Identification | Back Directory | [Name]
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) | [CAS]
488809-34-3 | [Synonyms]
(S)-[(RuCl(SEGPHOS® (S)-[(RuCl(SEGPHOS))2(μ-Cl)3][NH2Me2] (S)-[(RuCl(SEGPHOS(R)))2(μ-Cl)3][NH2Me2] [NH2Me2][(RuCl((S)-segphos[R]))2(μ-Cl)3] [NH2Me2][(RuCl((S)-segphos(regR)))2(mu-Cl)3] Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5' Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5μ-bis(diphenylphosphino)-4,4μ-bi-1,3-benzodioxole]diruthenate(II) Dimethylammonium dichlorotri(chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos)}2(Cl)3] DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos)}2(μ-Cl)3] Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos(R))}2(μ-Cl)3] | [Molecular Formula]
(CH3)2NH2+[C76H56Cl5O8P4Ru2]− | [MDL Number]
MFCD09753037 | [MOL File]
488809-34-3.mol | [Molecular Weight]
1650.69 |
Chemical Properties | Back Directory | [Melting point ]
>100°C | [storage temp. ]
2-8°C | [Water Solubility ]
Insoluble in water | [form ]
Powder | [color ]
light brown | [Sensitive ]
air sensitive |
Questions And Answer | Back Directory | [Reaction]
- Highly enantioselective, highly active catalyst for hydrogenation of functionalized ketones. The chlororuthenate salts show catalytic activity at relatively low temperature.
- Catalyst for enantioselective hydrogenation of enamines.
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