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ChemicalBook >> CAS DataBase List >>PETROLEUM ETHER

PETROLEUM ETHER

CAS No.
8032-32-4
Chemical Name:
PETROLEUM ETHER
Synonyms
HEXANES;NAPHTHA;PETROL;BENZINE;LIGROINE;LIGROIN;MINERAL SEAL OIL;vm;BENZIN;PETROLEUM OIL
CBNumber:
CB9248175
Molecular Formula:
unspecified
Molecular Weight:
0
MDL Number:
MFCD00081849
MOL File:
Mol file
MSDS File:
SDS
Last updated:2024-12-18 14:15:30

PETROLEUM ETHER Properties

Melting point -40℃
Boiling point 90-100 °C
Density 0.77 g/mL at 20 °C
vapor density 2.5 (vs air)
vapor pressure 25.8 psi ( 55 °C)
refractive index n20/D 1.428
Flash point −57 °F
storage temp. Store at room temperature.
solubility Chloroform (Soluble), Ethyl Acetate (Slightly)
form Liquid
color APHA: ≤10
Specific Gravity 0.715 (20/4℃)
Odor Gasoline or kerosene
explosive limit 8%
Evaporation Rate 10
Water Solubility Insoluble in water.
λmax λ: 210 nm Amax: 1.00
λ: 220 nm Amax: 0.30
λ: 230 nm Amax: 0.10
λ: 240 nm Amax: 0.05
λ: 260-400 nm Amax: 0.01
Merck 14,5489
Exposure limits TLV-TWA 300 ppm (~1350 mg/m3) (ACGIH), 75 ppm (~350 mg/m3) (NIOSH); TLV-STEL 400 ppm (ACGIH).
Stability Stable. Extremely flammable. Avoid strong oxidizing agents, all sources of ignition. As a consequence of its low flashpoint, mixtures of this material with air may ignite upon contact with hot surfaces - a naked flame is not required.
Indirect Additives used in Food Contact Substances LIGROINE
FDA UNII 5OQ4BMR99T
EPA Substance Registry System Ligroine (8032-32-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS08
Signal word  Danger
Hazard statements  H225-H304-H340-H350
Precautionary statements  P201-P210-P301+P310+P331-P308+P313
Hazard Codes  Xn,T,F,N,F+
Risk Statements  12-65-45-67-51/53-38-11-22-50/53-10-39/23/24/25-23/24/25-46-66-52/53
Safety Statements  62-45-53-61-16-60-23-36/37-24
RIDADR  UN 3295 3/PG 2
OEB A
OEL TWA: 350 mg/m3, Ceiling: 1800 mg/m3 [15-minute]
WGK Germany  3
RTECS  OI6180000
Autoignition Temperature 475 °F
TSCA  Yes
HazardClass  3
PackingGroup  I
HS Code  27101299
Hazardous Substances Data 8032-32-4(Hazardous Substances Data)
Toxicity LD50 intravenous in mouse: 40mg/kg
NFPA 704
4
1 0

PETROLEUM ETHER price More Price(39)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich LX0260 Ligroine Practical 8032-32-4 4L $235 2024-03-01 Buy
Sigma-Aldrich LX0260 Ligroine Practical 8032-32-4 20L $575 2024-03-01 Buy
Sigma-Aldrich 184519 Petroleum ether ACS reagent 8032-32-4 1l $87 2024-03-01 Buy
Sigma-Aldrich 184519 Petroleum ether ACSreagent 8032-32-4 18L $425 2024-03-01 Buy
Alfa Aesar 038985 Petroleum ether 35/60, HPLC Grade 8032-32-4 1L $65.3 2024-03-01 Buy
Product number Packaging Price Buy
LX0260 4L $235 Buy
LX0260 20L $575 Buy
184519 1l $87 Buy
184519 18L $425 Buy
038985 1L $65.3 Buy

PETROLEUM ETHER Chemical Properties,Uses,Production

Description

Petroleum ether, a petroleum distillation fraction, is a mixture of low molecular weight aliphatic hydrocarbons (mostly pentanes and hexanes) with a low boiling range, typically around 30-60oC. Its name is derived from its origin and its ease of evaporation.The majority components include paraffins, olefins, naphthenes, aromatics, and about 10%–40% ethyl alcohol。
Petroleum ether is commonly used as a nonpolar solvent for oils, fats, and waxes. Petroleum ether is used in pharmaceutical industries as a solvent to isolate compounds, e.g. petroleum ether can extract stigmasterol and beta-sitosterol from the aerial parts of Ageratum conyzoides and compounds with immunomodulatory activity from Anacyclus pyrethrum. It is also used as a detergent, a fuel, insecticide, in paints and varnishes, and in photography.

