Diethylaluminiumchlorid
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Diethylaluminiumchlorid Eigenschaften
- Schmelzpunkt:
- -85°C
- Siedepunkt:
- 125°C 50mm
- Dichte
- 0.887 g/mL at 25 °C
- Dampfdruck
- 3 mmHg ( 60 °C)
- Flammpunkt:
- −9 °F
- storage temp.
- 0-6°C
- L?slichkeit
- Miscible with hexane.
- Aggregatzustand
- Solution
- Wichte
- 0.711 (20/4℃)
- Farbe
- Colorless
- Wasserl?slichkeit
- reac H2O [CRC10]
- Sensitive
- Air & Moisture Sensitive
- Merck
- 326
- BRN
- 4123259
- CAS Datenbank
- 96-10-6(CAS DataBase Reference)
- EPA chemische Informationen
- Aluminum, chlorodiethyl- (96-10-6)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher | F,C,N | ||
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R-S?tze: | 14-17-34-67-65-62-51/53-48/20-14/15-11-63-50/53 | ||
S-S?tze: | 36/37/39-45-62-61-43-26-16 | ||
RIDADR | UN 3394 4.2/PG 1 | ||
WGK Germany | 2 | ||
RTECS-Nr. | BD0558000 | ||
F | 10 | ||
TSCA | Yes | ||
HazardClass | 4.3 | ||
PackingGroup | I | ||
HS Code | 29319090 | ||
Giftige Stoffe Daten | 96-10-6(Hazardous Substances Data) |
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Alarmwort | Achtung | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Gefahrenhinweise |
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Sicherheit |
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Diethylaluminiumchlorid Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R14:Reagiert heftig mit Wasser.R17:Selbstentzündlich an der Luft. Spontaneously flammable in air.
R34:Verursacht Ver?tzungen.
R67:D?mpfe k?nnen Schl?frigkeit und Benommenheit verursachen.
R65:Gesundheitssch?dlich: kann beim Verschlucken Lungensch?den verursachen.
R62:Kann m?glicherweise die Fortpflanzungsf?higkeit beeintr?chtigen.
R51/53:Giftig für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.
R48/20:Gesundheitssch?dlich: Gefahr ernster Gesundheitssch?den bei l?ngerer Exposition durch Einatmen.
R14/15:Reagiert heftig mit Wasser unter Bildung hochentzündlicher Gase.
R11:Leichtentzündlich.
R63:Kann das Kind im Mutterleib m?glicherweise sch?digen.
S-S?tze Betriebsanweisung:
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S62:Bei Verschlucken kein Erbrechen herbeiführen. Sofort ?rztlichen Rat einholen und Verpackung oder dieses Etikett vorzeigen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S43:Zum L?schen . . . (vom Hersteller anzugeben) verwenden (wenn Wasser die Gefahr erh?ht, anfügen: "Kein Wasser verwenden").
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
colorless solutionVorbereitung Methode
Ethylaluminum sesquichloride (26.5 kg) added to a nitrogen-purged reactor, was heated to 175 ℃. Then, while the mixture was stirred vigorously, 1.1 kg sodium was added over a 30 min period; the mixture was further heated at 155 – 190 ℃ for 60 min. The diethylaluminum chloride product distilled from the reactor at 100 – 161 ℃ (1.3 – 6.1 kPa). In this example, an excess of ethylaluminum sesquichloride was employed to facilitate draining the voluminous byproduct salt and aluminum solids from the reactor. In an alternate approach, a heavy hydrocarbon oil, added prior to reaction, may be employed to remove the solids in slurry form, permitting the use of a stoichiometric ratio of ethylaluminum sesquichloride and sodium reactants.Allgemeine Beschreibung
Colorless liquid. Dangerous fire and explosion hazard. Used as an intermediate in production of organometallics.Air & Water Reaktionen
Pyrophoric in air [Hawley]. Reacts violently with water, Rose(1961).Reaktivit?t anzeigen
Organometallics, such as DIETHYLALUMINUM CHLORIDE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Organometallics containing halogens (fluorine, chlorine, bromine, iodine) bonded to the metal typically with generate gaseous hydrohalic acids (HF, HCl, HBr, HI) with water.m?gliche Exposition
These materials are used as components of olefin polymerization catalysts. The reader is referred to the entry on “Aluminum alkyls” for additional information on this entry. The aluminum alkyl halides parallel very closely the aluminum alkylsVersand/Shipping
UN3052 Spontaneously combustible. Water reactive releasing large quantities of toxic and deadly hydrogen gas. (Note: this number does not appear in the 49/CFR HazMat tables)l?uterung methode
Distil it from excess dry NaCl (to remove ethyl aluminium dichloride) in a 50-cm column containing a heated nichrome spiral. [Beilstein 4 IV 4403.]Inkompatibilit?ten
