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Hydramethylnon

Hydramethylnon Struktur
67485-29-4
CAS-Nr.
67485-29-4
Bezeichnung:
Hydramethylnon
Englisch Name:
Hydramethylnon
Synonyma:
Hydramethylon;AMDRO;Matox;COMBAT;Wipeout;MAXFORCE;ac217300;cl217300;AC 217300;CL 217300
CBNumber:
CB0296517
Summenformel:
C25H24F6N4
Molgewicht:
494.48
MOL-Datei:
67485-29-4.mol

Hydramethylnon Eigenschaften

Schmelzpunkt:
185-190°C
Siedepunkt:
510.5±60.0 °C(Predicted)
Dichte
1.2816 (estimate)
Dampfdruck
2.7 x l0-6 Pa (25 °C)
storage temp. 
0-6°C
L?slichkeit
Chloroform (Slightly), DMSO (Sparingly), Methanol (Slightly)
Wasserl?slichkeit
0.005-0.007 mg l-1(25 °C)
pka
14.38±0.40(Predicted)
BRN 
6015162
Stabilit?t:
Light Sensitive
CAS Datenbank
67485-29-4(CAS DataBase Reference)
NIST chemische Informationen
2(1H)-pyrimidinone, tetrahydro-5,5-dimethyl-, (3-(4-(trifluoromethyl)phenyl)-1-(2-(4-(trifluoromethyl)phenyl)ethenyl)-2-propenylidene)hydrazone(67485-29-4)
EPA chemische Informationen
Hydramethylnon (67485-29-4)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher T;N,N,T
R-S?tze: 22-36-48/25-50/53
S-S?tze: 1/2-22-26-36/37-45-60-61
RIDADR  UN3077 9/PG 3
WGK Germany  3
RTECS-Nr. UW7583000
Giftige Stoffe Daten 67485-29-4(Hazardous Substances Data)
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitssch?dlich bei Verschlucken. Akute Toxizit?t oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H372 Sch?digt bei Hautkontakt und Verschlucken die Organe bei l?ngerer oder wiederholter Exposition. Spezifische Zielorgan-Toxizit?t (wiederholte Exposition) Kategorie 1 Achtung GHS hazard pictogramssrc="/GHS08.jpg" width="20" height="20" /> P260, P264, P270, P314, P501
H410 Sehr giftig für Wasserorganismen mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 1 Warnung GHS hazard pictogramssrc="/GHS09.jpg" width="20" height="20" /> P273, P391, P501
Sicherheit
P273 Freisetzung in die Umwelt vermeiden.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.
P314 Bei Unwohlsein ?rztlichen Rat einholen / ?rztliche Hilfe hinzuziehen.

Hydramethylnon Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R22:Gesundheitssch?dlich beim Verschlucken.
R36:Reizt die Augen.
R48/25:Giftig: Gefahr ernster Gesundheitssch?den bei l?ngerer Exposition durch Verschlucken.
R50/53:Sehr giftig für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.

S-S?tze Betriebsanweisung:

S1/2:Unter Verschluss und für Kinder unzug?nglich aufbewahren.
S22:Staub nicht einatmen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S60:Dieses Produkt und sein Beh?lter sind als gef?hrlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.

Beschreibung

Hydramethylnon is an organic pesticide active ingredient from the trifluoromethyl aminohydrazone chemical class. It is a registered chemical alternative for chlorpyrifos for use as a termiticide and against ants, crickets, and cockroaches around the home and lawn. Hydramethylnon is also used in a wide variety of professional pesticide products and in various formulations, These include foaming products, granular products, gel baits, liquid concentrates.

Chemische Eigenschaften

Yellow to orange crystal, solubility (25°C): water 0.005~0.007mg/L, (20°C) acetone 360g/L, chlorobenzene 390g/L, 1,2-dichloroethane 170g/L, ethanol 72g/L, methanol 230g/L, isopropanol 12g/L, xylene 94g/L. Stable at 25°C for 2 years, stable at 45°C for 90 days, decomposition by sunlight DT50 about 1 hour; fluorantrazone aqueous suspension is stable to hydrolysis, DT50 24-33 days (pH 4.9), 10-11 days (pH 7,03), 11-12 days (pH 8.87). Decomposition of DT50 in soil took about 6 days.