Chemical Properties

Petroleum ether is a colorless liquid. Extracts of leaves of Litchi chinensis Gaertn. (Sapindaceae) have been prepared in petroleum ether and were evaluated for antiinflammatory, analgesic and antipyretic activities. Pentanes and hexanes are the major constituents of petroleum ether.

uses

Petroleum ether is generally a mixture of low boiling aliphatic hydrocarbons mainly hexane and pentane. It is generally used as a laboratory solvent and also as an extraction solvent.
Petroleum ether has been used for the analysis of total dietary fiber content by employing a total dietary fibre assay kit. It may be used in the absorption chromatographic purification of organic compounds.

References

[1] Anjoo Kamboj, Ajay Kumar Saluja (2011) Isolation of Stigmasterol and beta sitosterol from petroleum ether extract of Aerial parts of Ageratum Conyzoides (Asteracea), Inter. J. Pharma. Pharma. Sci.  3, 94-¬96.
[2] Ashton Acton (2011) Advances in Immune System Research and Applications
[3] https://www.cdc.gov/niosh/pdfs/77-192c.pdf

Chemical Properties

colourless liquid with hydrocarbon odour

Chemical Properties

Petroleum ether is a flammable liquid used as a universal solvent and extractant during the processing of different chemicals, like fats, waxes, paints, varnishes, furniture polish thinning, as detergent, and as fuel. The major components include paraffi ns, olefi ns, naphthenes, aromatics, and about 10%–40% ethyl alcohol.

Uses

Thinners in paints and varnish.

Uses

Petroleum ether 35/60 is used as a mobile phase in High Performance Liquid Chromatography and Liquid Chromatography coupled with Mass Spectrometry.

Definition

A flammable mixture of hydrocarbons, mainly pentane and hexane, used as a solvent. Note that it is not an ether.

Definition

A colourlessvolatile flammable mixture of hydrocarbons(not an ether), mainly pentaneand hexane. It boils in the range30–70°C and is used as a solvent.

Definition

Any of a number of narrowboiling-range fractions of petroleum with bp of approximately 93–204C, according to the specific use.

General Description

Colorless liquid with the odor of gasoline. Less dense than water and insoluble in water. Hence floats on water. Also refered to as Varnish Makers & Painters Naphtha. This petroleum fraction is similar to Petroleum Ether (CAS 8030-30-6) but V.M. & P. is a heavier distillate. Flash point ranges from 20° F to 100° F.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

PETROLEUM NAPHTHA, [FLAMMABLE LIQUID LABEL] may be incompatible with strong oxidizing agents like nitric acid. Charring may occur followed by ignition of unreacted material and other nearby combustibles. In other settings, mostly unreactive. Not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents, burns exothermically to produce mostly carbon dioxide and water.

Hazard

Flammable, dangerous fire risk.

Health Hazard

After acute and prolonged exposures to petroleum ether in work places, occupational workers suffer and demonstrate a variety of health disorder. The symptoms of toxicity include, but are not limited to, erythema, edema, skin peeling, loss of appetite, muscle weakness, paresthesia, CNS depression, peripheral nerve disorders, skin and respiratory irritation, and chemical pneumonia in children. Occupational workers exposed to rubber solvent, varnish, thinner, and petroleum spirits develop skin irritation, respiratory problems, and hematologic effects.

Health Hazard

The vapors of VM&P solvent are irritant tothe eyes and upper respiratory tract. Suchirritant action in humans may be manifested at an exposure level of 1000 ppm for15 minutes. It is narcotic at high concentrations. The symptoms noted in rats of acuteexposure were loss of coordination as wellas convulsions. The inhalation LC50 value for4-hour exposure in rats is 3400 ppm (NIOSH1986)..

Health Hazard

Inhalation of concentrated vapor may cause intoxication. Liquid is not very irritating to skin or eyes but may get into lungs by aspiration.

Fire Hazard

Flammable liquid; flash point (closed cup) 14°C (57°F); vapors form explosive mixtures with air within the range 1.2–6.0% by volume in air.

Flammability and Explosibility

Extremely flammable

Safety Profile

Confirmed carcinogen. A poison by intravenous route. Mildly toxic by inhalation. Ingestion can cause a burning sensation, vomiting, diarrhea, drowsiness, and, in severe cases, pulmonary edema. Inhalation of concentrated vapors can cause intoxication resembling that from alcohol, headache, nausea, coma, and hemorrhage to various vital organs. An eye irritant. A flammable liquid and highly dangerous fire hazard when exposed to heat, flame, sparks, or oxidizing materials. Explosive in the form of vapor when exposed to heat or flame. Highly dangerous; keep away from heat or flame. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes

Purification Methods

Shake it several times with conc H2SO4, then 10% H2SO4 and concentrated KMnO4 (to remove unsaturated, including aromatic, hydrocarbons) until the permanganate colour persists. Wash it with water, aqueous Na2CO3 and again with water. Dry it with CaCl2 or Na2SO4, and distil it. It can be dried further using CaH2 or sodium wire. Passage through a column of activated alumina, or treatment with CaH2 or sodium, removes peroxides. For the elimination of carbonyl-containing impurities without using permanganate, see n-heptane. These procedures could be used for all fractions of pet ethers. See skellysolve below, p. 178. Rapid purification: Pass it through an alumina column and fractionally distilling, collecting the desired boiling fraction.

