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Nabam (ISO)

NABAM Struktur
142-59-6
CAS-Nr.
142-59-6
Bezeichnung:
Nabam (ISO)
Englisch Name:
NABAM
Synonyma:
D-14;NABAM;x-spor;nabame;chembam;carbond;D-14(R);ent9106;nabasan;chem-bam
CBNumber:
CB7722794
Summenformel:
C4H6N2Na2S4
Molgewicht:
256.34
MOL-Datei:
142-59-6.mol

Nabam (ISO) Eigenschaften

Schmelzpunkt:
76-80 °C
Dampfdruck
Negligible
storage temp. 
0-6°C
L?slichkeit
Methanol (Slightly), Water (Slightly)
Aggregatzustand
Solid
Wasserl?slichkeit
ca. 200 g l-1 (room temperature)
Farbe
Off-White to Pale Yellow
Merck 
13,6367
Stabilit?t:
Extremely Hygroscopic
LogP
1.656 (est)
EPA chemische Informationen
Nabam (142-59-6)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xn,N
R-S?tze: 36/37/38-50/53-43-37-22
S-S?tze: 26-36/37/39-61-60-46-24/25-8
RIDADR  UN3077 9/PG 3
RTECS-Nr. FA6825000
HS Code  29302000
Giftige Stoffe Daten 142-59-6(Hazardous Substances Data)
Toxizit?t LD50 orally in rats: 395 ±12 mg/kg (Smith)
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitssch?dlich bei Verschlucken. Akute Toxizit?t oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
H317 Kann allergische Hautreaktionen verursachen. Sensibilisierung der Haut Kategorie 1A Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
H410 Sehr giftig für Wasserorganismen mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 1 Warnung GHS hazard pictogramssrc="/GHS09.jpg" width="20" height="20" /> P273, P391, P501
Sicherheit
P261 Einatmen von Staub vermeiden.
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P501 Inhalt/Beh?lter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen.

Nabam (ISO) Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R50/53:Sehr giftig für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.
R43:Sensibilisierung durch Hautkontakt m?glich.
R37:Reizt die Atmungsorgane.
R22:Gesundheitssch?dlich beim Verschlucken.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S60:Dieses Produkt und sein Beh?lter sind als gef?hrlicher Abfall zu entsorgen.
S46:Bei Verschlucken sofort ?rztlichen Rat einholen und Verpackung oder Etikett vorzeigen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
S8:Beh?lter trocken halten.

Chemische Eigenschaften

Colorless crystals when pure. Easily sol-uble in water.

Verwenden

Nabam provides protection against fungal diseases of cotton, capsicums and onions when applied to soil.

Definition

ChEBI: A dithiocarbamate salt that is the disodium salt of ethylenebis(dithiocarbamic acid). A fungicide, algicide and bactericide used on various crops including on cotton, capsicums, onions and rice crops, it is considered to be a carcinogen, so is not licensed for use within the European Union. Mixing nabam with zinc sulfate affords the fungicide zineb.

Allgemeine Beschreibung

Colorless to light amber solid with a a slight odor. Mixes with water.

Air & Water Reaktionen

Water soluble. Decomposes in boiling hot to give poisonous hydrogen sulfide and flammable carbon disulfide.

Reaktivit?t anzeigen

NABAM is a dithiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.

Hazard

Irritant to skin and mucous membranes, nar-cotic in high concentrations, use may be restricted.

Health Hazard

Contact with liquid irritates eyes and may cause mild to severe erythema of skin as well as sensitization reactions.

Brandgefahr

Behavior in Fire: If water solution boils, poisonous hydrogen sulfide and highly flammable carbon disulfide vapors form.

Landwirtschaftliche Anwendung

Fungicide, Algaecide, Herbicide, Microbiocide: Nabam is a broad-spectrum fungicide/bactericide/ algaecide used to prevent crop damage by fungi, to protect harvested products from deterioration, and as an industrial microbiocide. As a result of the U.S. EPA review of nabam in 1989, all food uses were voluntarily canceled by the manufacturers except for one FDA-regulated food use on sugar mill grinding, crusher and/or diffuser systems, e.g., processing water systems. Registered only for nonfood application. Not approved for use in EU countries. Registered for use in the U.S. and Canada.

Handelsname

AMA-30®, Kemira Chemical (Finland); CAMBELL’S® NABAM SOIL FUNGICIDE; CARBON D®; NALCO D-62C44®; CHEM-BAM®; DITHANE A-40®; DITHANE A-46®; DITHANE D-14®[C]; NAFUN-IPO®; NALCO® D-62C44; PARZATE®; SPRING-BAK®

Sicherheitsprofil

intraperitoneal route. Experimental teratogenic and reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx, Na2O, and SOx. See also CARBAMATES.

m?gliche Exposition

Nabam is a broad spectrum dithiocarbamate fungicide/bactericide/algaecide/herbicide/microbiocide used to prevent crop damage by fungi, to protect harvested products from deterioration, and as an industrial microbiocide. As a result of the United States Environmental Protection Agency review of nabam in 1989, all food uses were voluntarily canceled by the manufacturers except for one FDA-regulated food use on sugar mill grinding, crusher, and/or diffuser systems, e.g., processing water systems. All other uses of nabam are for the control of algae, slime-forming bacteria, and fungi in indoor nonfood environments, paper mills, water cooling systems, drilling mud and packer fluids, and secondary oil recovery water system. Registered in the United States only for nonfood application.

