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ChemicalBook--->CAS DataBase List--->7212-44-4

7212-44-4

7212-44-4 Structure

7212-44-4 Structure
IdentificationMore
[Name]

Nerolidol
[CAS]

7212-44-4
[Synonyms]

3,7,11-TRIMETHYL-1,6,10-DODECATRIEN-3-OL
3-HYDROXY-3,7,11-TRIMETHYL-1,6,10-DODECATRIENE
3-HYDROXY-3,7,11-TRIMETHYL-1,6,10-DODECATRIENE,3,7,11-TRIMETHYL-1,6,10-DODECATRIEN-3-OL
(CIS AND TRANS)-NEROLIDOL
(E)-3,7,11-TRIMETHYL-1,6,10-DODECATRIEN-3-OL
FEMA 2772
NEROLIDOL
NEROLIDOL, TRANS-
TIMTEC-BB SBB007741
TRANS-3,7,11-TRIMETHYL-1,6,10-DODECATRIEN-3-OL
TRANS-NEROLIDOL
1,6,10-dodecatrien-3-ol,3,7,11-trimethyl-
10-dodecatrien-3-ol,3,7,11-trimethyl-6
3,7,11-trimethyl-1,6,10-dodecatrien-3-ol (nerolidol)
3,7,11-Trimethyl-1,6,10-dodecatriene-3-ol
3,7,11-trimethyl-dodeca-1,6,10-trien-3-ol
3,7,11-Trimethyldodeca-1,6,10-trien-3-ol
6,10-Dodecatrien-3-ol,3,7,11-trimethyl-1
cis,trans-Nerolidol
Nerolidol,c&t
[EINECS(EC#)]

230-597-5
[Molecular Formula]

C15H26O
[MDL Number]

MFCD00008911
[Molecular Weight]

222.37
[MOL File]

7212-44-4.mol
Chemical PropertiesBack Directory
[Appearance]

Clear slightly yellow liquid
[Melting point ]

-75 °C
[Boiling point ]

114 °C/1 mmHg (lit.)
[density ]

0.875 g/mL at 25 °C(lit.)
[vapor pressure ]

<1 hPa (20 °C)
[FEMA ]

2772
[refractive index ]

n20/D 1.479(lit.)
[Fp ]

230 °F
[storage temp. ]

Store below +30°C.
[solubility ]

0.014g/l
[form ]

Liquid
[pka]

14.44±0.29(Predicted)
[color ]

Clear slightly yellow
[Specific Gravity]

0.88
[Odor]

at 100.00 %. floral green waxy citrus woody
[explosive limit]

0.7-4.5%(V)
[Odor Type]

floral
[Water Solubility ]

immiscible
[JECFA Number]

1646
[Merck ]

14,6477
[BRN ]

1724135
[LogP]

4.5 at 24℃
[CAS DataBase Reference]

7212-44-4(CAS DataBase Reference)
[NIST Chemistry Reference]

1,6,10-Dodecatrien-3-ol, 3,7,11-trimethyl-(7212-44-4)
[EPA Substance Registry System]

7212-44-4(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi,N
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 3082 9 / PGIII
[WGK Germany ]

2
[RTECS ]

JR4977000
[F ]

10-23
[Autoignition Temperature]

230 °C
[TSCA ]

Yes
[HS Code ]

29052290
[Toxicity]

LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 5000 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Neroli oil-->Peru balsam-->Orange sweet oil
[Preparation Products]

FARNESOL-->Cyclohexene, 1-methyl-4-(5-methyl-1-methylene-4-hexen-1-yl)--->2Z,6Z-Farnesol
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Nerolidol(7212-44-4).msds
Questions And AnswerBack Directory
[Description]

Nerolidol occurs naturally including the essential oil of neroli, ylang-ylang, and Peru balsam. It has a faint, fresh, unusually sweet, tenacious, floral odor similar to rose and apple. It can be used as a flavor ingredient in foods, such as baked goods, frozen dairy, nonalcoholic beverages, and soft candy. It is also used as fragrance in the perfumery.
[References]

[1] George A. Burdock, Fenaroli's Handbook of Flavor Ingredients, 6th Edition, 2010
Hazard InformationBack Directory
[Chemical Properties]

Clear slightly yellow liquid
[Chemical Properties]

Nerolidol has a faint, fresh, unusually sweet, tenacious, floral odor similar to rose and appe
[Chemical Properties]

