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p-Mentha-1,4-dien

GAMMA-TERPINENE Struktur
99-85-4
CAS-Nr.
99-85-4
Bezeichnung:
p-Mentha-1,4-dien
Englisch Name:
GAMMA-TERPINENE
Synonyma:
γ-Terpinene;Moslene;G-TERPINENE;P-MENTHA-1,4-DIENE;1,4-Cyclohexadiene, 1-methyl-4-(1-methylethyl)-;Crithmene;γ- Terpinen;1-ISOPROPYL-4-METHYL-1,4-CYCLOHEXADIENE;1-methyl-4-(1-methylethyl)-1,4-cyclohexadiene;1,4-cyclohexadien, 1-methyl-4-(1-methylethyl)- [=gamma-terpinene]
CBNumber:
CB4443087
Summenformel:
C10H16
Molgewicht:
136.23
MOL-Datei:
99-85-4.mol

p-Mentha-1,4-dien Eigenschaften

Schmelzpunkt:
-59.03°C (estimate)
Siedepunkt:
182 °C (lit.)
Dichte
0.85 g/mL at 25 °C (lit.)
Dampfdichte
4.7 (vs air)
Dampfdruck
~0.7 mm Hg ( 20 °C)
FEMA 
3559 | P-MENTHA-1,4-DIENE
Brechungsindex
n20/D 1.474(lit.)
Flammpunkt:
125 °F
storage temp. 
2-8°C
L?slichkeit
water: soluble5%, clear, colorless to faintly yellow
Aggregatzustand
Powder or Cyrstals
Farbe
White
Wichte
0.849 (20/4℃)
Geruch (Odor)
at 10.00 % in dipropylene glycol. oily woody terpene lemon/lime tropical herbal
Geruchsart
terpenic
Wasserl?slichkeit
8.678mg/L(23.5 ºC)
JECFA Number
1340
Merck 
14,9170
BRN 
2038347
Stabilit?t:
Light Sensitive
InChIKey
YKFLAYDHMOASIY-UHFFFAOYSA-N
LogP
5.4 at 25℃
CAS Datenbank
99-85-4(CAS DataBase Reference)
EPA chemische Informationen
.gamma.-Terpinene (99-85-4)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xi
R-S?tze: 10-36/37/38
S-S?tze: 26-36
RIDADR  UN 2319 3/PG 3
WGK Germany  2
RTECS-Nr. OS8070000
10-23
HazardClass  3.2
PackingGroup  III
HS Code  29021990
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H226 Flüssigkeit und Dampf entzündbar. Entzündbare Flüssigkeiten Kategorie 3 Warnung
H411 Giftig für Wasserorganismen, mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 2
Sicherheit
P201 Vor Gebrauch besondere Anweisungen einholen.
P202 Vor Gebrauch alle Sicherheitshinweise lesen und verstehen.
P210 Von Hitze, hei?en Oberfl?chen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.
P233 Beh?lter dicht verschlossen halten.
P273 Freisetzung in die Umwelt vermeiden.
P308+P313 BEI Exposition oder falls betroffen: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen.

p-Mentha-1,4-dien Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R10:Entzündlich.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.

Chemische Eigenschaften

clear liquid

Occurrence

Reported found in papaya fruit, tea tree oil, tangerine, citrus, mandarins, Finocchoi fennel oil, papaya fruit, citrus peel oils, etc.

Verwenden

γ-Terpinene can be used as:
  • Hydrogen precursor in the catalytic transfer hydrogenation of silyl enol ethers.
  • A reference compound in the kinetic study of ozonolysis of (E)-β-farnesene.
  • A hydrogen atom donor in the Cr-catalyzed radical cyclization of halo acetals.

synthetische

From geranyl pyrophosphate by migration of a positive-charge, hydrid shift from the isopropyl side chain into the cyclohexenoid ring; from the essential oil of Lantana camara; also from p-cymene by the action of sodium and alcohol in liquid ammonia.

