| Identification | More | [Name]
Acetylene | [CAS]
74-86-2 | [Synonyms]
4-(chloromethyl)tolunitrile
CARBON BLACK
Ethine
Ethyne
Narcylen
Acetylen
C2H2
Vinylene
ethenylene
Welding Gas
ACETYLENE (DISSOLVED)
Acetylene (non-chemical use)
Acetylene (chemical use)
acetylene ethyne
Drew Ameroid Amerox Acetylene 40 LTR
Dissolved acetylene
Acetylene (liquefied) | [EINECS(EC#)]
200-816-9 | [Molecular Formula]
C2H2 | [MDL Number]
MFCD00008567 | [Molecular Weight]
26.04 | [MOL File]
74-86-2.mol |
| Chemical Properties | Back Directory | [Description]
Acetylene (100% purity) is odourless, but commercial purity has a distinctive garlic-like
odour and is very soluble in alcohol and almost miscible with ethane. Acetylene is a flammable
gas and kept under pressure in gas cylinders. Under certain conditions, acetylene
can react with copper, silver, and mercury to form acetylides, compounds which can act as
ignition sources. Brasses containing less than 65% copper in the alloy and certain nickel
alloys are suitable for acetylene. Acetylene is not compatible with strong oxidisers such as
chlorine, bromine pentafluoride, oxygen, oxygen difluoride and nitrogen trifluoride, brass
metal, calcium hypochlorite, heavy metals such as copper, silver, mercury, and their salts,
bromine, chlorine, iodine, fluorine, sodium hydride, caesium hydride, ozone, perchloric
acid, and potassium. | [Appearance]
Acetylene is an extremely flammable, colorless, compressed gas. It has a faint ethereal odor when pure; a garlic-like odor when contaminated | [Melting point ]
-88°C | [Boiling point ]
-28°C | [density ]
0.91 | [vapor pressure ]
3.04 X 104 mmHg (~40 atmospheres) at
16.8 °C | [refractive index ]
1.00051 | [Fp ]
-18°C | [pka]
25(at 25℃) | [Odor]
Odorless, although garlic-like or ''gassy" odor often detectable because of trace
impurities | [Water Solubility ]
0.106 g/100 mL | [Dielectric constant]
1.0217（0.0℃） | [CAS DataBase Reference]
74-86-2(CAS DataBase Reference) | [NIST Chemistry Reference]
Acetylene(74-86-2) | [EPA Substance Registry System]
74-86-2(EPA Substance) |
| Hazard Information | Back Directory | [Chemical Properties]
Acetylene (100% purity) is odorless but commercial purity has a distinctive garlic-like
odor. It is very soluble in alcohol and almost miscible with ethane. Acetylene is a flammable
gas and kept under pressure in gas cylinders. Under certain conditions, acetylene
can react with copper, silver, and mercury to form acetylides, compounds that can act as
ignition sources. Brasses contain a form acetylides, compounds that can act as ignition
sources. Brasses containing less than 65% copper in the alloy and certain nickel alloys are
suitable for acetylene. Acetylene is not compatible with strong oxidizers such as chlorine,
bromine pentafl uoride, oxygen, oxygen difl uoride, and nitrogen trifl uoride, brass metal,
calcium hypochlorite, heavy metals such as copper, silver, mercury, and their salts, bromine,
chlorine, iodine, fl uorine, sodium hydride, cesium hydride, ozone, perchloric acid,
or potassium. | [General Description]
A colorless gas with a faint garlic-like odor. Easily ignited and burns with a sooty flame. Gas is lighter than air. Flame may flash back to the source of a leak very easily. Under prolonged exposure to fire or heat the containers may rupture violently and rocket. | [Reactivity Profile]
ACETYLENE(74-86-2) reacts with alkali metals, forming Hydrogen gas. ACETYLENE(74-86-2) can react explosively with bromine [Von Schwartz 1918. p.142 ]. ACETYLENE(74-86-2) forms a sensitive acetylide when passed into an aqueous solution of mercuric nitrate, [Mellor 4:933. 