History

Hydramethylnon was developed by DuPont in 1975 and introduced to ornamentals industry in the 1990s. Acequinocyl was also discovered by DuPont in the 1970s and further developed by AgroKanesbo Co. Ltd. and Tomen Agro in Japan. Arysta LifeScience first introduced acequinocyl to the U.S. ornamentals market in 2005. Bifenazate was first developed by Uniroyal Chemical in 1990 and commercialized by Crompton Corporation in 1999. Bifenazate was introduced to the ornamental market in 2010.

Verwenden

Hydramethylon is an insecticide primarily used in the form of baits for cockroaches and ants.

Definition

ChEBI: Hydramethylnon is a member of the class of hydrazones that is used as an insecticide for control of ants and cockroaches. It has a role as a mitochondrial cytochrome-bc1 complex inhibitor and an insecticide. It is a hydrazone, a member of pyrimidines, a member of (trifluoromethyl)benzenes, an olefinic compound and a member of guanidines.

synthetische

Hydramethylnon synthesis was achieved through the coupling in alcoholic media refluxing the compound 1,5-bis[p-(trifluoromethoxy)phenyl]-1,4-pentadien-3-one afforded the desired product in 50% yield.
Synthesis of hydramethylnon
Synthesis of hydramethylnon

Application

Hydramethylnon is used in baits for selective control of agricultural and household Formicidae (especially Camponot us, Iridomyrmex, Monomorium, Solenopsis and Pogomyrmex spp. and Pheidole megacephala). It is also used to control Blattellidae (especially Blatta, Blattella, Periplaneta and Supella spp.). It can be carried into the nest by worker ants and kill the queen because it is slow acting.

Allgemeine Beschreibung

Hydramethylnon appears as odorless yellow crystals. Insoluble in water. Used as an insecticide.

Air & Water Reaktionen

Insoluble in water. Hydrolysis occurs rapidly at low and high pHs.

Reaktivit?t anzeigen

Hydramethylnon is a trifluoromethyl amidinohydrazone.

Sicherheitsprofil

Hydramethylnon is safe to use when applied according to label directions. It has been classified by the EPA as being a low threat when it comes to toxicity to humans, pets and birds.

Stoffwechselwegen

Amdro (AC 217,300) is rapidly photodegraded under borosilicate-filtered xenon arc lamps at 27 C as a suspension in distilled water. The half-life of amdro is calculated as 42 min and four degradation products are identified as 1,5-bis(a,a,a-trifluoro-p-tolyl)-1,4- pentadien-3-one, a,a,a-trifluoro-p-toluic acid, p- (trifluoromethyl)cinnamic acid, 6,7,8,9-tetrahydro-7,7- dimethyl-3-[p-(trifluoromethyl)styryl]-4H-pyrimido[2,1-c]- as-triazin-4-one. These degradation products are identical to those of the metabolites by insect.

Mode of action

Hydramethylnon is a metabolic inhibitor. It works by inhibiting complex III in the mitochondrial inner membrane and leads to a halting of oxidative phosphorylation.

Hydramethylnon Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Hydramethylnon Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 180)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hebei Weibang Biotechnology Co., Ltd
+8615531157085
abby@weibangbio.com China 8810 58
Shaanxi Dideu Medichem Co. Ltd
+86-29-81148696 +86-15536356810
1022@dideu.com China 3882 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578
sales@hbmojin.com China 12835 58
Hebei Jingbo New Material Technology Co., Ltd
+8619931165850
hbjbtech@163.com China 1000 58
Hebei Saisier Technology Co., LTD
+86-18400010335 +86-18034520335
admin@hbsaisier.cn China 1015 58
Hebei Longbang Technology Co., LTD
+86-18633929156 +86-18633929156
admin@hblongbang.com China 941 58
HebeiShuoshengImportandExportco.,Ltd
+86-18532138899 +86-18532138899
L18532138899@163.com China 939 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21634 55
career henan chemical co
+86-0371-86658258 +8613203830695
sales@coreychem.com China 29880 58
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28172 58

67485-29-4(Hydramethylnon)Verwandte Suche:


