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ChemicalBook--->CAS DataBase List--->74-39-5

74-39-5

74-39-5 Structure

74-39-5 Structure
IdentificationMore
[Name]

4-(4-NITROPHENYLAZO)RESORCINOL
[CAS]

74-39-5
[Synonyms]

4-(4'-NITROPHENYLAZO)-RESORCINOL
4-(4-NITROPHENYLAZO)RESORCINOL
4-(P-NITROBENZENEAZO)RESORCINOL
4-(P-NITROPHENYLAZO)ORCINOL
4-(P-NITROPHENYLAZO)RESORCINOL
AZO VIOLET
AZOVIOLET BENZENE
LABOTEST-BB LT00455004
MAGNESON
MAGNESON I
P-NITROBENZENEAZORESORCINOL
TIMTEC-BB SBB008851
1,3-Benzenediol,4-[(4-nitrophenyl)azo]-
3-Benzenediol,4-[(4-nitrophenyl)azo]-1
4-((4-nitrophenyl)azo)-3-benzenediol
4-((p-nitrophenyl)azo)-resorcino
4-[(4-Nitrophenyl)azo]-1,3-benzenediol
4-[(4-nitrophenyl)azo]-3-benzenediol
p-diazviolet
MagnesonⅠ
[EINECS(EC#)]

200-808-5
[Molecular Formula]

C12H9N3O4
[MDL Number]

MFCD00007310
[Molecular Weight]

259.22
[MOL File]

74-39-5.mol
Questions And AnswerBack Directory
[Description]

Oxygen violet can be prepared by one-step reaction of p-nitroaniline and 1,3-benzenediol. Azo violet can be used to prepare an azobenzene photochromic liquid crystal compound. Photochromic liquid crystal compounds have both photochromic properties and liquid crystallinity, which has become a research hotspot in the field of information storage. Azobenzene-based liquid crystals are the most interesting photochromic liquid crystal materials in recent years due to their unique photoinduced cis-trans isomerism. Azobenzene compounds undergo reversible cis-trans isomerization under the action of light, which makes them have great potential applications in many aspects such as optical storage, photo-holography and optical information processing.
Chemical PropertiesBack Directory
[Appearance]

dark red to brown crystalline powder
[Melting point ]

195-200 °C (dec.)(lit.)
[Boiling point ]

402.47°C (rough estimate)
[density ]

1.3450 (rough estimate)
[refractive index ]

1.5700 (estimate)
[storage temp. ]

Store below +30°C.
[form ]

Powder
[pka]

8.05±0.35(Predicted)
[color ]

Orange-red to red
[Odor]

Odorless
[Stability:]

Stable. Incompatible with strong oxidizing agents, strong bases.
[Water Solubility ]

Soluble in dilute sodium hydroxide. Insoluble in water.
[Merck ]

14,5695
[BRN ]

674709
[CAS DataBase Reference]

74-39-5(CAS DataBase Reference)
[EPA Substance Registry System]

1,3-Benzenediol, 4-[(4-nitrophenyl)azo]- (74-39-5)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/38:Irritating to eyes and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[RTECS ]

VH2810000
[TSCA ]

Yes
[HS Code ]

29270000
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Resorcinol-->N-Methyl-4-nitroaniline
Hazard InformationBack Directory
[Chemical Properties]

dark red to brown crystalline powder
[Uses]

4-(4-Nitrophenyl)azoresorcinol  is used for the detection of magnesium with which it yields a bright blue color in alkaline solution and it also used to determine molybdenum with which it forms a red-violet complex: Nikitina, Andrianova, C.A. 75, 136789v (1971).
[Uses]

It is a derivitized resorcinol dye compound with an absorption maximum of 432 nm. Used as a pH indicator.
[Definition]

ChEBI: An azobenzene in which the phenyl rings are 4-nitro- and 2,4-dihydroxy-substituted respectively.
[Biochem/physiol Actions]

4-(4-Nitrophenylazo)resorcinol is a pH indicator.
[Purification Methods]

Crystallise the dye from EtOH. [Beilstein 16 H 181, 16 IV 1266.]
Spectrum DetailBack Directory
[Spectrum Detail]

4-(4-Nitrophenyl)azoresorcinol(74-39-5)MS
4-(4-Nitrophenyl)azoresorcinol(74-39-5)1HNMR
4-(4-Nitrophenyl)azoresorcinol(74-39-5)13CNMR
4-(4-Nitrophenyl)azoresorcinol(74-39-5)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4-(4-Nitrophenylazo)resorcinol, dye content ca 90%(74-39-5)
[Alfa Aesar]

4-(4-Nitrophenylazo)resorcinol, 96%(74-39-5)
[Sigma Aldrich]

74-39-5(sigmaaldrich)
[TCI AMERICA]

Magneson(74-39-5)
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