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S-Ethyl-1-perhydroazepinthioat

Molinate Struktur
2212-67-1
CAS-Nr.
2212-67-1
Bezeichnung:
S-Ethyl-1-perhydroazepinthioat
Englisch Name:
Molinate
Synonyma:
G 10;sc998;BUD31;Yalan;Yulan;Felan;Jalan;ordam;HYDRAM;R-4572
CBNumber:
CB4768126
Summenformel:
C9H17NOS
Molgewicht:
187.3
MOL-Datei:
2212-67-1.mol

S-Ethyl-1-perhydroazepinthioat Eigenschaften

Schmelzpunkt:
<25 °C
Siedepunkt:
202°C (10 mmHg)
Dichte
1.06
Brechungsindex
1.5250 (estimate)
Flammpunkt:
100 °C
storage temp. 
0-6°C
L?slichkeit
Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
pka
-1.22±0.20(Predicted)
Aggregatzustand
Liquid
Farbe
Amber
Wasserl?slichkeit
0.08 g/100 mL
BRN 
1239196
LogP
3.210
CAS Datenbank
2212-67-1(CAS DataBase Reference)
NIST chemische Informationen
Molinate(2212-67-1)
EPA chemische Informationen
Molinate (2212-67-1)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher T,N,Xn
R-S?tze: 20/22-40-43-48/22-63-50/53-62
S-S?tze: 36/37-46-60-61
RIDADR  2902
WGK Germany  3
RTECS-Nr. CM2625000
HazardClass  6.1(b)
PackingGroup  III
Giftige Stoffe Daten 2212-67-1(Hazardous Substances Data)
Toxizit?t LC50 (96-hour) for bluegill sunfish 29–30 mg/L, goldfish 30 mg/L, mosquito fish 16.4 mg/L, rainbow trout 0.2–1.3 mg/L (Hartley and Kidd, 1987); acute oral LD50 of technical molinate for rats and mice 720 and 795 mg/kg, respectively (Ashton and Monaco, 1991), 501 mg/kg (RTECS, 1985).
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H317 Kann allergische Hautreaktionen verursachen. Sensibilisierung der Haut Kategorie 1A Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H351 Kann vermutlich Krebs verursachen. Karzinogenit?t Kategorie 2 Warnung P201, P202, P281, P308+P313, P405,P501
H361 Kann vermutlich die Fruchtbarkeit beeintr?chtigen oder das Kind im Mutterleib sch?digen. Reproduktionstoxizit?t Kategorie 2 Warnung P201, P202, P281, P308+P313, P405,P501
H410 Sehr giftig für Wasserorganismen mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 1 Warnung GHS hazard pictogramssrc="/GHS09.jpg" width="20" height="20" /> P273, P391, P501
Sicherheit
P201 Vor Gebrauch besondere Anweisungen einholen.
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P308+P313 BEI Exposition oder falls betroffen: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen.

S-Ethyl-1-perhydroazepinthioat Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R20/22:Gesundheitssch?dlich beim Einatmen und Verschlucken.
R40:Verdacht auf krebserzeugende Wirkung.
R43:Sensibilisierung durch Hautkontakt m?glich.
R48/22:Gesundheitssch?dlich: Gefahr ernster Gesundheitssch?den bei l?ngerer Exposition durch Verschlucken.
R63:Kann das Kind im Mutterleib m?glicherweise sch?digen.
R50/53:Sehr giftig für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.
R62:Kann m?glicherweise die Fortpflanzungsf?higkeit beeintr?chtigen.

S-S?tze Betriebsanweisung:

S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S46:Bei Verschlucken sofort ?rztlichen Rat einholen und Verpackung oder Etikett vorzeigen.
S60:Dieses Produkt und sein Beh?lter sind als gef?hrlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.

Verwenden

Selective herbicide used to control the germination of annual grasses and broadleaved weeds in rice crops.

Allgemeine Beschreibung

Clear liquid with aromatic odor. Non corrosive. Used as an herbicide.

Air & Water Reaktionen

Water soluble. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.

Reaktivit?t anzeigen

Molinate is a thiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.

