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ChemicalBook--->CAS DataBase List--->2246-46-0

2246-46-0

2246-46-0 Structure

2246-46-0 Structure
IdentificationMore
[Name]

4-(2-THIAZOLYLAZO)RESORCINOL
[CAS]

2246-46-0
[Synonyms]

2-(2,4-DIHYDROXYPHENYLAZO)THIAZOLE
4-(2-THIAZOLYLAZO)RESORCINOL
4-(2-THIAZOYLAZO)RESORCINOL
TAR
3-Benzenediol,4-(2-thiazolylazo)-1
4-(2-thiazolylazo)-3-benzenediol
4-(thiazol-2-ylazo)resorcinol
TAR [=4-(2-Thiazolylazo)resorcinol] [Metal indicator and spectrophotometric reagent for transition metals]
2-(2,4-Dihydroxyphenylazo)thiazole, TAR
4-(2-Thiazolylazo)-1,3-benzenediol
4-(Thiazole-2-ylazo)resorcinol
[EINECS(EC#)]

218-836-1
[Molecular Formula]

C9H7N3O2S
[MDL Number]

MFCD00005322
[Molecular Weight]

221.24
[MOL File]

2246-46-0.mol
Chemical PropertiesBack Directory
[Melting point ]

211 °C (dec.)(lit.)
[Boiling point ]

434.5±38.0 °C(Predicted)
[density ]

1.53±0.1 g/cm3(Predicted)
[solubility ]

almost transparency in hot EtOH50vol%
[form ]

powder to crystal
[pka]

7.99±0.35(Predicted)
[color ]

Light yellow to Brown
[BRN ]

204257
[Dielectric constant]

4.0(Ambient)
[Uses]

Used in treatment of psoriasis.
[CAS DataBase Reference]

2246-46-0(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[HS Code ]

2934.10.2000
Questions And AnswerBack Directory
[Description]

A dark, viscous,usually pungent substance, tar is derived from the destructive distillation of various organic compounds such as wood,coal, or shale,that is used for various industrial purposes.
Spectrum DetailBack Directory
[Spectrum Detail]

4-(2-THIAZOLYLAZO)RESORCINOL(2246-46-0)MS
4-(2-THIAZOLYLAZO)RESORCINOL(2246-46-0)1HNMR
4-(2-THIAZOLYLAZO)RESORCINOL(2246-46-0)13CNMR
4-(2-THIAZOLYLAZO)RESORCINOL(2246-46-0)IR1
4-(2-THIAZOLYLAZO)RESORCINOL(2246-46-0)IR2
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

4-(2-Thiazolylazo)resorcinol, 97%(2246-46-0)
[Sigma Aldrich]

2246-46-0(sigmaaldrich)
[TCI AMERICA]

TAR  [=4-(2-Thiazolylazo)resorcinol] [Metal indicator and spectrophotometric reagent for transition metals],>99.0%(T)(2246-46-0)
Hazard InformationBack Directory
[Purification Methods]

Dissolve it in aqueous alkali, extract it with diethyl ether, and re-precipitate it with dilute HCl. The purity is checked by TLC on silica gel using pet ether/diethyl ether/EtOH (10:10:1) as the mobile phase. It complexes with Cu2+ (pH 3-4), Co2+ and Ni2+ (pH 7) and Zn2+ , andCd2+ (pH 8.4). [Beilstein 27 III/IV 5988.]
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