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3-Chlorpropan-1-ol

3-Chloro-1-propanol Struktur
627-30-5
CAS-Nr.
627-30-5
Bezeichnung:
3-Chlorpropan-1-ol
Englisch Name:
3-Chloro-1-propanol
Synonyma:
3-CHLOROPROPAN-1-OL;3-Chloropropanol;TRIMETHYLENE CHLOROHYDRIN;1-Propanol, 3-chloro-;3-Chloropropyl alcohol;NSC 60190;Chloro-1-propa;oro-1-propanoL;3-CHLORPROPANOL;Chloro-1-propanol
CBNumber:
CB2407458
Summenformel:
C3H7ClO
Molgewicht:
94.54
MOL-Datei:
627-30-5.mol

3-Chlorpropan-1-ol Eigenschaften

Schmelzpunkt:
-20 °C
Siedepunkt:
160-162 °C(lit.)
Dichte
1.131 g/mL at 25 °C(lit.)
Brechungsindex
n20/D 1.445(lit.)
Flammpunkt:
164 °F
storage temp. 
0-6°C
L?slichkeit
50g/l (slow decomposition)
Aggregatzustand
Liquid
pka
14.73±0.10(Predicted)
Wichte
1.14
Farbe
Clear colorless to yellow
PH
3-4 (100g/l, H2O, 20℃)
Wasserl?slichkeit
300 g/L (20 ºC)
BRN 
773655
Expositionsgrenzwerte
No exposure limit is set. A TLV-TWA air value of 100 ppm (approximately 400 mg/m3) is suggested for this compound.
Stabilit?t:
Stability Stable, but light-sensitive. Combustible. Incompatible with strong oxidizing agents.
InChIKey
LAMUXTNQCICZQX-UHFFFAOYSA-N
CAS Datenbank
627-30-5(CAS DataBase Reference)
NIST chemische Informationen
1-Propanol, 3-chloro-(627-30-5)
EPA chemische Informationen
3-Chloro-1-propanol (627-30-5)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xn
R-S?tze: 22-36/37/38
S-S?tze: 26-36-36/37/39
RIDADR  UN 2849 6.1/PG 3
WGK Germany  3
RTECS-Nr. UA8930000
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29055910
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P271 Nur im Freien oder in gut belüfteten R?umen verwenden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P302+P352 BEI BERüHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckm??ig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.

3-Chlorpropan-1-ol Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R22:Gesundheitssch?dlich beim Verschlucken.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.

Chemische Eigenschaften

Colorless to pale-yellow liquid; characteristic odor. Soluble in water, alcohols, and ethers; insoluble in hydrocarbons. Combustible.

Verwenden

3-Chloro-1-propanol is used in organicsynthesis to produce cyclopropane andtrimethylene oxide. It is an intermediate inthe synthesis of pharmaceuticals, agrochemicals, antiseptic agents, and dyes. It is an inhibitor of triosephosphate isomerase and glyceraldehyde 3-phosphate dehydrogenase.

synthetische

3-Chloro-1-propanol is synthesized by the reaction of 1, 3-propanediol and hydrochloric acid, using benzene sulfonic acid as the catalyst.
Reaction: 250 g of trimethylene glycol are shaken with 450 g of sulfur chloride, the mixture becoming warm, sulfur dioxide being rapidly evolved, and sulfur deposited. This reaction continues for 1 hours without heating, whereafter the mixture is heated for a further 6 hours on the water-bath and then for 30 min, over a free flame. When no more sulfur dioxide is evolved, the mixture is allowed to cool, then extracted several times with ether. The sulfur is washed with ether, and the united ethereal layers are shaken with sodium carbonate solution to remove sulfur dioxide, dried over sodium sulfate, and freed from ether. The residue is fractionated and the fraction of b.p. 140-180° C is redistilled, giving 60% (160 g) of 3-chloro-1-propanol, b.p. 160-164°C/760 mm, 60-64° C/10 mm.
J. Amer. Chem. Soc, 38, 2481 (1916)
J. Chem. Soc, 1928, 2439

Allgemeine Beschreibung

3-Chloro-1-propanol appears as a colorless liquid with a mild odor. Slightly denser than water. Toxic by ingestion and inhalation . Flash point 270°F. Used to make plastics, resins and other chemicals.

Reaktivit?t anzeigen

3-Chloro-1-propanol may be sensitive to prolonged exposure to light. 3-Chloro-1-propanol may react with oxidizing agents. .

