| Identification | Back Directory | [Name]
Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II), 98% | [CAS]
12131-44-1 | [Synonyms]
Cinnamylpalladium chloride dimer
BIS[CINNAMYL PALLADIUM(II) CHLORIDE]
PalladiuM(II)(π-cinnaMyl) Chloride DiMer
PalladiuM(pi-cinnaMyl) chloride diMer 97%
PalladiuM(II)(pi-cinnaMyl) Chloride DiMer
Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladium(Ⅱ)
Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propen-1-yl]dipalladium
Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II), 98%
Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladiuM(II),98% | [EINECS(EC#)]
234-579-8 | [Molecular Formula]
[(C9H9)ClPd]2 | [MDL Number]
MFCD16621470 | [MOL File]
12131-44-1.mol | [Molecular Weight]
512.03 |
| Questions And Answer | Back Directory | [Application]
Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(ii) is an important organic regant for the use of transition-metal-mediated organic syntheses. It can be used as a catalyst for the ammonia cross-coupling reactions to synthesize arylamines and conversion of aryl triflates to fluorides.
| [Reaction]
- Precursor for the preparation of a palladium catalyst used in the carbonylative arylation of ketones, yielding vinylbenzoate compounds.
- Precursor for the preparation of a palladium catalyst used in the Buchwald-Hartwig amination of (hetero)aryl chlorides.
- Precursor for the preparation of a palladium catalyst used in the arylative dearomatization of phenols.
- Versatile palladium precursor for the preparation of palladium catalysts used in the cross-coupling of aryl chlorides and amines , conversion of aryl triflates to aryl fluorides , and the α-arylation of aldehydes .
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| Hazard Information | Back Directory | [Uses]
Palladium(π-cinnamyl) chloride dimer can be used as a catalyst for the:
- Ammonia cross-coupling reactions to synthesize arylamines.
- Conversion of aryl triflates to fluorides.
It can also be used as a source of palladium in the asymmetric α-arylation of amides. | [reaction suitability]
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst |
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