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ChemicalBook--->CAS DataBase List--->212143-23-2

212143-23-2

212143-23-2 Structure

212143-23-2 Structure
IdentificationBack Directory
[Name]

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)
[CAS]

212143-23-2
[Synonyms]

RuCl2[(R)-binap][(R
Dichloro[(R)-(+)-2,2-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
DICHLORO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II)
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)
Dichloro[(r)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1r,2r)-(+)-1,2-diphenylethylenediamine]ruthenium(ii)min
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II),min.90%
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediaMine]rutheniuM(II),RuCl2[(R)-binap][(R,R)-dpen]
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediaMine]rutheniuM(II),90% RuCl2[(R)-binap][(R,R)-dpen]
Ruthenium,[1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]dichloro[(1R,2R)-1,2-diphenyl-1,2-ethanediamine-kN1,kN2]-, (OC-6-13)-
[Molecular Formula]

C58H48Cl2N2P2Ru
[MDL Number]

MFCD02684565
[MOL File]

212143-23-2.mol
[Molecular Weight]

1006.94
Chemical PropertiesBack Directory
[Melting point ]

>100°C
[storage temp. ]

?20°C
[form ]

Powder
[color ]

white to pale yellow
[Sensitive ]

air sensitive, store cold
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

  1. Sequential asymmetric hydrogenation reactions with solution or polymer-bound BINAP/Diamine complexes.
  2. Asymmetic hydrogenation of imines.
  3. Catalysts for deracemization of benzylic alcohols. 
Reactions of 212143-23-2
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