Identification | More | [Name]
1,2-Diacetylbenzene | [CAS]
704-00-7 | [Synonyms]
1,2-DIACETYLBENZENE 2-ACETYLACETOPHENONE TIMTEC-BB SBB008490 1,1’-(1,2-phenylene)bis-ethanon 1,1’-(1,2-phenylene)bisethanone o-diacetyl-benzen benzene-1,2-bis(acetyl) 1,2-DIACETYLBENZENE, FOR FLUORESCENCE Ethanone, 1,1-(1,2-phenylene)bis- 1-(2-Acetylphenyl)ethanone | [EINECS(EC#)]
211-877-6 | [Molecular Formula]
C10H10O2 | [MDL Number]
MFCD00008733 | [Molecular Weight]
162.19 | [MOL File]
704-00-7.mol |
Chemical Properties | Back Directory | [Appearance]
yellow to light brown crystalline powder | [Melting point ]
39-41 °C (lit.) | [Boiling point ]
110 °C/0.1 mmHg (lit.) | [density ]
1.0613 (rough estimate) | [refractive index ]
1.5782 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
2-8°C | [solubility ]
dichloromethane: soluble50mg/mL, clear, colorless to yellow | [BRN ]
1862907 | [CAS DataBase Reference]
704-00-7(CAS DataBase Reference) |
Safety Data | Back Directory | [Safety Statements ]
S22:Do not breathe dust . S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [RTECS ]
KM5782637
| [F ]
8 | [HS Code ]
29143900 |
Hazard Information | Back Directory | [Chemical Properties]
yellow to light brown crystalline powder | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 40, p. 262, 1975 DOI: 10.1021/jo00890a029 | [General Description]
1,2-Diacetylbenzene, an aromatic hydrocarbon, is a protein-reactive γ-diketone metabolite of the neurotoxic solvent 1,2-diethylbenzene. | [Purification Methods]
Purify it by distilling and by recrystallising from pet ether. The bis-2,4-dinitrophenylhydrazone has m 221o (dec). [Halford & Weissmann J Org Chem 17 1646 1952, Riemschneider & Kassahn Chem Ber 92 1705 1959,[Beilstein 7 III 3501, 7 IV 2155.] |
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