1946-47]. An ACETYLENE(74-86-2) torch used to drill through a plow frame, which was filled with hydrogen gas, produced an explosion [NIOSH, June 1998]. ACETYLENE(74-86-2) reacts with silver, copper and lead to form sensitive, explosive salts. Since ACETYLENE(74-86-2) is endothermic and effectively a reducing agent, it's reaction with oxidants can be very violent (examples: calcium hypochlorite, nitric acid, nitrogen oxide, ozone, trifluoromethyl hypofluorite, etc.). Contact of very cold liquefied gas with water may result in vigorous or violent boiling of the product and extremely rapid vaporization, due to the large temperature differences involved. If the water is hot, there is the possibility that a liquid "superheat" explosion may occur. Pressures may build to dangerous levels if liquid gas contacts water in a closed container [Handling Chemicals Safely 1980]. ACETYLENE(74-86-2) and ammonia can form explosive silver salts in contact with Ag. (Renner, Hermann, Gunther Schlamp. "Silver, Silver Compounds, and Silver Alloys." Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA. 2001.). | [Air & Water Reactions]
Highly flammable. Slightly soluble in water. Reacts with water to form toxic ammonia fumes. | [Health Hazard]
Headache, dizziness and loss of consciousness may occur. Death from ``smothering'' may occur if oxygen content of the air is severely reduced by dilution with acetylene. | [Health Hazard]
Prolonged periods of exposure to acetylene cause symptoms including headaches, respiratory
diffi culty, ringing in ears, shortness of breath, wheezing, dizziness, drowsiness,
unconsciousness, nausea, vomiting, and depression of all the senses. The skin of a victim
of overexposure may have a blue color. Currently, there are no known adverse health
effects associated with chronic exposure to the components of this compressed gas. Lack
of suffi cient oxygen may cause serious injury or death. The target organs include the
kidneys, CNS, liver, respiratory system, and eyes. | [Potential Exposure]
Acetylene can be burned in air or oxygen and is used for brazing, welding, cutting, metallizing, hardening, flame scarfing; and local heating in metallurgy. The flame is also used in the glass industry. Chemically, acetylene is used in the manufacture of vinyl chloride, acrylinitrile, synthetic rubber; vinyl acetate; trichloroethylene, acrylate, butyrolactone, 1,4-butanediol, vinyl alkyl ethers, pyrrolidone, and other substances | [Fire Hazard]
Behavior in Fire: May explode in fire | [First aid]
Move victim to fresh air. Call emergency medical care. Apply artificial respiration if victim is not breathing. If breathing is difficult, give oxygen. Remove and isolate contaminated clothing and shoes. In the case of contact with liquefied gas, thaw frosted parts with lukewarm water. Keep victim warm and quiet. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. See also NIOSH criteria document cited below. If frostbite has occurred, seek medical attention immediately; do NOT rub the affected areas or flush them with water. In order to prevent further tissue damage, do NOT attempt to remove frozen clothing from frostbitten areas. If frostbite has NOT occurred, immediately and thoroughly wash contaminated skin with soap and water. | [Shipping]
UN1001 Acetylene, dissolved, Hazard Class: 2.1; Labels: 2.1-Flammable gas. Cylinders must be transported in a secure upright position, in a well-ventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner | [Incompatibilities]
The substance may polymerize due to heating. The substance decomposes on heating and increasing pressure, causing a fire and explosion hazard. The substance is a strong reducing agent and reacts violently with oxidants and with fluorine or chlorine under influence of light, causing fire and explosion hazard. Reacts with copper, silver, and mercury or their salts, forming shock-sensitive compounds (acetylides). The content of lines carrying acetylene must not exceed 63% copper. May form explosive mixture with air. Forms shock-sensitive mixture with copper and copper salts; mercury and mercury salts; and silver and silver salts. Reacts with brass, bromine, cesium hydride, chlorine, cobalt, cuprous acetylize; fluorine, iodine, mercuric nitrate; nitric acid, potassium, rubidium hydride; trifluoromethyl hypofluorite; and sodium hydride. | [Waste Disposal]
