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ChemicalBook--->CAS DataBase List--->346457-41-8

346457-41-8

346457-41-8 Structure

346457-41-8 Structure
IdentificationBack Directory
[Name]

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
[CAS]

346457-41-8
[Synonyms]

(R)-Ru(OAc)2(BINAP)
(R)-[(RUCL(SEGPHOS)2(Μ-CL)3[NH2ME2]
NH2ME2][(RUCL((R)-SEGPHOS))2(U-CL)3
[NH2ME2][(RUCL((R)-SEGPHOS))2(Μ-CL)3]
(R)-[(RuCl(SEGPHOS))2(μ-Cl)3][NH2Me2]
(R)-[(RuCl(SEGPHOS(R)))2(μ-Cl)3][NH2Me2]
[NH2Me2][(RuCl((R)-segphos[R]))2(μ-Cl)3]
(R)-[(RuCl(SEGPHOS(R)))2(mu-Cl)3][NH2Me2]
[NH2Me2][(RuCl((R)-segphos(regR)))2(mu-Cl)3]
-bi-1,3-benzodioxole]diruthenate(II),[NH2Me2][
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5μ-bis(diphenylphosphino)-4,4μ-bi-1,3-benzodioxole]diruthenate(II)
DIMETHYLAMMONIUM DICHLOROTRI(Μ-CHLORO)BIS[(R)-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]DIRUTHENATE(II),[NH2ME2][
Dimethylammonium dichlorotri(chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((R)-segphos)}2(Cl)3]
Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((R)-segphos(R))}2(μ-Cl)3]
[Molecular Formula]

2C38H28O4P2.C2H7N.Cl.Cl3Ru2.ClH
[MDL Number]

MFCD09753020
[MOL File]

346457-41-8.mol
[Molecular Weight]

1646.66
Chemical PropertiesBack Directory
[Melting point ]

>100°C
[storage temp. ]

2-8°C
[Water Solubility ]

Insoluble in water
[form ]

Powder
[color ]

light brown
[Sensitive ]

air sensitive
[CAS DataBase Reference]

346457-41-8
Safety DataBack Directory
[Symbol(GHS) ]


GHS08
[Signal word ]

Danger
[Hazard statements ]

H371-H373-H360
[Precautionary statements ]

P260-P264-P270-P309+P311-P405-P501-P260-P314-P501
[WGK Germany ]

3
[HS Code ]

2843.90.0000
Hazard InformationBack Directory
[Uses]

Takasago Ligands and Complexes for Asymmetric Reactions
[General Description]

(R)-[(RuCl(SEGPHOS?))2(μ-Cl)3][NH2Me2] is a ruthenium-based catalyst generally used in the asymmetric hydrogenation reactions of ketones. SEGPHOS?, the chiral ligand and its ruthenium-based catalysts are developed and commercialized by Takasago International Corporation.
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