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Hydrocarbon halides

Hydrocarbon halide, or hydrocarbon for short, refers to the product produced during the process of hydrogen atoms replaced by by halogen (fluorine, chlorine, bromine, iodine) in the hydrocarbon molecules. According to the different hydrocarbon groups, it could be divided into categories like aliphatic halogenated hydrocarbons (including saturated and unsaturated halogenated hydrocarbons), aromatic halogenated hydrocarbons. According to the amount of halogen atoms contained in the molecule, it could be divided into categories like halogenated hydrocarbons, dihalogenated hydrocarbons and polyhalogenated hydrocarbons. Most of the halogenated hydrocarbons are liquid. The proportion of Iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. They are insoluble in water and could be dissolved in any proportion with hydrocarbons, they also could dissolve many other organics. The proportion of Hydrocarbon halide would decreases with the increase of the amount of carbon atoms. When there are the same hydrocarbon groups, the boiling point and the proportion of the halogenated hydrocarbons would increase in the order of chlorinated hydrocarbons, brominated hydrocarbons, and iodinated hydrocarbons. In the isomer, the more branches it gets, the lower boiling point it has. Most of these substances are toxic and can burn. And their combustion properties decrease with the increase of the amount of halogen atoms in the compound. When it comes to storage, fire hazard should be managed in A, B, C three categories according to fire risk indicators. When it catch fire, the gas should be treated by the C class of fire treatment, liquid by B class of fire treatment. Eenough attention should be payed to anti-virus.
The amount of naturally occurring halo hydrocarbons is very small, and the majority of halo hydrocarbons are synthesized by halogenation of alkanes, and compounded by unsaturated hydrocarbons. It also could be compounded during the reaction between alcohol with hydrohalic acid.
The amount of Halohydrocarbons are more isomers than corresponding hydrocarbons. Apart from the carbon isomerism, unsaturated bond position isomerization, cis-trans isomerism and optical isomerism, there are halogen atom isomerizations as well.. when the Halogenated hydrocarbon was named, the hydrocarbon plays a rule as the matrix while halogen atom plays as substituents. The position, number and name of halogen should be lined out before the name of the hydrocarbon. At room temperature, apart from methyl chloride, methyl bromide, ethyl chloride, vinyl chloride and others which are gas in room temperature, the halo hydrocarbon is liquid in general and the highly  halogenated hydrocarbon is solid.
Halohydrocarbons is not dissolvable in water, but soluble in a variety of organic solvents, and can be dissolved in a variety of weak polarity and non-polar organic compounds. So it  is a kind of commonly used solvent. The relative density of iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. The boiling point of halogenated hydrocarbons increases with the increasing atomic amount of halogen atoms. The boiling point of the same series of halogenated hydrocarbons increases with increase of the amount of carbon chain. The more branched the isomer, the lower the boiling point would it have (except from fluorinated alkanes).
The chemical property of halogenated hydrocarbons is much more active than paraffin, so  halogenated hydrocarbons can produce a variety of chemical reactions, and turn them into various types of compounds. It has an important position in organic synthesis. Halo hydrocarbon has been applied widely in many trades, apart from being used as a solvent, it also could be used as refrigerant, extinguishing agent, anesthetics and preservatives.
