| Identification | Back Directory | [Name]
Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((S)-dm-segphos)]Cl | [CAS]
944451-31-4 | [Synonyms]
(S)-RuCl[(p-cyMene)(DM-SEGPHOS)]Cl
[RuCl(p-cymene)((S)-dm-segphos[R])]Cl
[RuCl(p-cymene)((S)-dm-segphos(regR))]Cl
Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((S)-dm-segphos)]Cl
Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-dm-segphos(R))]Cl | [Molecular Formula]
C56H58Cl2O4P2Ru | [MDL Number]
MFCD09753018 | [MOL File]
944451-31-4.mol | [Molecular Weight]
1026.98 |
| Chemical Properties | Back Directory | [Melting point ]
>100°C | [storage temp. ]
2-8°C | [Water Solubility ]
Insoluble in water | [form ]
Powder | [color ]
orange to brown | [Sensitive ]
air sensitive |
| Questions And Answer | Back Directory | [Reactions]
- Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters.
- Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
- Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone.
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Energy Chemical
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Sigma-Aldrich
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TCI Chemicals
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