Nerolidol is the sesquiterpene analog of linalool. Because of the double bond at the 6-position, it exists as (6Z)- and (6E)- isomers, each forming an enantiomeric pair, since the carbon atom in the 3-position is asymmetric. Nerolidol is a component of many essential oils. (3S,6E)-(+)-nerolidol occurs in cabreuva oil.
Synthetic nerolidol consists of a mixture of racemic (6Z)- and (6E)-nerolidol and is a colorless liquid with a long-lasting, mild floral odor. Industrial synthesis of nerolidol starts with linalool, which is converted into geranylacetone by using diketene, ethyl acetoacetate, or isopropenyl methyl ether, analogously to the synthesis of 6-methyl-5-hepten-2-one from 2-methyl- 3-buten-2-ol. Addition of acetylene and partial hydrogenation of the resultant dehydronerolidol produces a mixture of (6Z)- and (6E)-nerolidol racemates.Nerolidol is used as a base note in many delicate floral odor complexes. It is also an intermediate in the production of vitamins E and K1.
[Occurrence]

Reported found in over 25 natural sources, including the essential oils of neroli, ylang-ylang, Peru balsam; in currant aroma; also reported in Dalbergia sissoo (60%, dl-), vervain, the distillation water of petitgrain bigarade, Helicrysum italicum, Myrocarpus frondosus and Myrocarpus fastigiatus (80%, d-), Tolu balsam, Acacia farnesiana, orange flower water, Paraguay petitgrain, jasmine, Melaleuca smithii and Melaleuca viridiflora. Also reported found in citrus peel oils and juices, guava, strawberry, peppermint and spearmint oil, pepper, milk powder, hop oil, beer, cognac, white wine, green tea, beans, mushroom, cardamom, rice, dill, corn oil, basil, wort, myrtle leaf, maté and mastic gum oil.
[Uses]

anti-ulcer, insect antifeedant
[Uses]

Nerolidol is one of the main component in the essential oils from fresh aerial parts of Thymus ciliatus (Lamiaceae). Also, it is a terpene that displays high potency on the contractility of cardiac muscle in guinea pig left atrium. A potential and effective treatment for malaria.
[Definition]

ChEBI: Nerolidol is a farnesane sesquiterpenoid that is dodeca-1,6,10-triene which carries methyl groups at positions 3, 7 and 11 and a hydroxy group at position 3. It is a natural product that is present in various flowers and plants with a floral odor. Chemically, it exists in two geometric isomers, trans and cis forms. It is widely used in cosmetics (e.g. shampoos and perfumes), in non-cosmetic products (e.g. detergents and cleansers) and also as a food flavoring agent. It has a role as a flavouring agent, a cosmetic, a pheromone, a neuroprotective agent, an antifungal agent, an anti-inflammatory agent, an antihypertensive agent, an antioxidant, a volatile oil component, an insect attractant and a herbicide. It is a farnesane sesquiterpenoid, a tertiary allylic alcohol and a volatile organic compound.
[Preparation]

1) From Geranylacetone plus Acetylene, followed by reduction of the acetylenic linkage (HotTmann-laRoche process).
2) by isolation from Cabreuva oil or other essential oils.
[Aroma threshold values]

Detection: 10 ppb to 10 ppm
[Taste threshold values]

Taste characteristics at 25 ppm: green, floral, woody with fruity, citrus and melon nuances
[General Description]

Nerolidol is a naturally occurring sesquiterpene found in the essential oils.
[Flammability and Explosibility]

Nonflammable
[Synthesis]

The natural product can be dextro- or levorotatory, whereas the synthetic product is optically inactive; the double bond at position 6 to 7 accounts for the cis- and trans-forms.
[storage]

Store at -20°C
Spectrum DetailBack Directory
[Spectrum Detail]

Nerolidol(7212-44-4)MS
Nerolidol(7212-44-4)1HNMR
Nerolidol(7212-44-4)IR1
Nerolidol(7212-44-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

3-Hydroxy-3,7,11-trimethyl-1,6,10-dodecatriene, 97+% (total alcohols)(7212-44-4)
[Alfa Aesar]

Nerolidol, cis + trans, 97+%(7212-44-4)
[Sigma Aldrich]

7212-44-4(sigmaaldrich)
[TCI AMERICA]

Nerolidol  (cis-and trans-mixture),>97.0%(GC)(7212-44-4)
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