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Structure Chemical Name CAS MF
5-Bromoacenaphthene 5-Bromoacenaphthene 2051-98-1 C12H9Br
2-Iodobiphenyl 2-Iodobiphenyl 2113-51-1 C12H9I
TRANS-1,4-DICHLORO-2-BUTENE TRANS-1,4-DICHLORO-2-BUTENE 764-41-0 C4H6Cl2
2-Chloro-5-fluorobenzyl bromide 2-Chloro-5-fluorobenzyl bromide 81778-09-8 C7H5BrClF
Tetradecafluorohexane Tetradecafluorohexane 355-42-0 C6F14
1,3-Dibromoadamantane 1,3-Dibromoadamantane 876-53-9 C10H14Br2
4-BROMOPHENETHYL BROMIDE 4-BROMOPHENETHYL BROMIDE 1746-28-7 C8H8Br2
1,2,4-TRIBROMOBENZENE 1,2,4-TRIBROMOBENZENE 615-54-3 C6H3Br3
2-CHLORO-6-FLUOROBENZYL BROMIDE 2-CHLORO-6-FLUOROBENZYL BROMIDE 68220-26-8 C7H5BrClF
2-IODO-9H-FLUORENE 2-IODO-9H-FLUORENE 2523-42-4 C13H9I
1,3-DIBROMOTETRAFLUOROBENZENE 1,3-DIBROMOTETRAFLUOROBENZENE 1559-87-1 C6Br2F4
9-BROMOFLUORENE 9-BROMOFLUORENE 1940-57-4 C13H9Br
1,2-Dibromobutane 1,2-Dibromobutane 533-98-2 C4H8Br2
4,4'-Difluorodiphenylmethane 4,4'-Difluorodiphenylmethane 457-68-1 C13H10F2
2-CHLOROPENTANE 2-CHLOROPENTANE 625-29-6 C5H11Cl
10-BROMO-1-DECENE 10-BROMO-1-DECENE 62871-09-4 C10H19Br
1-CHLOROMETHYL-2-METHYLNAPHTHALENE 1-CHLOROMETHYL-2-METHYLNAPHTHALENE 6626-23-9 C12H11Cl
2-FLUOROPHENETHYL BROMIDE 2-FLUOROPHENETHYL BROMIDE 91319-54-9 C8H8BrF
1-BROMOPENTADECANE 1-BROMOPENTADECANE 629-72-1 C15H31Br
2,3,4,5,6-PENTABROMOTOLUENE 2,3,4,5,6-PENTABROMOTOLUENE 87-83-2 C7H3Br5
2-Chloroanthracene 2-Chloroanthracene 17135-78-3 C14H9Cl
1,1,1-Trichloroethane 1,1,1-Trichloroethane 71-55-6 C2H3Cl3
9-Bromo-9-phenylfluorene 9-Bromo-9-phenylfluorene 55135-66-5 C19H13Br
9-BROMO-1-NONENE 9-BROMO-1-NONENE 89359-54-6 C9H17Br
2,4-BIS(CHLOROMETHYL)MESITYLENE 2,4-BIS(CHLOROMETHYL)MESITYLENE 1585-17-7 C11H14Cl2
2,3,6-TRIFLUOROBENZYL BROMIDE 2,3,6-TRIFLUOROBENZYL BROMIDE 151412-02-1 C7H4BrF3
(S)-1-Bromo-2-methylbutane (S)-1-Bromo-2-methylbutane 534-00-9 C5H11Br
PENTACHLOROETHANE PENTACHLOROETHANE 76-01-7 C2HCl5
2-CHLORO-5-IODOTOLUENE 2-CHLORO-5-IODOTOLUENE 116632-41-8 C7H6ClI
3-FLUORO-4-IODOTOLUENE 3-FLUORO-4-IODOTOLUENE 452-79-9 C7H6FI
beta-Bromostyrene beta-Bromostyrene 103-64-0 C8H7Br
DIBENZOSUBERYL CHLORIDE DIBENZOSUBERYL CHLORIDE 1210-33-9 C15H13Cl
Triphenylmethyl bromide Triphenylmethyl bromide 596-43-0 C19H15Br
1,8-Dichlorooctane 1,8-Dichlorooctane 2162-99-4 C8H16Cl2