Stoffwechselwegen

Nabam and other alkylenebis(dithi0carbamate) fungicides are degraded and metabolised via a common pathway. Limited information is available to describe the fate of nabam in soil and animals. Based on information generated with structurally similar compounds (see maneb, zineb), the initial degradation reaction of nabam in water and plants involves the dissociation of the metal complex and decomposition to numerous degradation products including ethylenethiourea (ETU) and ethyleneurea (EU) as major products (Scheme 1).

Versand/Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard Class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

l?uterung methode

It crystallises (as hexahydrate) from aqueous ethanol. It is a skin irritant. [Beilstein 4 III 149, 4 IV 234.]

Inkompatibilit?ten

Combustible material. Dust may form explosive mixture in air, water, acid, oxidizing materials. Heat or contact with moisture or acids causes rapid decomposition and the generation of toxic and flammable hydrogen sulfide and carbon disulfide. Dithiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of dithiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of dithiocarbamate with aldehydes, nitrides, and hydrides. Dithiocarbamate are incompatible with acids, peroxides, and acid halides. Corrosive to iron, copper, brass, and zinc metals, especially in the presence of moisture. Heat alkalies (lime), moisture can cause decomposition. Decomposes on prolonged storage; by moisture, light, and heat. Degradation produces ethylene thiourea.

Waste disposal

Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. A potential candidate for liquid injection incineration at a temperature range of 650 1600℃ and a residence time 0.1-2 seconds. Also, a potential candidate for rotary kiln incineration at a temperature range of 820 1600℃ and residence times of seconds for liquids and gases, and hours for solids.

Nabam (ISO) Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Nabam (ISO) Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 47)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886
info@dakenam.com China 18781 58
SHANDONG ZHI SHANG CHEMICAL CO.LTD
+86 18953170293
sales@sdzschem.com China 2930 58
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28172 58
Hubei xin bonus chemical co. LTD
86-13657291602
linda@hubeijusheng.com CHINA 22963 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873
sales@chemdad.com China 39894 58
SUZHOU SENFEIDA CHEMICAL CO.,LTD
+86-0512-83500002 +8615195660023
sales@senfeida.com China 23046 58
Shanghai Likang New Materials Co., Limited
+86-16631818819 +86-17736933208
3684455296@qq.com China 9300 58
Mainchem Co., Ltd. +86-0592-6210733
sale@mainchem.com China 32343 55
Chizhou Kailong Import and Export Trade Co., Ltd.
xg01_gj@163.com China 9484 50
Shandong Xiya Chemical Co., Ltd. 4009903999 13395398332
sales@xiyashiji.com China 20806 60

142-59-6(Nabam (ISO))Verwandte Suche:


  • nabam (ISO) disodium ethylenebis(N,N'-dithiocarbamate)
  • D-14
  • 1,2-Ehanediylbiscarbamodithioicaciddisodiumsalt
  • CarbaModithioic acid,N,N'-1,2-ethanediylbis-, sodiuM salt (1:2)
  • 1,2-ethanediylbiscarbamodithioicaciddisodiumsalt
  • 1,2-ethanediylbis-carbamodithioicacidisodiumsalt
  • Carbamodithioicacid,1,2-ethanediylbis-,disodiumsalt
  • carbond
  • chembam
  • chem-bam
  • x-spor
  • D-14(R)
  • Dithane D-14
  • DITHANE S(R)
  • Disodium ethylene-1,2-bis-dithiocarbamate
  • DISODIUM ETHYLENE BIS[DITHIOCARBAMATE]
  • CHEM BAM(R)
  • NABAM
  • PARZATE LIQUID(R)
  • NABAM TECHNICAL MIXTURE, PESTANAL (DISOD
  • NABAM, 1GM, NEAT
  • SodiumEthyleneBisDithioCarbamate
  • Ethylene bis(dithiocarbamic acid), sodium salt
  • nabam (bsi,iso)
  • Ethylenebisdithiocarbamate, disodium.
  • dinatrium-(n,n’-aethylen-bis(dithiocarbamat))
  • dinatrium-(n,n’-ethyleen-bis(dithiocarbamaat))
  • di-natrium-aethylenbisdithiocarbamat
  • disodium1,2-ethanediylbis(carbamodithioate)
  • dithanea-40
  • dithaned-14(discontinued)
  • ent9106
  • ethylen-bis-dithiokarbamansodny
  • ethylenebis(dithiocarbamate),disodiumsalt
  • ethylenebis(dithiocarbamicacid)disodiumsalt
  • ethylenebis(dithio-carbamicacidisodiumsalt
  • n,n’-ethylenebis(dithiocarbamatedesodium)
  • n,n’-ethylenebis(dithiocarbamatedesodium)(french)
  • n,n’-etilen-bis(ditiocarbammato)disodio
  • nabame
  • nabame(french)
  • nabasan
  • nabasan(discontinued)
  • nafunipo
  • parzateliquid
  • spring-bak
  • sodium ethane-1,2-diyldicarbamodithioate
  • 142-59-6
  • NaSSCNHCH2CH2NHCSSNa
  • C4H6N2Na2S4
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