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SAMARIUM ???

SAMARIUM ???
SAMARIUM ??? ??? ???
?? ??:
12060-58-1
???:
SAMARIUM ???
???(??):
SAMARIUM???;??????;?????
???:
Samarium oxide
???(??):
99.6%;samaria;samarium(3+);SaMariuM oxid;Samarium oxide;samariumtrioxide;SAMARIUM OXIDE GR;Samarium(Ⅲ) oxide;samarium(3+)oxide;Sumarium trioxide
CBNumber:
CB5743142
???:
O3Sm2
??? ??:
348.72
MOL ??:
12060-58-1.mol

SAMARIUM ??? ??

???
2325 °C
??
8.35 g/mL at 25 °C(lit.)
???
1.97
?? ??
no restrictions.
??? ??
????
??
???
Specific Gravity
8.347
??????(pH)
8.0 (10g/l, H2O, 25℃)(slurry)
???
?? ???.
Crystal Structure
Cubic
crystal system
Monoclinic
Merck
14,8347
Space group
C2/m
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
1.41770.36330.88479099.96900.4488
InChI
InChI=1S/3O.2Sm
InChIKey
PRCWVHVINXAFRG-UHFFFAOYSA-N
SMILES
O([Sm]=O)[Sm]=O
CAS ??????
12060-58-1(CAS DataBase Reference)
EPA
Samarium oxide (Sm2O3) (12060-58-1)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
????? 22-24/25
WGK ?? 2
RTECS ?? VP3153000
F ?????? 3-10-34
TSCA Yes
HS ?? 28469019
?? LD50 orally in Rabbit: > 5000 mg/kg
???? ?? KE-30864
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P332+P313 ?? ??? ??? ???? ??· ??? ????.
P337+P313 ?? ?? ??? ???? ???? ??· ??? ????.
NFPA 704
0
0 1

SAMARIUM ??? MSDS


Samarium oxide

SAMARIUM ??? C??? ??, ??, ??

??? ??

light beige crystalline powder

??? ??

Yellowish-white powder; density 8.347g/cm3; insoluble in water; dissolves readily in mineral acids.

??

Samarium sesquioxide is used in optical and infrared absorbing glass to absorb infrared radiation. Also, it is used as a neutron absorber in control rods for nuclear power reactors. The oxide catalyzes dehydration of acyclic primary alcohols to aldehydes and ketones. Another use involves preparation of other samarium salts.

?? ??

Samarium sesquioxide may be prepared by two methods; (1) thermal decomposition of samarium carbonate, hydroxide, nitrate, oxalate or sulfate:
Sm2(CO3)3 → Sm2O3 + 3CO2
2Sm(OH)3 → Sm2O3 + 3H2O
or (2) by burning the metal in air or oxygen at a temperature above 150°C:
4Sm + 3O2 → 2Sm2O3.

SAMARIUM ??? ?? ?? ? ???

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SAMARIUM ??? ?? ??

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SAMARIUM ??? ?? ??:

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