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ChemicalBook >> CAS DataBase List >> Dess-Martin periodinane

Dess-Martin periodinane

Dess-Martin periodinane price.
  • $10.64 - $2390
  • Product name: Dess-Martin periodinane
  • CAS: 87413-09-0
  • MF: C13H13IO8
  • MW: 424.14
  • EINECS:672-328-8
  • MDL Number:MFCD00130127
  • Synonyms:1,1,1-Triacetoxy-1,3-dihydro-3-oxo-1,2-benziodoxole-IV;1,1-Dihydro-1,1,1-triacetoxy-1,2-benzoiodooxol-3(1H)-one (Dess-M;Dess-Martin periodinane solution;Dess-Martin periodinane,1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one;Acetic acid, 1,1',1''-(3-oxo-1.lambda.5-1,2-benziodoxol-1(3H)-ylidyne) ester;Dess-Martin periodinane, 15 wt.% solution in dichloromethane, AcroSeal;1,1-dihydro-1,1,1-triacetoxy-1,2-benziodoxol-3(1H)-one;1,1,1-Triacetoxy-1,2-benziodoxol-3(1H)-one(Dess-Martin periodinane)
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Brand
  • AHH
  • AK Scientific
  • Alfa Aesar
  • Alichem
  • Atlantic Research Chemicals
  • Azepine
  • Biosynth Carbosynth
  • BroadPharm
  • Chemenu
  • Chem-Impex
  • ChemSupplyAustralia
  • Iris Biotech GmbH
  • JR MediChem
  • Matrix Scientific
  • Medical Isotopes, Inc.
  • Oakwood
  • Sigma-Aldrich
  • TCI Chemical
  • TRC
Package
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  • 25G
  • 50g
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  • 100g
  • 250ML
  • 250g
  • 500g
  • 1kg
  • 1000g
  • 1gm:
  • ManufacturerAHH
  • Product numberMT-07642
  • Product descriptionDess-Martin Periodinane 97%
  • Packaging100g
  • Price$378
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberB193
  • Product descriptionDess-Martin Periodinane
  • Packaging10g
  • Price$25
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberL15779
  • Product descriptionDess-Martin periodinane
  • Packaging1g
  • Price$39.3
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberL15779
  • Product descriptionDess-Martin periodinane
  • Packaging5g
  • Price$132
  • Updated2024-03-01
  • Buy
  • ManufacturerAlichem
  • Product number87413090
  • Product description(1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one
  • Packaging250g
  • Price$367.2
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number87413090
  • Product description(1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one
  • Packaging1000g
  • Price$832.02
  • Updated2021-12-16
  • Buy
  • ManufacturerAtlantic Research Chemicals
  • Product numberXS10028
  • Product description1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3-(1H)-one(Dess-MartinPeriodinane) 95%
  • Packaging1gm:
  • Price$14.14
  • Updated2021-12-16
  • Buy
  • ManufacturerAzepine
  • Product numberAZ0001-0494
  • Product descriptionDess-Martin Periodinane 98
  • Packaging5G
  • Price$19
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFD10776
  • Product descriptionDess-Martin periodinane
  • Packaging50g
  • Price$65
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFD10776
  • Product descriptionDess-Martin periodinane
  • Packaging100g
  • Price$115
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD10776
  • Product descriptionDess-Martin periodinane
  • Packaging250g
  • Price$250
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD10776
  • Product descriptionDess-Martin periodinane
  • Packaging500g
  • Price$450
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD10776
  • Product descriptionDess-Martin periodinane
  • Packaging1kg
  • Price$800
  • Updated2021-12-16
  • Buy
  • ManufacturerBroadPharm
  • Product numberBP-20360
  • Product descriptionDess-Martin Periodinane 97%
  • Packaging5G
  • Price$55
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM101881
  • Product description3-oxo-1l5-benzo[d][1,2]iodaoxole-1,1,1(3H)-triyltriacetate 98%
  • Packaging500g
  • Price$309
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number14504
  • Product description1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one,98%(Assaybytitration) 98%(Assaybytitration)
  • Packaging1G
  • Price$10.64
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AHH MT-07642 Dess-Martin Periodinane 97% 100g $378 2021-12-16 Buy
AK Scientific B193 Dess-Martin Periodinane 10g $25 2021-12-16 Buy
Alfa Aesar L15779 Dess-Martin periodinane 1g $39.3 2024-03-01 Buy
Alfa Aesar L15779 Dess-Martin periodinane 5g $132 2024-03-01 Buy
Alichem 87413090 (1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one 250g $367.2 2021-12-16 Buy
Alichem 87413090 (1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one 1000g $832.02 2021-12-16 Buy
Atlantic Research Chemicals XS10028 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3-(1H)-one(Dess-MartinPeriodinane) 95% 1gm: $14.14 2021-12-16 Buy
Azepine AZ0001-0494 Dess-Martin Periodinane 98 5G $19 2021-12-16 Buy
Biosynth Carbosynth FD10776 Dess-Martin periodinane 50g $65 2021-12-16 Buy
Biosynth Carbosynth FD10776 Dess-Martin periodinane 100g $115 2021-12-16 Buy
Biosynth Carbosynth FD10776 Dess-Martin periodinane 250g $250 2021-12-16 Buy
Biosynth Carbosynth FD10776 Dess-Martin periodinane 500g $450 2021-12-16 Buy
Biosynth Carbosynth FD10776 Dess-Martin periodinane 1kg $800 2021-12-16 Buy
BroadPharm BP-20360 Dess-Martin Periodinane 97% 5G $55 2021-12-16 Buy
Chemenu CM101881 3-oxo-1l5-benzo[d][1,2]iodaoxole-1,1,1(3H)-triyltriacetate 98% 500g $309 2021-12-16 Buy
Chem-Impex 14504 1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one,98%(Assaybytitration) 98%(Assaybytitration) 1G $10.64 2021-12-16 Buy

Properties

Melting point :130-133 °C (lit.)
Boiling point :40 °C
Density :1.369 g/mL at 25 °C
Flash point :>221 °F
storage temp. :-20°C
solubility :Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
form :Liquid
color :Colorless to light yellow
Sensitive :Light Sensitive
Merck :14,2933
BRN :4548207
Stability :Light Sensitive
InChI :InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
InChIKey :NKLCNNUWBJBICK-UHFFFAOYSA-N
SMILES :I1(OC(=O)C)(OC(=O)C)(OC(=O)C)OC(=O)C2C=CC=CC1=2
CAS DataBase Reference :87413-09-0(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H272 May intensify fire; oxidizer Oxidising liquids;Oxidising solids Category 2
Category 3		 Danger
Warning		 GHS hazard pictograms P210, P220, P221P280, P370+P378,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220 Keep/Store away from clothing/…/combustible materials.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

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