Global( 383)Suppliers
Supplier Tel Email Country ProdList Advantage
Aladdin Scientific
+1-+1(833)-552-7181 sales@aladdinsci.com United States 57505 58
SHANGHAI KEAN TECHNOLOGY CO., LTD.
+8613817748580 cooperation@kean-chem.com China 40066 58
Yujiang Chemical (Shandong) Co.,Ltd.
+86-17736087130 +86-18633844644 catherine@yjchem.com.cn China 990 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
ATK CHEMICAL COMPANY LIMITED
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career henan chemical co
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Chongqing Chemdad Co., Ltd
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View Lastest Price from PETROLEUM ETHER manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
PETROLEUM OIL pictures 2024-11-26 PETROLEUM OIL
US $0.00 / kg 1kg 99 20tons qingdao trust agri chemical co.,ltd
PETROLEUM ETHER pictures 2024-05-07 PETROLEUM ETHER
8032-32-4
US $1400.00 / T 1T 98% 20T Yujiang Chemical (Shandong) Co.,Ltd.
petroleum ether pictures 2023-06-26 petroleum ether
8032-32-4
US $150.00 / ASSAYS 10g more than 99.6% 500kg/month Hebei Mingeng Biotechnology Co., Ltd
  • PETROLEUM ETHER pictures
  • PETROLEUM ETHER
    8032-32-4
  • US $1400.00 / T
  • 98%
  • Yujiang Chemical (Shandong) Co.,Ltd.
  • petroleum ether pictures
  • petroleum ether
    8032-32-4
  • US $150.00 / ASSAYS
  • more than 99.6%
  • Hebei Mingeng Biotechnology Co., Ltd

PETROLEUM ETHER Spectrum

Petrol puriss., bp 100-140 C Petrol puriss., bp 90-100 C Petroleum Ether, 35-60 C PetroleuM Ether, B.R. 35 DEG -60 DEG C, Reagent, ACS PetroleuM benzine boiling range30-60℃ PetroleuM benzine boiling range60-90℃ PetroleuM benzine boiling range90-120℃ PETROLEUM BENZINE BOILING RANGE 30-50 DE G. C, R. G. PETROLEUM ETHER, SPECTROPHOTOMETRIC GRAD E LIGROIN BP 80-95 C PETROLEUM BENZINE BOILING RANGE 100-140 DEG. C, CHEM. PURE PETROLEUM ETHER 30-60 DEG CAPILLARY GC& PETROLEUM BENZIN BP 80-110 C PETROLEUM BENZIN BP 140-160 C PETROLEUM ETHER A.C.S. REAGENT (SAFETY& PETROLEUM BENZIN BP 100-130 C LIGROIN BP 60-100 C PETROLEUM BENZIN BP 90-100 C PetroleumEther80-100BoilingRange PetroleumEther,Acs PetroleumEther40-60C PetroleumEther60-80C PetroleumEther60-80CGr PetroleumEther60-80BoilingRange PetroleumEtherGr40-60C PetroleumEther100-120BoilingRange PetroleumEther40-60ForHplc petroleun ether Petrleum ether Petroleum ether (60-90℃) Petroleumether35/60,ACS Petroleumether35/60,HPLCGrade Petroleumether40/60,HPLCGrade Petroleumether60/80,HPLCGrade PETROLEUM ETHER DISTILLED IN GLASS PETROLEUM ETHER REAGENT (ACS) Naptha,VM&P benzine 100-140℃ petroleum ether 35/60, environmental grade petroleumbenzin 100-140℃ PETROLEUMETHER,ACS(BULK PETROLEUMETHER,OMNISOLV VARNISHMAKERSANDPRINTERSNAPHTHA PetroleuM Ether, Anhydrous, B.R. 35 DEG -60 DEG C PetroleuM Ether, B.R. 100 DEG -140 DEG C PetroleuM Ether, B.R. 20 DEG -40 DEG C PetroleuM Ether, B.R. 35 DEG -60 DEG C, PestiSolv(R) PetroleuM Ether, B.R. 35 DEG -60 DEG C, UniSolv(R) PetroleuM Ether, B.R. 60 DEG -90 DEG C, Reagent PetroleuM Ether, GR ACS PetroleuM Ether, Non-UV, OMniSolv(R) PetroleuM ether, SuperDry, boiling range 60 - 90 ℃, J&KSeal Petroleum ether4x1L PetroleuM ether 60℃~90℃ RULE 66 MINERAL SPIRITS PVOC MIXTURE 3, WISCONSIN PETROLEUM SPIRIT 60/80 PETROLEUM ETHER 100-140