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ChemicalBook >> CAS DataBase List >> Chloro(1,5-cyclooctadiene)iridium(I) dimer

Chloro(1,5-cyclooctadiene)iridium(I) dimer

Chloro(1,5-cyclooctadiene)iridium(I) dimer price.
  • $56 - $6000
  • Product name: Chloro(1,5-cyclooctadiene)iridium(I) dimer
  • CAS: 12112-67-3
  • MF: C16H24Cl2Ir2
  • MW: 671.7
  • EINECS:235-170-7
  • MDL Number:MFCD00012414
  • Synonyms:DI-MU-CHLOROBIS[(ETA-CYCLOOCTA-1,5-DIENE)IRIDIUM (I)];DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-CYCLOOCTADIENE]DIIRIDIUM;CHLORO(1,5-CYCLOOCTADIENE)IRIDATE (I) DIMER;CHLORO(1,5-CYCLOOCTADIENE)IRIDIUM(I) DIMER;IRIDIUM I CYCLOOCTADIENE CHLORIDE;IRIDIUM CHLORO-1,5-CYCLOOCTADIENE;IRIDIUM COD CHLORIDE;1,5-CYCLOOCTADIENE-IRIDIUM(I) CHLORIDE DIMER
48 prices
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Brand
  • AK Scientific
  • Alfa Aesar
  • Alichem
  • Ambeed
  • American Custom Chemicals Corporation
  • Arctom
  • Biosynth Carbosynth
  • Chem-Impex
  • ChemScene
  • ChemSupplyAustralia
  • Crysdot
  • JR MediChem
  • Matrix Scientific
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Package
  • 100mg
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  • 0.25g
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  • 5gm
  • 10g
  • 25g
  • 100g
  • ManufacturerAK Scientific
  • Product number8413CP
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) Dimer
  • Packaging1g
  • Price$205
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product number8413CP
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) Dimer
  • Packaging5g
  • Price$600
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number012749
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%
  • Packaging0.25g
  • Price$105
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number012749
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%
  • Packaging1g
  • Price$422
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number012749
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%
  • Packaging5g
  • Price$1932
  • Updated2023-06-20
  • Buy
  • ManufacturerAlichem
  • Product number12112673
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) Dimer
  • Packaging25g
  • Price$1430
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1194534
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) Dimer 98%+(57.2%Ir)
  • Packaging100mg
  • Price$60
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA132084
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) Dimer 97+%
  • Packaging100mg
  • Price$60
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA132084
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) Dimer 97+%
  • Packaging250mg
  • Price$100
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA132084
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) Dimer 97+%
  • Packaging1g
  • Price$360
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1194534
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) Dimer 98%+(57.2%Ir)
  • Packaging1g
  • Price$360
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA132084
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) Dimer 97+%
  • Packaging5g
  • Price$1224
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1194534
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) Dimer 98%+(57.2%Ir)
  • Packaging5g
  • Price$1600
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA132084
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) Dimer 97+%
  • Packaging10g
  • Price$3000
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1194534
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) Dimer 98%+(57.2%Ir)
  • Packaging10g
  • Price$3000
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA132084
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) Dimer 97+%
  • Packaging25g
  • Price$6000
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 8413CP Chloro(1,5-cyclooctadiene)iridium(I) Dimer 1g $205 2021-12-16 Buy
AK Scientific 8413CP Chloro(1,5-cyclooctadiene)iridium(I) Dimer 5g $600 2021-12-16 Buy
Alfa Aesar 012749 Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2% 0.25g $105 2023-06-20 Buy
Alfa Aesar 012749 Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2% 1g $422 2023-06-20 Buy
Alfa Aesar 012749 Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2% 5g $1932 2023-06-20 Buy
Alichem 12112673 Chloro(1,5-cyclooctadiene)iridium(I) Dimer 25g $1430 2021-12-16 Buy
Ambeed A1194534 Chloro(1,5-cyclooctadiene)iridium(I) Dimer 98%+(57.2%Ir) 100mg $60 2021-12-16 Buy
Ambeed A132084 Chloro(1,5-cyclooctadiene)iridium(I) Dimer 97+% 100mg $60 2021-12-16 Buy
Ambeed A132084 Chloro(1,5-cyclooctadiene)iridium(I) Dimer 97+% 250mg $100 2021-12-16 Buy
Ambeed A132084 Chloro(1,5-cyclooctadiene)iridium(I) Dimer 97+% 1g $360 2021-12-16 Buy
Ambeed A1194534 Chloro(1,5-cyclooctadiene)iridium(I) Dimer 98%+(57.2%Ir) 1g $360 2021-12-16 Buy
Ambeed A132084 Chloro(1,5-cyclooctadiene)iridium(I) Dimer 97+% 5g $1224 2021-12-16 Buy
Ambeed A1194534 Chloro(1,5-cyclooctadiene)iridium(I) Dimer 98%+(57.2%Ir) 5g $1600 2021-12-16 Buy
Ambeed A132084 Chloro(1,5-cyclooctadiene)iridium(I) Dimer 97+% 10g $3000 2021-12-16 Buy
Ambeed A1194534 Chloro(1,5-cyclooctadiene)iridium(I) Dimer 98%+(57.2%Ir) 10g $3000 2021-12-16 Buy
Ambeed A132084 Chloro(1,5-cyclooctadiene)iridium(I) Dimer 97+% 25g $6000 2021-12-16 Buy

Properties

Melting point :205 °C (dec.)(lit.)
storage temp. :Keep in dark place,Inert atmosphere,2-8°C
solubility :Chloroform (Slightly), Methanol (Slightly)
form :Powder
color :red to orange
Water Solubility :insoluble
Hydrolytic Sensitivity :7: reacts slowly with moisture/water
InChIKey :XHOSESNLNGITPM-XRGHXPOKSA-L

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.

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