1-Bromotridecane 1-Bromotridecane 765-09-3 C13H27Br
2-FLUOROBENZOTRICHLORIDE 2-FLUOROBENZOTRICHLORIDE 488-98-2 C7H4Cl3F
4-Fluoro-1,1'-biphenyl 4-Fluoro-1,1'-biphenyl 324-74-3 C12H9F
1,2,4,5-TETRABROMOBENZENE 1,2,4,5-TETRABROMOBENZENE 636-28-2 C6H2Br4
Perfluorodecalin Perfluorodecalin 306-94-5 C10F18
1-BroMoheptadecafluorooctane 1-BroMoheptadecafluorooctane 423-55-2 C8BrF17
Chloroform Chloroform 67-66-3 CHCl3
1-ETHYNYL-3 5-DIFLUOROBENZENE  97 1-ETHYNYL-3 5-DIFLUOROBENZENE 97 151361-87-4 C8H4F2
1-BROMO-3,7-DIMETHYLOCTANE 1-BROMO-3,7-DIMETHYLOCTANE 3383-83-3 C10H21Br
HEXABROMOBENZENE HEXABROMOBENZENE 87-82-1 C6Br6
4-BROMOHEPTANE 4-BROMOHEPTANE 998-93-6 C7H15Br
1-BROMO-4-TRIMETHYLSILYLBENZENE 1-BROMO-4-TRIMETHYLSILYLBENZENE 6999-03-7 C9H13BrSi
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-O-XYLENE 13209-15-9 C8H6Br4
TRANS-4-BROMO-BETA-NITROSTYRENE TRANS-4-BROMO-BETA-NITROSTYRENE 5153-71-9 C8H6BrNO2
1-Chloro-2,5-difluorobenzene 1-Chloro-2,5-difluorobenzene 2367-91-1 C6H3ClF2
5-BROMO-2-METHYL-2-PENTENE 5-BROMO-2-METHYL-2-PENTENE 2270-59-9 C6H11Br
3-Chloro-1-butene 3-Chloro-1-butene 563-52-0 C4H7Cl
2,4-Bis(trifluoromethyl)benzyl bromide 2,4-Bis(trifluoromethyl)benzyl bromide 140690-56-8 C9H5BrF6
4-ISOPROPYLBENZYL CHLORIDE 4-ISOPROPYLBENZYL CHLORIDE 2051-18-5 C10H13Cl
1,14-DIBROMOTETRADECANE 1,14-DIBROMOTETRADECANE 37688-96-3 C14H28Br2
ALLYLPENTAFLUOROBENZENE ALLYLPENTAFLUOROBENZENE 1736-60-3 C9H5F5
7-CHLORO-1-HEPTENE 7-CHLORO-1-HEPTENE 929-21-5 C7H13Cl
1-BROMO-3-(BROMOMETHYL)ADAMANTANE 1-BROMO-3-(BROMOMETHYL)ADAMANTANE 1822-25-9 C11H16Br2
1,10-DIIODODECANE 1,10-DIIODODECANE 16355-92-3 C10H20I2
1-Chloroadamantane 1-Chloroadamantane 935-56-8 C10H15Cl
1-Bromoundecane 1-Bromoundecane 693-67-4 C11H23Br
1,1,1,2,2-PENTAFLUORO-4-IODOBUTANE 1,1,1,2,2-PENTAFLUORO-4-IODOBUTANE 40723-80-6 C4H4F5I
1-BROMO-2-METHYLNAPHTHALENE 1-BROMO-2-METHYLNAPHTHALENE 2586-62-1 C11H9Br
1-BROMO-2-ETHYNYLBENZENE 1-BROMO-2-ETHYNYLBENZENE 766-46-1 C8H5Br
1,4-DIBROMOTETRAFLUOROBENZENE 1,4-DIBROMOTETRAFLUOROBENZENE 344-03-6 C6Br2F4
1-Bromo-4-methylpentane 1-Bromo-4-methylpentane 626-88-0 C6H13Br
2-BROMO-3-CHLORO-1-PROPENE 2-BROMO-3-CHLORO-1-PROPENE 16400-63-8 C3H4BrCl
4-METHYL-2,3,5,6-TETRAFLUOROBENZYL BROMIDE 4-METHYL-2,3,5,6-TETRAFLUOROBENZYL BROMIDE 92814-00-1 C8H5BrF4
