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ChemicalBook CAS DataBase List Cuprous iodide
7681-65-4

Cuprous iodide synthesis

4synthesis methods
-

Yield:-

Reaction Conditions:

in methanol; for 0.25 h;Cooling with ice;

Steps:

2.2.2.3. Synthesis of [Cu(L)I] (6).

For the synthesis of this complex, asolution of CuNO3.5H2O (0.246 g, 1 mmol) in 10 mL of methanol and a solution of NaI (0.1525 g, 1 mmol) in 10 mL of methanol were mixed and boiled for 15 min and then chilled in ice. The precipitated CuI was filtered and CuI was treated with a solution of thiosemicarbazone, HL (0.284 g, 1 mmol) in 10 mL hot methanoland refluxed for 4 h and cooled. The dark green shining crystals formed were filtered, washed with few drops of methanol andether and dried over P4O10 in vacuo.

References:

Jayakumar;Sithambaresan;Aravindakshan, A. Ambili;Kurup, M.R. Prathapachandra [Polyhedron,2014,vol. 75,p. 50 - 56]

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