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ChemicalBook--->CAS DataBase List--->127593-28-6

127593-28-6

127593-28-6 Structure

127593-28-6 Structure
IdentificationBack Directory
[Name]

[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE
[CAS]

127593-28-6
[Synonyms]

-binaphthyl]palladium(II)
Dichloro[(S)-(−
Dichloro[(S)-()-2,2′-bis(dip
-bis(diphenylphosphino)-1,1′
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYLPALLADIUM(II) CHLORIDE
[(S)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)
((S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium
Dichloro[(S)-()-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]palladiuM(II)
[(S)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE
Dichloro[(S)-(-)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]palladiuM(II)
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladiuM(II),Min.98%
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%
REF DUPL: [(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium (II) chloride
Palladium,[(1S)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine-kP]]dichloro-, (SP-4-2)-
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladiuM(II),98% (S-BINAP)PdCl2
PALLADIUM, [(1S)-[1,1''-BINAPHTHALENE]-2,2''-DIYLBIS[DIPHENYLPHOSPHINE-.KAPPA.P]]DICHLORO-, (SP-4-2)-
[EINECS(EC#)]

1312995-182-4
[Molecular Formula]

C44H32Cl2P2Pd
[MDL Number]

MFCD00075254
[MOL File]

127593-28-6.mol
[Molecular Weight]

800
Chemical PropertiesBack Directory
[Melting point ]

>300°C
[storage temp. ]

Inert atmosphere,2-8°C
[InChIKey]

VDHAUMFISVWIRX-UHFFFAOYSA-L
[CAS DataBase Reference]

127593-28-6
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H312-H315-H319-H332-H335
[Precautionary statements ]

P261-P280-P305+P351+P338
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22-36/37/38
[Safety Statements ]

26-37/39
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

  1. Catalyst precursor, with AgBF4 , for the enantioselective addition of silyl ethers, to imines to produce β-amino ketones, and to aldehydes to produce 3-hydroxy-1-propanone aldol addition products.
  2. Catalyst precursor, with AgSbF6, for the asymmetric carbonyl-ene reaction.
  3. Catalyst precursor for hetero Diels-Alder reaction of simple dienes with aldehydes and aryl glyoxals.
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