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ChemicalBook--->CAS DataBase List--->93-18-5

93-18-5

93-18-5 Structure

93-18-5 Structure
IdentificationMore
[Name]

2-Ethoxynaphthalene
[CAS]

93-18-5
[Synonyms]

2-ETHOXYNAPHTHALENE
2-NAPHTHOL ETHYL ETHER
2-NAPHTHYL ETHYL ETHER
AKOS 92213
BETA-NAPHTHOL ETHYL ETHER
BETA-NAPHTHYL ETHYL ETHER
B-NAPHTHYL ETHYL ETHER
BROMELIA
ETHOXYLATED BETA NAPHTHALENE
ETHYL 2-NAPHTHYL ETHER
ethyl 2-naphtyl ether
ETHYL BETA-NAPTHYL ETHER
FEMA 2768
NAPHTHYL BETA ETHYL ETHER
NEROLIN
NEROLIN BROMELIA
NEROLINE
NEROLINE BROMELIA
2-ethoxy-naphthalen
2-Ethoxynaphthalin
[EINECS(EC#)]

202-226-7
[Molecular Formula]

C12H12O
[MDL Number]

MFCD00016808
[Molecular Weight]

172.22
[MOL File]

93-18-5.mol
Chemical PropertiesBack Directory
[Appearance]

light brown crystals
[Melting point ]

35-37 °C(lit.)
[Boiling point ]

282°C
[density ]

1.0640
[vapor pressure ]

0.518Pa at 25℃
[FEMA ]

2768
[refractive index ]

1.5975 (estimate)
[Fp ]

134°C
[solubility ]

alcohol: soluble
[form ]

neat
[color ]

White to Almost white
[Odor]

at 10.00 % in dipropylene glycol. naphtha floral orange blossom powdery grape
[Odor Type]

naphthyl
[Water Solubility ]

insoluble
[JECFA Number]

1258
[Merck ]

14,3752
[BRN ]

2042397
[LogP]

3.747 at 25℃
[CAS DataBase Reference]

93-18-5(CAS DataBase Reference)
[NIST Chemistry Reference]

Naphthalene, 2-ethoxy-(93-18-5)
[EPA Substance Registry System]

93-18-5(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R38:Irritating to the skin.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

2
[RTECS ]

QJ6900000
[TSCA ]

Yes
[HS Code ]

29093090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Diethyl sulfate-->2-Naphthol-->Ethanol-->Sulfuric acid
[Preparation Products]

2-Ethoxynaphthalene-1-carbonyl chloride-->2-ETHOXY-1-NAPHTHOIC ACID-->2-ETHOXY-1-NITRONAPHTHALENE-->1-(2-ethoxynaphthalen-1-yl)ethanone
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Ethoxynaphthalene(93-18-5).msds
Hazard InformationBack Directory
[Description]

(β-Naphthyl ethyl ether has an odor suggestive of orange blossom with a faint, fruity undertone. It has a corresponding sweet taste suggestive of strawberry (on extreme dilution only). This substance may be prepared by esterification of P-naphthol with ethyl alcohol and sulfuric acid; from β-naphtholsodium and diethylsulfate in weak aqueous base; fromβ-naphtholsodium and ethyl bromide.
[Chemical Properties]

Ethyl 2-Naphthyl Ether forms white crystals (mp 37–38°C), with a mild, long-lasting, orange blossom fragrance.
[Chemical Properties]

light brown crystals
[Chemical Properties]

β-Naphthyl ethyl ether has an odor suggestive of orange blossom with a faint, fruity undertone. Also, it has a corresponding sweet taste suggestive of strawberry (on extreme dilution only)
[Uses]

The fluorescence of 2-Ethoxynaphthalene has been shown to be weakly quenched by m-dimethlphthalate and methyl benzoate. Importantly, at increased concentration methyl benzoate enhances the fluorescence by increasing the polarity of the solvent .
[Definition]

ChEBI: 2-Ethoxynaphthalene is a member of naphthalenes.
[Preparation]

By esterification of β-naphthol with ethyl alcohol and sulfuric acid; from β-naphtholsodium and diethylsulfate in weak aqueous base; from β-naphtholsodium and ethyl bromide.
[Taste threshold values]

Taste characteristics at 4 ppm: powdery, floral, soapy and heavy with a berry and grape nuance.
[General Description]

Nerolin bromelia is an alkyl ether of 2-naphthol, which is generally used as a perfume and flavoring compound.
[Flammability and Explosibility]

Notclassified
[Purification Methods]

Crystallise it from pet ether or EtOH (m 37-38o). Dry it in vacuo, or distil it in a vacuum. The picrate has m 104.5o (from EtOH or CHCl3). [Beilstein 6 H 606, 6 II 578, 6 III 2972, 6 IV 4257.]
Spectrum DetailBack Directory
[Spectrum Detail]

2-Ethoxynaphthalene(93-18-5)1HNMR
2-Ethoxynaphthalene(93-18-5)13CNMR
2-Ethoxynaphthalene(93-18-5)IR1
2-Ethoxynaphthalene(93-18-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Ethoxynaphthalene, 98%(93-18-5)
[Alfa Aesar]

2-Ethoxynaphthalene, 99%(93-18-5)
[Sigma Aldrich]

93-18-5(sigmaaldrich)
[TCI AMERICA]

2-Ethoxynaphthalene,>98.0%(GC)(93-18-5)
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