1-(2-BROMO-ETHYL)-2-METHYL-BENZENE 1-(2-BROMO-ETHYL)-2-METHYL-BENZENE 16793-90-1 C9H11Br
VINYLIDENE CHLORIDE VINYLIDENE CHLORIDE 75-35-4 C2H2Cl2
Cyclobutyl chloride Cyclobutyl chloride 1120-57-6 C4H7Cl
2-Chloro-1,4-dimethylbenzene 2-Chloro-1,4-dimethylbenzene 95-72-7 C8H9Cl
DIBROMODIFLUOROMETHANE DIBROMODIFLUOROMETHANE 75-61-6 CBr2F2
2-BROMO-2-BUTENE 2-BROMO-2-BUTENE 13294-71-8 C4H7Br
2-BROMO-1-PHENYLPROPANE 2-BROMO-1-PHENYLPROPANE 2114-39-8 C9H11Br
HEXAKIS(BROMOMETHYL)BENZENE HEXAKIS(BROMOMETHYL)BENZENE 3095-73-6 C12H12Br6
P,P'-DDD P,P'-DDD 72-54-8 C14H10Cl4
1,1,2-Trichlorotrifluoroethane 1,1,2-Trichlorotrifluoroethane 76-13-1 C2Cl3F3
1,6-Diiodododecafluorohexane 1,6-Diiodododecafluorohexane 375-80-4 C6F12I2
1-IODOOCTADECANE 1-IODOOCTADECANE 629-93-6 C18H37I
3-(Bromomethyl)biphenyl 3-(Bromomethyl)biphenyl 14704-31-5 C13H11Br
4-Iodo-1,2-dimethylbenzene 4-Iodo-1,2-dimethylbenzene 31599-61-8 C8H9I
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-M-XYLENE ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-M-XYLENE 36323-28-1 C8H6Br4
3,4,5-TRIFLUOROBENZYL BROMIDE 3,4,5-TRIFLUOROBENZYL BROMIDE 220141-72-0 C7H4BrF3
Methyl bromide Methyl bromide 74-83-9 CH3Br
4-BROMO-2,3,5,6-TETRAFLUOROBENZOTRIFLUORIDE 4-BROMO-2,3,5,6-TETRAFLUOROBENZOTRIFLUORIDE 17823-46-0 C7BrF7
1,6-DIIODOHEXANE 1,6-DIIODOHEXANE 629-09-4 C6H12I2
11-BROMO-1-UNDECENE 11-BROMO-1-UNDECENE 7766-50-9 C11H21Br
4-(Chloromethyl)biphenyl 4-(Chloromethyl)biphenyl 1667-11-4 C13H11Cl
2-BROMONONANE 2-BROMONONANE 2216-35-5 C9H19Br
1,3-Difluoro-5-iodobenzene 1,3-Difluoro-5-iodobenzene 2265-91-0 C6H3F2I
Perfluorobutyl iodide Perfluorobutyl iodide 423-39-2 C4F9I
TRIMETHYL(PENTAFLUOROPHENYL)SILANE TRIMETHYL(PENTAFLUOROPHENYL)SILANE 1206-46-8 C9H9F5Si
3,5-DI-TERT-BUTYLBENZYL BROMIDE 3,5-DI-TERT-BUTYLBENZYL BROMIDE 62938-08-3 C15H23Br
Chloromethane Chloromethane 74-87-3 CH3Cl
2,4-DIBROMOMESITYLENE 2,4-DIBROMOMESITYLENE 6942-99-0 C9H10Br2
6-Chlorohex-1-ene 6-Chlorohex-1-ene 928-89-2 C6H11Cl
1,3-DIBROMO-1-PROPENE 1,3-DIBROMO-1-PROPENE 627-15-6 C3H4Br2
1,3,5-Trichloro-2,4,6-trifluorobenzene 1,3,5-Trichloro-2,4,6-trifluorobenzene 319-88-0 C6Cl3F3
Chloropentafluorobenzene Chloropentafluorobenzene 344-07-0 C6ClF5
1,2,3,4-Tetrachlorobenzene 1,2,3,4-Tetrachlorobenzene 634-66-2 C6H2Cl4
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