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O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphat

Tolclofos-methyl Struktur
57018-04-9
CAS-Nr.
57018-04-9
Bezeichnung:
O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphat
Englisch Name:
Tolclofos-methyl
Synonyma:
S-3349;RIZOLEX;Basilex;Risolex;Risolex(TM);Tolcofos-methyl;olclofos-methyl;Methyl tolclofo;TOLCLOFOS-METHYL;Methyl tolclofos
CBNumber:
CB2451996
Summenformel:
C9H11Cl2O3PS
Molgewicht:
301.13
MOL-Datei:
57018-04-9.mol

O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphat Eigenschaften

Schmelzpunkt:
78-80°C
Siedepunkt:
338.5±52.0 °C(Predicted)
Dichte
1.401±0.06 g/cm3(Predicted)
Dampfdruck
1.84 x 10-3 (Pa 25 °C)
Flammpunkt:
>100 °C
storage temp. 
2-8°C
L?slichkeit
Chloroform (Slightly), DMSO (Slightly)
Aggregatzustand
Solid
Wasserl?slichkeit
1.10 mg l-1 (25 °C)
Farbe
White to off-white
Merck 
13,9587
BRN 
2136521
InChIKey
OBZIQQJJIKNWNO-UHFFFAOYSA-N
LogP
4.560
CAS Datenbank
57018-04-9(CAS DataBase Reference)
NIST chemische Informationen
Phosphorothioic acid, o-(2,6-dichloro-4-methylphenyl) o,o-dimethyl ester(57018-04-9)
EPA chemische Informationen
Tolclofos-methyl (57018-04-9)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xi,N
R-S?tze: 43-50/53
S-S?tze: 22-24/25-61-60-37-24
RIDADR  UN 3077 9 / PGIII
WGK Germany  3
RTECS-Nr. TF0460000
HS Code  29201900
Giftige Stoffe Daten 57018-04-9(Hazardous Substances Data)
Toxizit?t LD50 in male, female rats, male, female mice (mg/kg): ~5000, ~5000, 3500, 3600 orally; all >5000 dermally; ~5000, 4900, 1070, 1260 i.p.; all >5000 s.c. (Ohtsuki, Fujinami)
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H317 Kann allergische Hautreaktionen verursachen. Sensibilisierung der Haut Kategorie 1A Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H410 Sehr giftig für Wasserorganismen mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 1 Warnung GHS hazard pictogramssrc="/GHS09.jpg" width="20" height="20" /> P273, P391, P501
Sicherheit
P261 Einatmen von Staub vermeiden.
P272 Kontaminierte Arbeitskleidung nicht au?erhalb des Arbeitsplatzes tragen.
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P302+P352 BEI BERüHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckm??ig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.
P333+P313 Bei Hautreizung oder -ausschlag: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen.

O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphat Chemische Eigenschaften,Einsatz,Produktion Methoden

S-S?tze Betriebsanweisung:

S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.

Verwenden

Tolclofos-methyl is a non-systemic organophosphorus fungicide with both protective and curative activities that control soil-borne diseases caused by Rhizoctonia solani, Corticium rolfsii, Tphula incamata and Typhula ishikariensis in/on potatoes, sugar beet, cotton and peanuts.

Definition

ChEBI: An organic thiophosphate that is 2,6-dichloro-4-methylphenol in which the hydrogen of the hydroxy group group has been replaced by a dimethoxyphosphorothioyl group. Tolclofos-methyl is a phospholipid biosynthesis inhibitor and fungicide that is used for co trolling soil-borne diseases caused by Typhula incarnata, Corticium rolfsii, Typhula ishikariensis, and Rhizoctonia solani.

Stoffwechselwegen

Tolclofos-methyl underwent common degradation and metabolic pathways in water, soil, plants and animals. These reactions are well documented for most organophosphorus compounds and include oxidative desulfuration, hydroxylation/oxidation of the 4-methyl group to the alcohol and carboxylic acid, cleavage of the P-O-aryl linkage, O-demethylation and conjugation. In addition to the above reactions, photolytic isomerisation to the thionate (P=S) was also observed. A schematic presentation of the primary metabolic pathways for tolclofosmethyl is illustrated in Scheme 1.

