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ChemicalBook >> CAS DataBase List >>(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY

CAS No.
656233-53-3
Chemical Name:
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY
Synonyms
(R)-SHIP;(S)-SHIP;1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY;PHENYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE;PHENYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE;Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite ,97%;Phenyl-[(R)-1,1′-spirobiindane-7,7′-diyl]-phosphite((R)-ShiP);12-phenoxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine;(11AR)-10,11,12,13-TETRAHYDRO-5-PHENOXY-DIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN;(11aR)-10,11,12,13-Tetrahydro-5-phenoxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin
CBNumber:
CB7382271
Molecular Formula:
C23H19O3P
Molecular Weight:
374.37
MDL Number:
MFCD08459341
MOL File:
656233-53-3.mol
Last updated:2023-05-04 15:16:47

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Properties

Melting point 104-106°C
Boiling point 454.8±45.0 °C(Predicted)
alpha +216° (c 0.5, CH2Cl2)
form solid
color white
Sensitive moisture sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P264-P270-P301+P312-P330-P501
Hazard Codes  Xn
Risk Statements  22

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-5156 (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy, min. 98% (R)-ShiP 656233-53-3 100mg $113 2022-04-27 Buy
Strem Chemicals 15-5156 (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy, min. 98% (R)-ShiP 656233-53-3 500mg $452 2022-04-27 Buy
American Custom Chemicals Corporation ING0001117 (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY 95.00% 656233-53-3 50MG $614.87 2021-12-16 Buy
American Custom Chemicals Corporation ING0001117 (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY 95.00% 656233-53-3 250MG $821.64 2021-12-16 Buy
Product number Packaging Price Buy
15-5156 100mg $113 Buy
15-5156 500mg $452 Buy
ING0001117 50MG $614.87 Buy
ING0001117 250MG $821.64 Buy

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Chemical Properties,Uses,Production

Reaction

  1. Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids.
  2. Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids.
  3. Chiral ligands for rhodium-catalyzed arylation of α-ketoesters with arylboronic acids.
  4. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
  5. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-β-arylenamides.
Reactions of 656233-53-3_1
Reactions of 656233-53-3_2

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656233-53-3((11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY)Related Search:

(11aR)-10,11,12,13-Tetrahydro-5-phenoxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin,99%e.e. (11AR)-10,11,12,13-TETRAHYDRO-5-PHENOXY-DIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite ,97% (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY (11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite, (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-phenoxy (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy,min.98%(R)-ShiP PHENYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE PHENYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE (S)-SHIP (R)-SHIP 12-phenoxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine Phenyl-[(R)-1,1′-spirobiindane-7,7′-diyl]-phosphite((R)-ShiP) Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, 10,11,12,13-tetrahydro-5-phenoxy-, (11aR)- 1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1'',7''-fg][1,3,2]dioxaphosphocin-5-phenoxy (11aR)-10,11,12,13-Tetrahydro-5-phenoxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin 11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY 656233-53-3