Identification | More | [Name]
1-Methylpiperazine | [CAS]
109-01-3 | [Synonyms]
1-METHYLPIPERAZINE AKOS BBS-00003665 LABOTEST-BB LTBB000517 methylpiperazine METHYLPIPERAZINE-N N-METHYLPIPERAZINE NMPRZ 1-methyl-piperazin Piperazine,1-methyl- 1-METHYLPIPERAZINE, STANDARD FOR GC N-MethylPiperazineForSynthesis N-EthylPiperazineForSynthesis N-Methylpiperazine, 98+% 1-Methylpiperazine, 99+% N-Methylpiperazin n-METHYL PIPERAZINE extrapure 1-Methylpiperazine, 98+% 4-Methylpiperazine | [EINECS(EC#)]
203-639-5 | [Molecular Formula]
C5H12N2 | [MDL Number]
MFCD00005966 | [Molecular Weight]
100.16 | [MOL File]
109-01-3.mol |
Chemical Properties | Back Directory | [Appearance]
clear liquid | [Melting point ]
-6 °C
| [Boiling point ]
138 °C(lit.)
| [density ]
0.903 g/mL at 25 °C(lit.)
| [vapor density ]
3.5 (vs air)
| [vapor pressure ]
12 hPa (20 °C) | [refractive index ]
n20/D 1.466(lit.)
| [Fp ]
108 °F
| [storage temp. ]
Store under Nitrogen | [solubility ]
Chloroform (Soluble), Methanol (Soluble) | [form ]
Liquid | [pka]
pK1:4.94(+2);pK2:9.09(+1) (25°C,μ=0.1) | [color ]
Clear | [Specific Gravity]
0.903 | [PH]
11-12 (50g/l, H2O, 20℃) | [explosive limit]
1.2-9.9%(V) | [Water Solubility ]
soluble | [Sensitive ]
Hygroscopic | [Detection Methods]
GC,NMR | [BRN ]
102724 | [InChIKey]
PVOAHINGSUIXLS-UHFFFAOYSA-N | [LogP]
-0.57 at 25℃ | [CAS DataBase Reference]
109-01-3(CAS DataBase Reference) | [NIST Chemistry Reference]
Piperazine, 1-methyl-(109-01-3) | [Storage Precautions]
Moisture sensitive;Heat sensitive | [EPA Substance Registry System]
109-01-3(EPA Substance) |
Safety Data | Back Directory | [Hazard Codes ]
T,F,C,Xi | [Risk Statements ]
R10:Flammable. R21:Harmful in contact with skin. R23:Toxic by inhalation. R34:Causes burns. R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S36:Wear suitable protective clothing . | [RIDADR ]
UN 2734 8/PG 2
| [WGK Germany ]
2
| [RTECS ]
TM1225000
| [Autoignition Temperature]
320 °C | [Hazard Note ]
Flammable/Toxic/Corrosive/Store under nitrogen | [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29335995 | [Safety Profile]
Poison by
intraperitoneal route. Moderately toxic by
inhalation, ingestion, and skin contact. A
severe skin and eye irritant. Flammable
liquid when exposed to heat or flame; can
react with oxidizing materials. To fight fire,
use alcohol foam, CO2, dry chemical. When
heated to decomposition it emits toxic
fumes of NOx. | [Toxicity]
LD50 orally in Rabbit: 2547 mg/kg LD50 dermal Rabbit 1341 mg/kg |
Hazard Information | Back Directory | [Hazard]
Moderate fire risk. | [Chemical Properties]
clear liquid | [Uses]
1-Methylpiperazine is used in the preparation of 2-(4-Methyl-1-piperazinylmethyl)acrylophenone(MPMAP) | [Definition]
ChEBI: 1-Methylpiperazine is a N-methylpiperazine. | [Flammability and Explosibility]
Flammable |
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