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ChemicalBook >> CAS DataBase List >> CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) price.
  • $16 - $796
  • Product name: CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
  • CAS: 92390-26-6
  • MF: C18H27ClRu5*
  • MW: 379.93
  • EINECS:
  • MDL Number:MFCD07369035
  • Synonyms:Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II),98%;Ruthenium,chloro[(1,2,5,6-h)-1,5-cyclooctadiene][(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]-;1,5-Cyclooctadiene, ruthenium complex;Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium;Chloro(1，5-cyclooctadiene)(pentamethylcyclopent...;Chloro(pentaMethylcyclopentadienyl)(cyclooctadiene)rutheniuM;CHLORO(PENTAMETHYLCYCLOPENTADIENYL)(CYC&;CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
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Brand
  • AK Scientific
  • Alfa Aesar
  • Alichem
  • Ambeed
  • American Custom Chemicals Corporation
  • Arctom
  • Chemenu
  • ChemScene
  • ChemSupplyAustralia
  • Crysdot
  • Labseeker
  • Matrix Scientific
  • Sigma-Aldrich
  • Strem Chemicals
  • TRC
Package
  • 100mg
  • 250mg
  • 500mg
  • 1g
  • 5g
  • ManufacturerAK Scientific
  • Product number5607AC
  • Product descriptionChloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium
  • Packaging1g
  • Price$428
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number046803
  • Product descriptionChloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II)
  • Packaging250mg
  • Price$113.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number046803
  • Product descriptionChloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II)
  • Packaging1g
  • Price$394
  • Updated2024-03-01
  • Buy
  • ManufacturerAlichem
  • Product number92390266
  • Product descriptionChloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium
  • Packaging1g
  • Price$281.96
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1233025
  • Product descriptionChloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98%
  • Packaging5g
  • Price$350
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA280115
  • Product descriptionChloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98+%
  • Packaging5g
  • Price$350
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1233025
  • Product descriptionChloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98%
  • Packaging1g
  • Price$90
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA280115
  • Product descriptionChloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98+%
  • Packaging1g
  • Price$90
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1233025
  • Product descriptionChloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98%
  • Packaging250mg
  • Price$38
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA280115
  • Product descriptionChloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98+%
  • Packaging250mg
  • Price$38
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1233025
  • Product descriptionChloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98%
  • Packaging100mg
  • Price$16
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA280115
  • Product descriptionChloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98+%
  • Packaging100mg
  • Price$16
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0016419
  • Product descriptionCHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM 95.00%
  • Packaging1G
  • Price$796
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0016419
  • Product descriptionCHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM 95.00%
  • Packaging250MG
  • Price$526
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS505329
  • Product descriptionChloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium ≥98%
  • Packaging250mg
  • Price$38
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS505329
  • Product descriptionChloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium ≥98%
  • Packaging1g
  • Price$107
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 5607AC Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 1g $428 2021-12-16 Buy
Alfa Aesar 046803 Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II) 250mg $113.65 2024-03-01 Buy
Alfa Aesar 046803 Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II) 1g $394 2024-03-01 Buy
Alichem 92390266 Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 1g $281.96 2021-12-16 Buy
Ambeed A1233025 Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98% 5g $350 2021-12-16 Buy
Ambeed A280115 Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98+% 5g $350 2021-12-16 Buy
Ambeed A1233025 Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98% 1g $90 2021-12-16 Buy
Ambeed A280115 Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98+% 1g $90 2021-12-16 Buy
Ambeed A1233025 Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98% 250mg $38 2021-12-16 Buy
Ambeed A280115 Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98+% 250mg $38 2021-12-16 Buy
Ambeed A1233025 Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98% 100mg $16 2021-12-16 Buy
Ambeed A280115 Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium 98+% 100mg $16 2021-12-16 Buy
American Custom Chemicals Corporation ING0016419 CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM 95.00% 1G $796 2021-12-16 Buy
American Custom Chemicals Corporation ING0016419 CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM 95.00% 250MG $526 2021-12-16 Buy
Arctom AS505329 Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium ≥98% 250mg $38 2021-12-16 Buy
Arctom AS505329 Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium ≥98% 1g $107 2021-12-16 Buy

Properties

Melting point :143-147℃
storage temp. :-20°C
color :brown microxtls
Stability :store cold
InChIKey :JBVMVFXUVNUNNG-ONEVTFJLSA-M

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3		 Danger
Warning		 GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
Precautionary statements:
P231+P232 Handle under inert gas. Protect from moisture.
P422 Store contents under …

Description

Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.
It can be used:
  • To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.
  • To catalyze C-C coupling of norbornenes and norbornadiene with alkynes?to form [2 + 2] cycloadducts.
  • In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.
  • To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.
  • To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.

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