Return refillable compressed gas cylinders to supplier. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Incineration. | [Physical properties]
Acetylene, which is the simplest alkyne hydrocarbon, exists as a colorless, flammable, unstable gas with a distinctive pleasant odor (acetylene prepared from calcium carbide has a garlic smell resulting from traces of phosphine produced in this process). The term acetylenes is used generically in the petroleum industry to denote chemicals based on the carbon-carbon triple bond. | [History]
Acetylene was discovered in 1836 by Edmund Davy (1785-1857) who produced the gas while trying to make potassium metal from potassium carbide (K2C2). In 1859, Marcel Morren in France produced acetylene by running an electric arc between carbon electrodes in the presence of hydrogen. Morren called the gas produced carbonized hydrogen. Three years later, Pierre Eugène-Marcelin Berthelot (1827-1907) repeated Morren’s experiment and identified carbonized hydrogen as acetylene. | [Uses]
About 80% of acetylene production is used as a closed-system
manufacturing intermediate for the production of other
chemicals. The other chemicals synthesized from acetylene
include vinyl chloride monomer, N-vinylcarbazole, 1,4-
butanediol, vinyl ethers, N-vinyl-2-pyrrolidone, vinyl fluoride,
N-vinylcaprolactam, and vinyl esters. The other use of acetylene
as oxyacetylene torches for metal cutting and welding is
about 20%. | [Uses]
Acetylene is used in oxyacetylene flame forwelding and cutting metals; as an illuminant;as a fuel; for purifying copper, silver, andother metals; and in the manufacture ofacetic acid, acetaldehyde, and acetylides. Itis formed when calcium carbide reacts withwater. It is also obtained from cracking ofpetroleum naphtha fractions. | [Uses]
Illuminant, oxyacetylene welding, cutting, and soldering metals, signalling; pptg metals, particularly Cu; manufacture of acetaldehyde, acetic acid; fuel for motor boats. | [Definition]
A
gaseous alkyne. Traditionally ethyne has
found use in oxy-acetylene welding
torches, since its combustion with oxygen
produces a flame of very high temperature.
It is also important in the organic chemicals
industry for the production of
chloroethene (vinyl chloride), which is the
starting material for the production of
polyvinyl chloride (PVC), and for the production
of other vinyl compounds. Until
recently, ethyne was manufactured by the
synthesis and subsequent hydrolysis of calcium
dicarbide, a very expensive procedure.
Modern methods increasingly
employ the cracking of alkanes. | [Production Methods]
Commercially, acetylene is produced from the pyrolysis of naphtha in a two-stage cracking process. Both acetylene and ethylene are end products. The ratio of the two products can be changed by varying the naphtha feed rate. Acetylene also has been produced by a submerged-flame process from crude oil. In essence, gasification of the crude oil occurs by means of the flame, which is supported by oxygen beneath the surface of the oil. Combustion and cracking of the oil take place at the boundaries of the flame. The composition of the cracked gas includes about 6.3% acetylene and 6.7% ethylene. Thus, further separation and purification are required. Several years ago when procedures were developed for the safe handling of acetylene on a large scale, J. W. Reppe worked out a series of reactions that later became known as “Reppe chemistry.” These reactions were particularly important to the manufacture of many high polymers and other synthetic products. Reppe and his associates were able to effect synthesis of chemicals that had been commercially unavailable. An example is the synthesis of cyclooctatetraene by heating a solution of acetylene under pressure in tetrahydrofuran in the presence of a nickel cyanide catalyst. In another reaction, acrylic acid was produced from CO and H2O in the presence of a nickel catalyst: C2H2 + CO + H2O → CH2:CH·COOH. These two reactions are representative of a much larger number of reactions, both those that are straight-chain only, and those involving ring closure. | [Production Methods]
