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ChemicalBook--->CAS DataBase List--->808142-88-3

808142-88-3

808142-88-3 Structure

808142-88-3 Structure
IdentificationBack Directory
[Name]

Ir[p-F(Me)ppy]2(dtbbpy)PF6
[CAS]

808142-88-3
[Synonyms]

Ir[p-F(Me)ppy]2(dtbbpy)PF6
)-2,2'-bipyridine-κN,κN]bis[5-fL
N]bis[5-fluoro-2-(5-methyl-2-pyridinyl-κ
(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[2-(4-fluorophenyl)-5-methylpyridine]iridium(III) Hexafluorophosphate
(4,4'-di-tert-butyl-2,2'-bipyridine)-bis-(5-methyl-2-(5-fluoro-phenyl)-pyridine)-iridium(iii)] hexafluorophosphate
[4,4'-Bis(1,1-dimethylethyl)-2,2'-bipyridine-κN,κN]bis[5-fluoro-2-(5-methyl-2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate
(4,4'-Di-tert-butyl-2,2'-bipyridine-kappa~2~N~1~,N~1'~)[bis[5-fluoro-2-(5-methyl-2-pyridinyl-kappaN)phenyl-kappaC~1~]]iridium Hexafluorophosphate
(OC-6-33)-[4,4’-Bis(1,1-dimethylethyl)-2,2’-bipyridine-κN1,κN1’]bis[5-fluoro-2-(5-methyl-2-pyridinyl-κN)phenyl-κC]Iridium(1+) Hexafluorophosphate(1-)
Iridium(1+), [4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-fluoro-2-(5-methyl-2-pyridinyl-κN)phenyl-κC]-, (OC-6-33)-, hexafluorophosphate(1-) (1:1)
[Molecular Formula]

C42H42F8IrN4P
[MOL File]

808142-88-3.mol
[Molecular Weight]

978
Chemical PropertiesBack Directory
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

powder or crystals
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
Hazard InformationBack Directory
[Uses]

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.
[reaction suitability]

reaction type: Photocatalysis
reagent type: catalyst
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