| Identification | More | [Name]
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE | [CAS]
13209-15-9 | [Synonyms]
1,2-BIS(DIBROMOMETHYL)BENZENE
A,A,A',A'-TETRABROMO-O-XYLENE
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-2-XYLENE
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE
ALPHA,ALPHA,BETA,BETA-TETRABROMO-O-XYLENE
O-XYLYLENE TETRABROMIDE
1,2-bis(dibromomethyl)-benzen
Benzene,1,2-bis(dibromomethyl)-
2-(m-Aminobenzenesulfamido)-6,8-Disulfonic Acid
ALPHA ALPHA ALPHA' ALPHA'-TETRABROMO-O-&
a,a,a,a-Tertabromo-O-Xylene
à,à,à',à'-tetrabromo-o-xylene
AAAATETRABROMOORTHOXYLENE
ɑ,ɑ,ɑ',ɑ'-Tetrabromo-o-xylene, 97%
1,2-Phenylenebis(dibromomethane) | [EINECS(EC#)]
236-176-2 | [Molecular Formula]
C8H6Br4 | [MDL Number]
MFCD00000131 | [Molecular Weight]
421.75 | [MOL File]
13209-15-9.mol |
| Chemical Properties | Back Directory | [Appearance]
OFF-WHITE TO GREY CRYSTALLINE POWDER | [Melting point ]
114-116 °C(lit.) | [Boiling point ]
303.01°C (rough estimate) | [density ]
2.2654 (rough estimate) | [refractive index ]
1.7040 (estimate) | [storage temp. ]
Store below +30°C. | [form ]
Liquid or Low Melting Solid | [color ]
Clear colorless to yellow | [Water Solubility ]
Insoluble | [BRN ]
2211698 | [InChI]
InChI=1S/C8H6Br4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4,7-8H | [InChIKey]
LNAOKZKISWEZNY-UHFFFAOYSA-N | [SMILES]
C1(C(Br)Br)=CC=CC=C1C(Br)Br | [CAS DataBase Reference]
13209-15-9(CAS DataBase Reference) | [EPA Substance Registry System]
13209-15-9(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns.
R36/37:Irritating to eyes and respiratory system . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
19-21 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29039990 |
| Hazard Information | Back Directory | [Chemical Properties]
OFF-WHITE TO GREY CRYSTALLINE POWDER | [Uses]
α,α,α′,α′-Tetrabromo-o-xylene can be employed as a precursor for the synthesis of:
- Poly(o-phenylene vinylene) (o-PPV) via electrochemical polymerization.
- A pentacene derivative by reacting with naphthalene moieties for the development of organic thin-film transistors (OTFTs).
- Bitopic pyrazole containing ligands.
| [Uses]
α,α,α',α'-Tetrabromo-o-xylene reacts with 5endo,6endo-bis-chlormethyl-norborn-2-en to obtain trans/cis-2,3-bis(chloromethyl)-1,4-methano-1,2,3,4-tetrahydroanthracene. Further, it is involved in the preparation of 1-(3-butenyl)-2-(deuteriomethyl)benzene by reacting with allylmagnesium bromide. In addition this, it is used to prepare exo-benzocyclobuteno-1,2,3,4-tetrahydro-1,4-methanoanthracene by reacting with exo-1,4,4a,8b-tetrahydro-1,4-methanobiphenylene. |
| Spectrum Detail | Back Directory | [Spectrum Detail]
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE(13209-15-9)MS
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE(13209-15-9)1HNMR
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE(13209-15-9)13CNMR
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE(13209-15-9)IR1
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE(13209-15-9)IR2
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE(13209-15-9)IR3
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE(13209-15-9)Raman
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