The aluminum alkyl halides are strong reducing agents; they react—possibly violently—with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. These chemicals react violently with nitromethaneEthylaluminum sesquichloride reacts explosively with carbon tetrachloride at room temperature. This chemical reacts violently with water, forming corrosive hydrogen chloride and flammable ethane gas. Diethylaluminum chloride may form an explosive product with chlorine azide.Diethylaluminiumchlorid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Activator reagent
Triethylaluminium
Natrium
Chlorethan
Aluminium
Aluminium magnesium alloy powder
Ethyl aluminum chloride
Downstream Produkte
Diethylaluminiumchlorid Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 136)Lieferanten
Firmenname | Telefon | Land | Produktkatalog | Edge Rate | |
---|---|---|---|---|---|
TEKA-FAST LIMITED | +8618601192704 |
info@tekafast.com | China | 76 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21634 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29879 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28172 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 |
sales@chemdad.com | China | 39894 | 58 |
Antai Fine Chemical Technology Co.,Limited | 18503026267 |
info@antaichem.com | CHINA | 9636 | 58 |
SIMAGCHEM CORP | +86-13806087780 |
sale@simagchem.com | China | 17365 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 |
sales@tnjchem.com | China | 34563 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 |
1026@dideu.com | China | 7724 | 58 |
Baoji Guokang Bio-Technology Co., Ltd. | 0917-3909592 13892490616 |
gksales1@gk-bio.com | China | 9311 | 58 |
96-10-6(Diethylaluminiumchlorid)Verwandte Suche:
Acrylnitril
Salicylaldehydhydrazon
Aluminiumchlorid
Diethylzink
Trimethylaluminium
Dimethylzink
Diisobutylaluminiumhydrid
n-Hexan
Triethyldialuminiumtrichlorid
Dimethylaluminiumchlorid
Diethylaluminiumchlorid
Chlordiisobutylaluminium
Aluminiumtrihydrid
- aluminiumdiethylchloride
- Aluminum, chlorodiethyl-
- Diethylchoroaluminum
- DIETHYLALUMINUM CHLORIDE
- CHLORODIETHYLALUMINUM
- Aluminium diethyl monochloride
- Diethylaluminium chloride, 1M solution in hexanes
- Diethylaluminumchloride,97%
- diethylaluminum chloride solution
- aluminum diethyul monochloride
- DIETHYLALUMINUM CHLORIDE, 1.0M SOLUTION IN HEPTANE
- DIETHYLALUMINUM CHLORIDE, 25 WT. % (1.8M ) SOLUTION IN TOLUENE
- DIETHYLALUMINUM CHLORIDE, 1.0M SOLUTION IN HEXANES
- DIETHYLALUMINUM CHLORIDE SOLUTION, ~1 M IN HEXANE
- DIETHYLALUMINUM CHLORIDE STEEL FLASK 0.3 L (NET ~150 G)
- Diethylaluminumchloride,25%w/winheptane,95+%
- Diethylaluminium chloride, 0.9M solution in toluene
- Aluminiumdiethylmonochlorid
- DiethylaluMinuM chloride, 2.0 M solution in hexanes, J&KSeal
- DiethylaluMinuM chloride, 0.9 M solution in toluene, J&KSeal
- DiethylaluMinuM chloride, 1.0 M solution in hexanes, J&KSeal
- DiethylaluMinuM chloride, 0.9 M solution in Toluene, SpcSeal
- DiethylaluMinuM chloride, 1.0 M solution in Hexanes, SpcSeal
- DiethylaluMinuM chloride, 2.0 M solution in hexanes, SpcSeal
- Aluminum,chlorodiethyl-
- aluminumdiethylmonochloride
- Chloro(diethyl)aluminium
- chlorodiethyl-aluminu
- dichlorotetraethyldi-aluminu
- Diethylaluminum monochloride
- diethylaluminummonochloride
- Diethylchloroaluminum
- Diethylaluminum Chloride (ca. 15% in Hexane, ca. 0.87mol/L)
- Chlorodiethylaluminum: (Diethylaluminum chloride)
- Diethylaluminium chloride, 1.1M solution in toluene
- Diethylaluminium chloride1.1M solution in tolueneAcroSeal§3
- Diethylaluminium chloride1M solution in hexanesAcroSeal§3
- Diethylaluminium chloride0.9M solution in tolueneAcroSeal§3
- DIETHYLALMINIUMCHLORIDE
- Diethylaluminum chloride, 96%, 25% w/w in heptane
- Diethylaluminum Chloride, 20% Solution in Hexanes
- Diethylaluminum chloride solution 1.0 in heptane
- Diethylaluminum chloride solution 25t. % in toluene
- Diethylaluminum chloride 97%
- Diethylaluminium chloride, 0.9M solution in toluene, AcroSeal
- Diethylaluminium chloride, 1.1M solution in toluene, AcroSeal
- Diethylaluminium chloride, 1M solution in hexanes, AcroSeal
- Diethylaluminum chloride, 97% (Material solid in non-returnable cylinder)
- Diethylaluminum Chloride, 25% in Toluene
- uminum chL
- DIETHYLALUMINUM CHLORIDE ISO 9001:2015 REACH
- Et2AlCl 1M in heptane
- Diethylaluminum Chloride - 25% in Toluene (about 2M)
- Diethylaluminum Chloride Solution (1M in hexanes)
- chloro(diethyl)alumane
- DEAC
- DIETHYLALUMINIUM CHLORIDE
- Diethylaluminum