Allgemeine Beschreibung

γ-Terpinene, volatile essential oil derived from Melaleuca alternifolia, shows antimicrobial properties against various human pathogens. It is also extracted from Lippia multiflora. The antioxidant, anti-inflammatory and anti-proliferative activities of γ-terpinene is studied.

Pharmakologie

Combinations of terpenes, such as terpinene, with nonionic surfactants and stabilizers have been patented for use as gallstone solvents. Artificial or human cholesterol calculi placed in terpinene with or without human bile at 37°C were dissolved within 1-2 hr (Hisamitsu Pharmaceutical Co., Inc., 1973).

Sicherheitsprofil

Moderately toxic by ingestion. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

p-Mentha-1,4-dien Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


p-Mentha-1,4-dien Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 276)Lieferanten
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99-85-4(p-Mentha-1,4-dien)Verwandte Suche:


  • 1-ISOPROPYL-4-METHYL-1,4-CYCLOHEXADIENE P-MENTHA-1,4-DIENE
  • 1,4-P-MENTHADIENE
  • GAMMA-TERPINENE
  • FEMA 3559
  • Chrithmene
  • gamma-Terpinene, stabilized, 98+%
  • γ-terpinene,1-methyl-4-(1-methylethyl)-1,4-cyclohexadiene
  • 1-methyl-4-propan-2-yl-cyclohexa-1,4-diene
  • PARA-MENTHA-1,4-DIENE
  • GAMMA TERPINENE P&F
  • GAMMA-TERPINENE 95+% FCC
  • GAMMA-TERPINENE, TERPENE STANDARD
  • Y-TERPINENE WITH GC
  • Gamma-terpinene, 98+%, stabilized
  • gamma-Terpinene, stabilized
  • 1-Methyl-4-(1-methylethyl)-4-cy
  • γ-Terpinene, stabilized
  • γ-Terpinene,1-Isopropyl-4-methyl-1,4-cyclohexadiene, p-Mentha-1,4-diene
  • gaMMa-Terpinene, 97%, stabilized
  • gaMMa-Terpinene puruM, >=97.0% (GC)
  • γ-Terpinene, 95%, 95%
  • TERPINENE, GAMMA-
  • 1,4-Cyclohexadiene, 1-methyl-4-isopropyl-
  • 1-isopropyl-4-methyl-1,4-cyclohexadiene (gamma-terpinene)
  • 1-Isopropyl-4-methyl-cyclohexa-1,4-diene
  • 1-methyl-4-(1-methylethyl)-4-cyclohexadiene
  • 1-Methyl-4-isopropyl-1,4-cyclohexadiene
  • 1-methyl-4-isopropyl-4-cyclohexadiene
  • 1-Methyl-4-isopropylcyclohexadiene-1,4
  • 4-Cyclohexadiene,1-methyl-4-(1-methylethyl)-1
  • 4-Isopropyl-1-methyl-1,4-cyclohexadiene
  • gamma-Terpinen
  • gamma-Terpinene solution
  • gamma-Terpinene@100 μg/mL in Methanol
  • NATURAL Y-TERPINENES
  • GAMMA-TERPINENE 99-85-4
  • Γ-terpinene (Γ-terpinene)
  • 1-ISOPROPYL-4-METHYL-1,4-CYCLOHEXADIENE
  • 1,4-cyclohexadien, 1-methyl-4-(1-methylethyl)- [=gamma-terpinene]
  • 1,4-Cyclohexadiene, 1-methyl-4-(1-methylethyl)-
  • G-TERPINENE
  • γ- Terpinen
  • P-MENTHA-1,4-DIENE
  • 1-methyl-4-(1-methylethyl)-1,4-cyclohexadiene
  • Crithmene
  • Moslene
  • γ-Terpinene
  • γ-Terpinene 1000 μg/mL in Isopropanol
  • gama-Terpinolene
  • Terpinene
  • γ-Terpinene in Isopropanol
  • 99-85-4
  • 98-85-4
  • Monocyclic Monoterpenes
  • TA - TE
  • Organic Building Blocks
  • Cyclic
  • Building Blocks
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