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ChemicalBook--->CAS DataBase List--->387859-70-3

387859-70-3

387859-70-3 Structure

387859-70-3 Structure
IdentificationBack Directory
[Name]

Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III)
[CAS]

387859-70-3
[Synonyms]

Ir(Fppy)3
Ir(4,6Fppy)3
Tris(2-(4,6-difuorophenyl)pyridine)iridium(III)
[Molecular Formula]

C33H18F6IrN3
[MDL Number]

MFCD09842738
[MOL File]

387859-70-3.mol
[Molecular Weight]

762.74
Chemical PropertiesBack Directory
[Melting point ]

401 °C
[storage temp. ]

under inert gas (nitrogen or Argon) at 2–8 °C
[form ]

Powder
[color ]

yellow
[Sensitive ]

air sensitive
[λmax]

347 nm
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[TSCA ]

No
Questions And AnswerBack Directory
[Reaction]

  1. Photoredox catalysis for trifluoromethylation of arenes and heteroarenes.
  2. Photocatalyst for C–F alkenylation coupling reactions between perfluoroarenes and alkynes.
Reactions of 387859-70-3
Hazard InformationBack Directory
[Uses]

Ir(dFppy)3 is a photocatalyst that readily facilitates the decarboxylative arylation of α amino acids using visible light.
[reaction suitability]

core: iridium
reaction type: Photocatalysis
reagent type: catalyst
Spectrum DetailBack Directory
[Spectrum Detail]

Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) (387859-70-3)1HNMR
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