Health Hazard

3-Chloro-1-propanol also know as Trimethylene chlorohydrin, is a moderatelytoxic compound. Skin contact can cause irritation.Ingestion can result in CNSdepression, muscle contraction, gastrointesti nal pain, and ulceration or stomach bleed ing. High dosage can cause liver injury. Thetoxicity of this compound, however, is lesssevere than that of its isomer, propylene β-chlorohydrin.
LD50 value, oral (mice): 2300 mg/kg

Brandgefahr

Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.

Sicherheitsprofil

Moderately toxic by ingestion. Mutation data reported. Chloropropanols have mutagenic and carcinogenic properties. The 3-monochloropropanol (3-MCPD) is the main chloropropanol found in hydrolyzates of vegetable protein (HVP) made by acid hydrolysis.

Waste disposal

Trimethylene chlorohydrin is burned in achemical incinerator equipped with an afterburner and scrubber.

3-Chlorpropan-1-ol Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


3-Chlorpropan-1-ol Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 381)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hubei Ipure Biology Co., Ltd
+8613367258412
ada@ipurechemical.com China 10319 58
Shaanxi Didu New Materials Co. Ltd
+86-89586680 +86-13289823923
1026@dideu.com China 8670 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578
sales@hbmojin.com China 12835 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177
peter@yan-xi.com China 5857 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-13131129325
sales1@chuanghaibio.com China 5889 58
Taixing Foreign Trade Nanjing Co., Ltd.
+86-025-83346564; +8613182976929
sales@tx-chem.com China 122 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21634 55
Hangzhou FandaChem Co.,Ltd.
+8615858145714
FandaChem@Gmail.com China 9087 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795
ivan@atkchemical.com China 32957 60
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +8618949832763
info@tnjchem.com China 2986 55

627-30-5(3-Chlorpropan-1-ol)Verwandte Suche:


  • 1-Chloro-3-propanol
  • 3-Chloro-1-hydroxypropane
  • 3-chloro-1-propano
  • 3-Chloropropane-1-ol
  • 3-Chloropropanol-1
  • 3-Chlorpropan-1-ol
  • Propanol, 3-chloro-
  • LABOTEST-BB LT01690209
  • 3-CHLORO-1-PROPANOL
  • 1-CHLORO-3-HYDROXYPROPANE
  • 1-CHLORO-3-HYDROXYPROPANE, 3-CHLORO-1-PROPANOL, TRIMETHYLENE CHLOROHYDRIN
  • Chloro-1-propanol
  • 3-Chloro-1-propanol,98+%
  • 3-Chloro-1-propyl alcohol
  • 1-Chloro-3-hydroxypropane, stabilized, 98%
  • Chloropropanol,98%
  • 3-CHLORO-1-PROPANOL / 1-CHLORO-3-HYDROXYPROPANE
  • 1-Chloro-3-hydroxypropane, stabilized, 98% 100GR
  • 1-Chloro-3-hydroxypropane, stabilized, 98% 25GR
  • 1-Chloro-3-hydroxypropane, 98%, stabilized
  • NSC 60190
  • 3-CHLORO-1-PROPANOL FOR SYNTHESIS
  • 1-Chloro-3-hydroxypropane, Trimethylene chlorohydrin
  • Chloro-1-propa
  • 3-chloro-1-propanol, 3-chloro-propanol
  • 3-CHLORPROPANOL
  • oro-1-propanoL
  • 3-chloro-1-propane
  • 3-Chloro-1-propanol>
  • Fudosteine Intermediate
  • TRIMETHYLENE CHLOROHYDRIN
  • 3-Chloropropanol
  • 3-CHLOROPROPAN-1-OL
  • 1-Propanol, 3-chloro-
  • 3-Chloropropyl alcohol
  • 3-chlorine-1-propyl alcohol
  • Fudosteine Impurity C
  • 3-Chloro-1-propanol, ≥ 98.0%
  • 1-Chloro-3-propanol in methanol
  • 627-30-5
  • 627-30-6
  • ClCH2CH2CH2OH
  • ClCH23OH
  • Oxygen Compounds
  • Organic Building Blocks
  • Building Blocks
  • Alcohols
  • C2 to C6
  • 蠅-Functional Alkanols, Carboxylic Acids, Amines & Halides
  • 蠅-Chloroalkanols
  • Cyclomethycaine
  • Piperocaine
  • omega-Chloroalkanols
  • omega-Functional Alkanols, Carboxylic Acids, Amines & Halides
  • Alcohols
  • Building Blocks
  • C2 to C6
  • Chemical Synthesis
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