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ChemicalBook--->CAS DataBase List--->677-22-5

677-22-5

677-22-5 Structure

677-22-5 Structure
IdentificationMore
[Name]

TERT-BUTYLMAGNESIUM CHLORIDE
[CAS]

677-22-5
[Synonyms]

T-BUTYLMAGNESIUM CHLORIDE
TERT-BUTYLMAGNESIUM CHLORIDE
TERT-BUTYLMAGNESIUM CHLORIDE 2.0M &
TERT-BUTYLMAGNESIUM CHLORIDE, 1.0M SOLUT ION IN TETRAHYDROFURAN
TERT-BUTYLMAGNESIUM CHLORIDE, 2.0M SOLUT ION IN DIETHYL ETHER
TERT-BUTYLMAGNESIUM CHLORIDE SOLUTION, ~1 M IN THF
TERT-BUTYLMAGNESIUM CHLORIDE SOLUTION,~2 M IN DIETHYL ETH.
TERT-BUTYLMAGNESIUM CHLORIDE SOLUTION,~20% IN THF
t-Butylmagnesium Chloride 1.0 M In Butyl Diglyme
t-Butylmagnesium Chloride 1.0 M In Tetrahydrofuran
solution~1MinTHF
tert-Butylmagnesium chloride, 1,7M solution in diethyl ether
tert-Butylmagnesium chloride, 1.7M solution in THF
tert-BUTYL MAGNESIUM CHLORIDE, 1 M in TETRAHYDROFURAN
Magnesium, chloro(1,1-dimethylethyl)-
tert-butylmagnesium chloride solution
TERT-BUTYLMAGNESIUM CHLORIDE: (26% IN ETHYL ETHER, CA. 2MOL/L)
TERT-BUTYLMAGNESIUM CHLORIDE: (26% IN TETRAHYDROFURAN, CA. 2MOL/L
tert-Butylmagnesium Chloride (23% in Tetrahydrofuran, ca. 2mol/L)
tert-Butylmagnesium chloride1.7M solution in THFAcroSeal§3
[EINECS(EC#)]

211-638-6
[Molecular Formula]

C4H9ClMg
[MDL Number]

MFCD00000465
[Molecular Weight]

116.87
[MOL File]

677-22-5.mol
Chemical PropertiesBack Directory
[Appearance]

clear faint grey to grey, grey-brown or light
[Melting point ]

-108℃ (Tetrahydrofuran)
[density ]

0.931 g/mL at 25 °C
[Fp ]

34 °F
[storage temp. ]

2-8°C
[form ]

Liquid
[color ]

Clear brown to dark brown
[Water Solubility ]

Miscible with alcohol and water.
[Sensitive ]

Air & Moisture Sensitive
[Detection Methods]

TITR
[BRN ]

3535403
[InChIKey]

ZDRJSYVHDMFHSC-UHFFFAOYSA-M
[CAS DataBase Reference]

677-22-5(CAS DataBase Reference)
[Storage Precautions]

Store under nitrogen
Safety DataBack Directory
[Hazard Codes ]

F+,C,F
[Risk Statements ]

R12:Extremely Flammable.
R14/15:Reacts violently with water, liberating extremely flammable gases .
R19:May form explosive peroxides.
R22:Harmful if swallowed.
R34:Causes burns.
R66:Repeated exposure may cause skin dryness or cracking.
R67:Vapors may cause drowsiness and dizziness.
R15:Contact with water liberates extremely flammable gases.
R11:Highly Flammable.
R14:Reacts violently with water.
[Safety Statements ]

S9:Keep container in a well-ventilated place .
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S29:Do not empty into drains .
S33:Take precautionary measures against static discharges .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3399 4.3/PG 1
[WGK Germany ]

1
[F ]

1-3-10
[HazardClass ]

4.3
[PackingGroup ]

I
[HS Code ]

29319090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Tetrahydrofuran-->Magnesium-->2-Chloro-2-methylpropane
[Preparation Products]

4-tert-Butylcyclohexanol-->2-Propanesulfinic acid,2-methyl--->2,2-DIMETHYL-1-BUTANOL-->N-tert-butylhydroxylamine-->2,2-DIMETHYL-3-HEXANOL-->2,2-DIMETHYL-3-HEXANONE-->DI-TERT-BUTYLPHENYLPHOSPHINE-->Pinacolone
Hazard InformationBack Directory
[Chemical Properties]

clear faint grey to grey, grey-brown or light
[Uses]

tert-Butylmagnesium chloride is a Grignard reagent used in organic synthesis. It is also involved in copper-catalyzed cross-coupling reaction with primary-alkyl halides.
[General Description]

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks" and "Inherently Safer Chemistry for Accident Prevention". Find details here.
Spectrum DetailBack Directory
[Spectrum Detail]

TERT-BUTYLMAGNESIUM CHLORIDE(677-22-5)ESR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

tert-Butylmagnesium chloride, 2.0M solution in diethyl ether(677-22-5)
[Sigma Aldrich]

677-22-5(sigmaaldrich)
[TCI AMERICA]

tert-Butylmagnesium Chloride  (26% in Ethyl Ether, ca. 2mol/L)(677-22-5)
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