Landwirtschaftliche Anwendung

Herbicide: Molinate is a selective herbicide used on rice for the control of water grass and other weeds.

Handelsname

ARROSOLO®; FELAN®; HIGALNATE®; HYDRAM®; JALAN®; MALERBANE-GIAVONI-L®;ORDAM®; ORDRAM®; R-4572®; RICECO; SAKKIMOL®; STAUFFER R 4,572®; YALAN®; YULAN®

Environmental Fate

Soil. Hydrolyzes in soil forming ethyl mercaptan, carbon dioxide and dialkylamine (half-life approximately 2–5 weeks) (Hartley and Kidd, 1987). At recommended rates of application, the half-life of molinate in moist loam soils at 21–27°C is approximately 3 weeks (Humburg et al., 1989). Rajagopal et al. (1989) reported that under flooded conditions, molinate was hydroxylated at the 3- and 4-position with subsequent oxidation forming many compounds including molinate sulfoxide, carboxymethyl molinate, hexahydroazepine- 1-carbothioate, 4-hydroxymolinate, 4-hydroxymolinate sulfoxide, hexahydroazepine, S-methyl hexahydroazepine-1-carbothioate, 4-ketomolinate, 4-hydroxyhexahydroazepine, 4-hydroxy-N-acetyl-hexahydroazepine, carbon dioxide and bound residues.
Plant. Molinate is rapidly metabolized by plants releasing carbon dioxide and naturally occurring plant constituents (Humburg et al., 1989).
Photolytic. Molinate in a hydrogen peroxide solution (120 mM) was irradiated by UV light (l = 290 nm) at 23°C. The major photooxidation products were the two isomers of 2-oxomolinate (20% yield) and s-molinate oxide (5% yield) (Draper and Crosby, 1984).
Half-lives of 180 and 120 hours were observed using one and two equivalents of hydrogen peroxide, respectively (Draper and Crosby, 1984). Molinate has a UV absorption maximum at 225 nm and no absorption at wavelengths >290 nm. Therefore, molinate is not expected to undergo aqueous photolysis under natural sunlight (l = 290 nm). In the presence of tryptophan, a naturally occurring photosensitizer, molinate in aqueous solution photodegraded to form 1-((ethylsulfinyl)carbonyl)hexahydro-1H-azepine, S-ethyl hexahydro-2- oxo-1H-azepine-1-carbothioate and hexamethyleneimine (Soderquist et al., 1977).
Chemical/Physical. Metabolites identified in tap water were molinate sulfoxide, 3- and 4-hydroxymolinate, ketohexamethyleneimine and 4-ketomolinate (Verschueren, 1983).

Stoffwechselwegen

Juvenile white sturgeon and common carp are exposed to 14C-molinate in a flow-through metabolism system and oxidize molinate to form several products and hydrolyze or conjugate with glutathione (GSH), the sulfoxide, or sulfone. Both fish form a D-glucuronic acid conjugate. The higher toxicity of molinate in common carp may be due to greater bioconcentration, slower depuration, and less efficient metabolic deactivation. In the blood of common carp, molinate is oxidized by erythrocytes to the sulfoxide and possibly the sulfone, then conjugated with GSH or cysteine and cleaved to form mercapturic acid in both erythrocytes and plasma. Conjugation and possible hemoglobin carbamylation occur only after sulfoxidation of molinate. Molinate is distributed uniformly throughout the soil layers, and its degradation products are identified as 2-oxomolinate, 4-oxomolinate, molinate acid, and hexamethyleneimine. In rice plants, 4-hydroxymolinate, 2-oxomolinate, 4-oxomolinate, S-ethyl-N-carboxymethylthiocarbamate, molinate acid, and molinate alcohol are detected. By the soil microorganisms, oxidation of the S-ethyl moiety is considered to be the main pathway, and hydroxy and oxoderivatives on the azepine ring are identified.

