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ChemicalBook--->CAS DataBase List--->82113-65-3

82113-65-3

82113-65-3 Structure

82113-65-3 Structure
IdentificationMore
[Name]

TRIFLUOROMETHANESULFONIMIDE
[CAS]

82113-65-3
[Synonyms]

1,1,1-TRIFLUORO-N-[(TRIFLUOROMETHYL)SULFONYL]METHANESULFONAMIDE
BIS(TRIFLUOROMETHANE)SULFONAMIDE
BISTRIFLUOROMETHANESULFONIMIDE
BIS(TRIFLUOROMETHANESULFONYL)AMINE
Bis(trifluoromethanesulfonyl)imide
BIS(TRIFLUOROMETHYLSULFONYL)AMINE
N,N-BIS(TRIFLUOROMETHANESULFONYL)IMIDE
N,N-BIS(TRIFLUOROMETHANESULFONYL)IMIDE ACID
N,N-BIS(TRIFLUOROMETHYLSULPHONYL)AMINE
TRIFLUOROMETHANESULFONIMIDE
bistrifluoromethanesulfonimidesol.
Trifluoromethansulfonimide
bis(Trifluoromethanesulphonyl)imide
BISTRIFLUOROMETHANESULFONIMIDE SOL., ~0. 5 M IN DICHLOROM.
N,N-Bis(trifluoromethylsulfonyl)amine
bis(trifluoromethane)sulfonimide solution
Methanesulfonamide, 1,1,1-trifluoro-N-((trifluoromethyl)sulfonyl)-
N,N-Bis-(trifluoromethylsulfonyl)-imide
TRIFLUOROMETHANSULFONAMIDE
Bis(trifluoromethanesulfonyl)amine, Bis(trifluoromethylsulfonyl)amine
[EINECS(EC#)]

214-152-2
[Molecular Formula]

C2HF6NO4S2
[MDL Number]

MFCD00214154
[Molecular Weight]

281.15
[MOL File]

82113-65-3.mol
Chemical PropertiesBack Directory
[Appearance]

light yellow to brown liquid
[Melting point ]

52-56 °C
[Boiling point ]

90-91 °C(lit.)
[density ]

1.36
[storage temp. ]

2-8°C
[solubility ]

800g/l Risk of violent reaction.
[form ]

Crystals
[pka]

-10.42±0.40(Predicted)
[color ]

Colorless to brownish
[PH]

0.8 (100g/l, H2O, 20℃)Risk of violent reaction.
[Stability:]

Stable. Incompatible with strong oxidizing agents. Reacts violently with water.
[BRN ]

4754101
[InChIKey]

ZXMGHDIOOHOAAE-UHFFFAOYSA-N
[LogP]

-0.771 at 25.5℃ and pH6.7
[CAS DataBase Reference]

82113-65-3(CAS DataBase Reference)
[EPA Substance Registry System]

Methanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]- (82113-65-3)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
R40:Limited evidence of a carcinogenic effect.
R14:Reacts violently with water.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3265 8/PG 2
[WGK Germany ]

3
[F ]

3-10-21
[Hazard Note ]

Corrosive
[HazardClass ]

8
[PackingGroup ]

I
[HS Code ]

29350090
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

1-BUTYL-1-METHYLPYRROLIDINIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE-->Sliver bis(trifluoromethane sulfonimide)-->1-IODO-3,4-METHYLENEDIOXYBENZENE
Hazard InformationBack Directory
[Chemical Properties]

light yellow to brown liquid
[Uses]

Trifluoromethanesulfonimide is a strong acid, used in the preparation of highly efficient Lewis acid catalysts.
[Application]

Trifluoromethanesulfonimide may be used in the following studies:
As catalyst during the polymerization of octamethylcyclotetrasiloxane in the presence of hexamethyldisiloxane.
As efficient catalyst in the synthesis of various non-reducing disaccharides, via ketopyranosylation of 2,3,4,6-tetra-O-benzyl-1-C-methyl-D-hexopyranoses.
Starting material for preparing the N-fluoro derivative, a reactive fluorinating agent.
As a component of solid polymer electrolytes.
[General Description]

Bis(trifluoromethane)sulfonimide (TFSI, Tf2N) is utilized as anion species to form 1-ethyl-3-methylimidazolium molten salts. It undergoes acid-base complexation with rod-like poly(2,5-pyridine) to afford highly-ordered lamellar self-assemblies in the hydrated films.
Spectrum DetailBack Directory
[Spectrum Detail]

TRIFLUOROMETHANESULFONIMIDE(82113-65-3)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Bis(trifluoromethanesulfonyl)imide,99%(82113-65-3)
[Sigma Aldrich]

82113-65-3(sigmaaldrich)
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