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10294-40-3
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???(??):
?????;??????;??? ??;?? ??;?? ??? ???? (BaCrO4);?? ??? ??;??? (H2CrO4), ?? ? (1:1);??? ?? (1:1);??? ?? (BaCrO4);???(VI) ??;?????(VI)
???:
Barium chromate
???(??):
Lemon yellow;ci77103;c.i.77103;C.I. 77103;lemonchrome;lemonyellow;Lemon chrome;barytayellow;Baryta yellow;Barium cromate
CBNumber:
CB4674975
???:
BaCrO4
??? ??:
253.3207
MOL ??:
10294-40-3.mol
MSDS ??:
SDS

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???
210 °C (dec.) (lit.)
??
4.5 g/mL at 25 °C (lit.)
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reacts with acid solutions
??? ??
??
Specific Gravity
4.5
??
???
???
?? ???. ??? ?????.
Merck
14,972
Solubility Product Constant (Ksp)
pKsp: 9.93
?? ??
OSHA: Ceiling 0.1 mg/m3
NIOSH: IDLH 15 mg/m3; TWA 0.0002 mg/m3
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????. ???. ???? ???? ??? ? ??.
InChIKey
QFFVPLLCYGOFPU-UHFFFAOYSA-N
CAS ??????
10294-40-3(CAS DataBase Reference)
NIST
barium chromate(VI)(10294-40-3)
EPA
Barium chromate (10294-40-3)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? O,T,N,Xn
?? ???? ?? 49-8-20/22-43-50/53
????? 53-36/37-45-60-61-28
????(UN No.) UN 1479 5.1/PG 2
WGK ?? 3
RTECS ?? CQ8760000
TSCA Yes
?? ?? 5.1
???? III
?? ?? ??? 10294-40-3(Hazardous Substances Data)
?? sce-ham:ovr 100 mg/L MUREAV 156,219,85
???? ?? KE-02040
?????? ??? 97-1-271;06-5-10
?????? ??? ??1-152
?, ??????? ??? 9
?? ? ???? ????: ????; ???(??)????: ???(6+)??? ? ?? 0.1% ?? ??? ???
????(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H272 ??? ???? ?; ??? ??? ??;??? ?? ?? 2
?? 3
??
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GHS hazard pictograms P210, P220, P221P280, P370+P378,P501
H350 ?? ??? ? ?? (????? ?? ???? ???? ???? ??? ?? ????? ??? ???? ??) ??? ?? ?? 1A, 1B ?? GHS hazard pictograms
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P201 ?? ? ?? ???? ?????.
P202 ?? ?? ?? ??? ?? ???? ??? ???? ???.
P210 ?·???·??·????? ????? - ?? ???.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
P308+P313 ?? ?? ??? ???? ???? ??· ??? ????.
NFPA 704
0
2 0
OX

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Barium chromate is a heavy, yellow powder(s); rhomb, monoclinic; prepared from BaCl2 and Na2CrO4 solutions, followed by filtering resulting precipitate; used in safety matches, as a corrosion inhibitor.[MER06] [HAW93]

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Yellow orthorhombic crystal; density 4.50 g/cm3; darkens on heating; insoluble in water and organic solvents; dissolves in mineral acid with decomposition.

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Barium chromate has been found to be useful in many capacities. It is an oxidizing agent, making it useful as a burn rate modifier in pyrotechnic compositions. It is especially useful in delay compositions such as delay fuses. Barium chromate is used as a pigment, oxidizing agent, colorant in glass, and sulfate scavenger in chromium electroplating baths, ceramics, and porcelain. It acts as a corrosion inhibitor in jointing pastes and metal primers. Further, it is used in fuses, safety matches, ignition control devices and high-temperature batteries. In addition to this, it is used as a carrier for the chromium ions and useful as a burn rate modifier in pyrotechnic compositions. It is involved as a catalyst in the alkane dehydration reaction.

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Barium chromate is an oxidizing chemical compound composed of the elements barium and chromium. It is a pigment almost entirely in anticorrosion jointing pastes to prevent electro-chemical corrosion at junctions of dissimilar metals; some use in artists' colors and in coloring glass, ceramics, porcelain. Also used in metal primers, pyrotechnic compositions.

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Interaction of barium chloride and sodium chromate. The precipitate is washed, filtered and dried.
BaCl2+Na2CrO4→BaCrO4↓+2NaCl

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Confirmed carcinogen.

Safety Profile

Confirmed human carcinogen. A poison. Mutation data reported. Reacts vigorously with reducing materials. See also BARIUM COMPOUNDS (soluble) and CHROMIUM COMPOUNDS. Used in pyrotechnics and as an explosive initiator.

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