S-Ethyl-1-perhydroazepinthioat Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


S-Ethyl-1-perhydroazepinthioat Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 80)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hubei xin bonus chemical co. LTD
86-13657291602
linda@hubeijusheng.com CHINA 22963 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873
sales@chemdad.com China 39894 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427
sales@conier.com China 49374 58
career henan chemical co
+86-0371-86658258 +8613203830695
factory@coreychem.com China 29811 58
Hangzhou MolCore BioPharmatech Co.,Ltd.
+86-057181025280; +8617767106207
sales@molcore.com China 49734 58
Hebei Weibang Biotechnology Co., Ltd
+8617732866630
bess@weibangbio.com China 18151 58
GIHI CHEMICALS CO.,LIMITED
+8618058761490
info@gihichemicals.com China 49978 58
SUZHOU SENFEIDA CHEMICAL CO.,LTD
+86-0512-83500002 +8615195660023
sales@senfeida.com China 23046 58
Aladdin Scientific
+1-+1(833)-552-7181
sales@aladdinsci.com United States 57505 58
Mainchem Co., Ltd. +86-0592-6210733
sale@mainchem.com China 32343 55

2212-67-1(S-Ethyl-1-perhydroazepinthioat)Verwandte Suche:


  • perhydroazepin-1-carbothioate
  • S-Aethyl-N-hexahydro-1H-azepinthiolcarbamat
  • s-aethyl-n-hexahydro-1h-azepinthiolcarbamat[german]
  • sc998
  • S-Ethyl 1-azepanecarbothioate
  • S-Ethyl 1-hexamethyleneiminothiocarbamate
  • S-Ethyl Hexahydroazepine-1-carbothioate
  • S-Ethyl N,N-hexamethylenothiocarbamate
  • s-ethyl1-hexamethyleneiminothiocarbamate
  • s-ethylazepane-1-carbothioate
  • s-ethylesterhexahydro-1h-azepine-1-carbothioicacid
  • s-ethylhexahydroazepine-1-carbothioate
  • S-Ethyl-N-hexamethylenethiocarbamate
  • s-ethylperhydroazepin-1-carbothioate
  • s-ethylperhydroazepine-1-thiocarboxylate
  • Stauffer R-4,572
  • staufferr-4,572
  • HYDRAM
  • Ethyl 1-hexamethyleneiminecarbothioate
  • ETHYL-1-HEXAMETHYLENE IMINE CARBOTHIOLATE
  • molinate (bsi,iso,jmaf)
  • MOLINATE-(S-ETHYLHEXAHYDRO-AZEPINE-1-CARBOTHIOATE
  • AZEPINE-1-CARBOTHIOICACID,HEXAHYDRO-,S-ETHYLESTER
  • H-Azepine-1-carbothioic acid, hexahydro-S-ethyl ester
  • Hexahydro-1H-azepine-1-carbothioate, S-ethyl
  • molinate (ISO) S-ethyl 1-perhydroazepinecarbothioate S-ethyl perhydroazepine-1-carbothioate
  • azepane-1-carbothioic acid S-ethyl ester
  • s-Ethyl-n-hexahydro-1h-azepinthiolcarbamat
  • 1-(Ethylcarbonyl)azepane
  • 1-Azepanethiocarboxylic acid S-ethyl
  • Molinate Standard
  • Molinate 250mg [2212-67-1]
  • Ordram(ICI)
  • R-4572(Zeneca)
  • Ssakkimol
  • MOLINAT PESTANAL (S-ETHYL N,N-HEXA- METH
  • MOLINATE, 250MG, NEAT
  • MOLINATE PESTANAL(TM)
  • Ethyl 1-hexamethylene imine carbothiolalate
  • Ethyl azepane-1-carbothioate
  • G 10
  • Oxonate
  • 1h-azepine-1 carbothioic acid hexahydro-s-ethyl ester
  • BUD31
  • R-4572
  • ORDRAM
  • Ordram granules
  • ORDRAM(R)
  • S-ETHYLHEXAHYDRO-1H-AZEPINE-1-CARBOTHIOATE
  • S-ETHYL N,N-HEXAMETHYLENETHIOCARBAMATE
  • SAKKIMOL
  • Morinate granules
  • Molinate granules
  • MOLINAT
  • MOLINATE
  • Yalan
  • Yulan
  • Felan
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