O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphat Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphat Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 169)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hebei Weibang Biotechnology Co., Ltd
+8617732866630
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Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21634 55
Hangzhou FandaChem Co.,Ltd.
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FandaChem@Gmail.com China 9087 55
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18871490254
linda@hubeijusheng.com CHINA 28172 58
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sales@chemdad.com China 39894 58
CONIER CHEM AND PHARMA LIMITED
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sales@conier.com China 49374 58
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+8617531190177
peter@yan-xi.com China 5857 58
SIMAGCHEM CORP
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sale@simagchem.com China 17365 58
TargetMol Chemicals Inc.
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marketing@targetmol.com United States 32161 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763
sales@tnjchem.com China 34563 58

57018-04-9(O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphat)Verwandte Suche:


  • 2,6-dichloro-4-methylphenyl o,o-dimethyl phosphorothioate
  • Dimethyl O-(2,6-dichloro-4-methylphenyl) phosphorothioate
  • S-3349
  • RIZOLEX
  • O-(2,6-DICHLORO-4-METHYLPHENYL) O,O-DIMETHYL PHOSPHOROTHIOATE
  • TOLCLOFOS-METHYL
  • Basilex
  • Dichloro-4-methylphenyl-O,O-dimethyl phosphorothioate
  • o-(2,6-Dichloro-4-methylphenyl) o,o-dimethyl thiophosphate
  • o-(2,6-dichloro-p-tolyl)o,o-dimethylesterofphosphorothioicacid
  • O-(2,6-Dichloro-p-tolyl)-O,O-dimethylthiophosphate
  • o,o-dimethylo-(2,6-dichloro-4-methylphenyl)phosphorothioate
  • Phosphorothioic acid, O-(2,6-dichloro-4-methylphenyl) O,O-dimethyl ester
  • Phosphorothioicacid,esters,O-(2,6-dichloro-4-methylphenyl)-O,O-dimethylester
  • phosphorothioicacid,o-(2,6-dichloro-4-methylphenyl)o,o-dimethylester
  • phosphorothioicacid,o-(2,6-dichloro-p-tolyl)o,o-dimethylester
  • Risolex
  • Tolcofos-methyl
  • BENZTHIAZURON PESTANAL, 100 MG
  • tolclofos-methyl (bsi,iso)
  • TOLCHLOFOS-METHYL
  • O,O-dimethyl-O-(2,6-dichloro-p-tolyl) phosphorothioate
  • (2,6-Dichloro-4-methylphenoxy)-dimethoxy-sulfanylidenephosphorane
  • Phosphorothioic acid O-(2,6-dichloro-4-methylphenyl) O,O-dimethyl
  • Thiophosphoric acid O-(2,6-dichloro-4-methylphenyl)O,O-dimethyl ester
  • Thiophosphoric acid O,O-dimethyl O-(2,6-dichloro-4-methylphenyl) ester
  • Thiophosphoric acid=O-(2,6-dichloro-4-methylphenyl)=O,O-dimethyl ester
  • O-2,6-DICHLORO-P-TOLYLO,O-DIMETHYLPHOSPHOROTHIOATE
  • Tolclofos-methyl Standard
  • Tolclofos-methyl Solution, 100ppm
  • Tolclofos-Methyl 500mg [57018-04-9]
  • Risolex(TM)
  • Tolclofos-methyl Solution, 1000ppm
  • Tolclofos-methyl@1000 μg/mL in Acetone
  • Tolclofos-methyl @100 μg/mL in MeOH
  • Tolchlophos-methyl
  • Tolclofos-MethylStock,100mg/L,1ml
  • olclofos-methyl
  • TIANFU-CHEM - Tolclofos-methyl
  • Methyl tolclofos
  • Methyl tolclofo
  • Tolclofos-methyl Solution in Methanol
  • Tolclofos-methyl Solution in Hexane
  • Tolclofos-methyl-d6 (O,O-dimethyl-d6) in methanol
  • Tolclofos Methyl in Acetone
  • Tolclofos Methyl in Methanol
  • C17590000 Tolclofos-methyl
  • L17590000CY Tolclofos-methyL10μg/mLin Cycloh
  • Tolclofos-methyl 10.0 μg/ml Ethyl acetate
  • Tolclofos-methyl 100 μg/ml Acetonitrile
  • Tolclofos-methyl 100 μg/ml Toluene
  • 57018-04-9
  • C9H11Cl2O3PS
  • FUNGICIDE
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