  • TETRAHYDRO-5,5-DIMETHYL-2(1H)-PYRIMIDINONE [3-[4-(TRIFLUOROMETHYL)-PHENYL]-1-[2-[4-(TRIFLUOROMETHYL)-PHENYL]ETHENYL]-2-PROPENYLIDENE]-HYDRAZONE
  • Tetrahydro-5,5-dimethyl-2(1H)-pyrimidinone[3-[4-(trifluoromethyl)phenyl]-1-[2-[4-(trifluoromethyl)phenyl]ethenyl]-2-propenylidene]hydrazone
  • AC 217300(R)
  • AMDRO
  • Wipeout
  • hydramrthynon
  • AMDRO, 100MG, NEAT
  • 2(1H)-Pyrimidinone, tetrahydro-5,5-dimethyl-, 3-4-(trifluoromethyl)phenyl-1-2-4-(trifluoromethyl)phenylethenyl-2-propenylidenehydrazone
  • (TETRAHYDRO-5,5-DIMETHYL-2(1H)-PYRIMIDINONE)(1,5-BIS(A,A,.
  • 5-dimethyl-tetrahydro-(3-(4-(trifluoromethyl)phenyl)-1-2(1h)-pyrimidinon(2-(4- (trifluoromethyl)phenyl)ethenyl)-2-propenylidene)hydrazone
  • 5,5-dimethyl-perhydro-pyrimidin-2-one α-(4-trifluoromethylstyryl)-α-(4-trifluoromethyl)cinnamylidenehydrazone
  • TETRAHYDRO-5,5-DIMETHYL-2(1H)-PYRIMIDINONE[p-(TRIFLUOROMETHYL)-ALPHA-[p-(TRIFLUOROMETHYL)STYRYL]CINNAMYLIDENE]HYDRAZONE
  • TETRAHYDRO-5,5-DIMETHYL-2(1H)-PYRIMIDINONE(3-(4-TRIFLUOROMETHYL)PHENYL)-1-(2-(4-TRIFLUOROMETHYL)PHEN
  • 2-{2-[(1E,4E)-1,5-bis[4-(trifluoroMethyl)phenyl]penta-1,4-dien-3-ylidene]hydrazin-1-ylidene}-5,5-diMethyl-1,3-diazinane
  • 1,5-Bis[4-(trifluoromethyl)phenyl]-1,4-pentadien-3-one 2-(1,4,5,6-tetrahydro-5,5-dimethyl-2-pyrimidinyl)hydrazone
  • NSC 379665
  • Tetrahydro-5,5-dimethyl-2(1H)-pyrimidinone[3-[4-(trifluoromethyl)phenyl]-1-[2-[4-(trifluoromethyl)phenyl]ethenyl]-2-propylidene]hydrazone
  • (E,E)-hydramethylnon
  • MAXFORCE
  • HYDRAMETHYLNON
  • HYDRAMETHYLNONE
  • COMBAT
  • (1E,4E)-1,5-Bis[4-(trifluoromethyl)phenyl]-1,4-pentadien-3-one (5,5-dimethyltetrahydro-2(1H)-pyrimidinylidene)hydrazone
  • (2-(4-(trifluoromethyl)phenyl)ethenyl)-2-propenylidene)hydrazone
  • 2(1H)-Pyrimidinone,tetrahydro-5,5-dimethyl-,[3-[4-(trifluoromethyl)phenyl]-1-[2-[4-(trifluoromethyl)phenyl]ethenyl]-2-propenylidene]hydrazone
  • 5-dimethyl-tetrahydro-(3-(4-(trifluoromethyl)phenyl)-1-2(1h)-pyrimidinon
  • AC 217300
  • ac217300
  • CL 217300
  • cl217300
  • Matox
  • tetrahydro-5,5-dimethyl-2(1h)-pyrimidinon(3-(4-(trifluoromethyl)phenyl)-1-(2-(4-(trifluoromethyl)phenyl)ethenyl)-2-propenylidene)hydrazone
  • Hydramethylnon Standard
  • Hydramethylnon @100 μg/mL in MeOH
  • 1,4-Pentadien-3-one, 1,5-bis[4-(trifluoromethyl)phenyl]-, 2-(1,4,5,6-tetrahydro-5,5-dimethyl-2-pyrimidinyl)hydrazone
  • Hydramethylnon Solution in Methanol, 1000μg/mL
  • Hydramethylnon 67485-29-4
  • Hydramethylon
  • Hydromethylnon
  • C14220000 Hydramethylnon
  • Hydramethylnon in Methanol
  • Sofosbuvir Impurity 144
  • 67485-29-4
  • C25H24F6N4
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  • 67485-29-4
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