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ChemicalBook--->CAS DataBase List--->1092775-62-6

1092775-62-6

1092775-62-6 Structure

1092775-62-6 Structure
IdentificationBack Directory
[Name]

[Ir{dFCF3ppy}2(bpy)]PF6
[CAS]

1092775-62-6
[Synonyms]

[Ir{dFCF3ppy}2(bpy)]PF6
Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate
[Molecular Formula]

C34H18F16IrN4P
[MOL File]

1092775-62-6.mol
[Molecular Weight]

1009.7
Chemical PropertiesBack Directory
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[form ]

Powder
[color ]

yellow
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P280-P301+P312-P302+P352-P305+P351+P338
Questions And AnswerBack Directory
[Reaction]

  1. Catalyst used for the chemo-, regio, and stereoselective trifluoromethylation of styrene.
  2. Photoredox catalyst used in cross-coupling: Ir/Ni dual catalysts for the synthesis of benzylic ethers.
  3. Iridium complex used for catalytic olefin hydroamidation enabled by proton-coupled electron transfer.
  4. Catalyst used for visible light photoredox cross-coupling of acyl chlorides with potassium alkoxymethyltrifluoroborates.
  5. Iridium catalyst used in the photoredox/nickel dual catalytic cross-coupling of secondary alkyl β-trifluoroboratoketones and –esters with aryl bromides.
  6. Photocatalyst used in the cross-coupling of trifluoroalkylboranes.
Reactions of 1092775-62-6_1
Reactions of 1092775-62-6_2
Hazard InformationBack Directory
[Uses]

When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp3 hybridized trifluoroborates with aryl bromides under exceptionally mild conditions.
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