90
- 2-chloro-4-ethylamino-6-iso-propyladmino-1,3,5-triazine
- A 1317
- Artrex
- Atrazinegeigy
- Semparol
- 2-Chloro-4-ethylamino-6-isopropylamino-s-triazine,98%
- Atrazine,2-Chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine
- Atrazine 500mg [1912-24-9]
- aatrexnine-o
- Actinite PK
- actinitepk
- Akticon
- Aktikon PK
- aktikonpk
- Aktinit A
- Aktinit PK
- aktinita
- aktinitpk
- aneldazin
- Argezin
- Ashlade atrazine 50 FL
- Atazinax
- Atraflow
- Atraflow plus
- Atrasine
- Atrataf
- Atratol A
- epapesticidecode080803.
- Extrazine II