The traditional method of producing acetylene is from reacting lime, calcium oxide (CaO), with coke to produce calcium carbide (CaC2). The calcium carbide is then combined with water to produce acetylene:
2CaO(s) + 5C(s)→2CaC2(g) + CO2(g)
CaC2(s) + 2H2O(l)→ C2H2(g) + Ca(OH)2(aq)
Several processes for producing acetylene from natural gas and other petroleum products developed in the 1920s. Thermal cracking of methane involves heating methane to approximately 600℃ in an environment deficient in oxygen to prevent combustion of all the methane. Combustion of part of the methane mix increases the temperature to approximately 1,500℃, causing the remaining methane to crack according the reaction: 2CH4(g) → C2H2(g) + 3H2(g). In addition to methane, ethane, propane, ethylene, and other hydrocarbons can be used as feed gases to produce acetylene. | [Reactions]
Acetylene reacts (1) with chlorine, to form acetylene tetrachloride C2H2Cl4 or CHCl2·CHCl2 or acetylene dichloride C2H2Cl2 or CHCl:CHCl, (2) with bromine, to form acetylene tetrabromide C2H2Br4 or CHBr2·CHBr2 or acetylene dibromide C2H2Br2 or CHBr:CHBr, (3) with hydrogen chloride (bromide, iodide), to form ethylene monochloride CH2:CHCl (monobromide, monoiodide), and 1,1-dichloroethane, ethylidene chloride CH3·CHCl2 (dibromide, diiodide), (4) with H2O in the presence of a catalyzer, e.g., mercuric sulfate HgO4S, to form acetaldehyde CH3·CHO, (5) with hydrogen, in the presence of a catalyzer, e.g., finely divided nickel heated, to form ethylene C2H4 or ethane C2H6, (6) with metals, such as copper or nickel, when moist, also lead or zinc, when moist and unpurified. Tin is not attacked. Sodium yields, upon heating, the compounds C2HNa and C2Na2. (7) With ammoniocuprous (or silver) salt solution, to form cuprous (or silver) acetylide C2Cu2, dark red precipitate, explosive when dry, and yielding acetylene upon treatment with acid, (8) with mercuric chloride solution, to form trichloromercuric acetaldehyde C(HgCl)3·CHO, precipitate, which yields with HCl acetaldehyde plus mercuric chloride. | [Hazard]
The LEL of acetylene is reached well before asphyxiation can occur, and the danger of explosion is reached before any other health hazard is present. When fighting fires involving acetylene containers, the fire should be extinguished before closing the valve to the container. This is because the acetylene has such a wide flammable range that it can burn inside the container. Acetylene is incompatible with bromine, chlorine, fluorine, copper, silver, mercury, and their compounds. Acetylene has a four-digit UN identification number of 1001. The NFPA 704 designation is health 1, flammability 4, and reactivity 3. Reactivity is reduced to 2 when the acetylene is dissolved in acetone. | [Flammability and Explosibility]
Acetylene is a highly flammable gas and forms explosive mixtures with air over an
unusually wide range of concentrations (2 to 80%). Acetylene can polymerize
exothermically, leading to deflagration. With a very high positive free energy of
formation, acetylene is thermodynamically unstable and is sensitive to shock and
pressure. Its stability is enhanced by the presence of small amounts of other
compounds such as methane, and acetylene in cylinders is relatively safe to handle
because it is dissolved in acetone. Acetylene fires can be fought with carbon dioxide,
dry chemical, and halon extinguishers; firefighting is greatly facilitated by shutting
off the gas supply. | [Industrial uses]
Acetylene is a colorless, flammable gas with a garlic-like odor. Under compressed conditions, it is highly explosive; however, it can be safely compressed and stored in high-pressure cylinders if the cylinders are lined with absorbent material soaked with acetone. Users are cautioned not to discharge acetylene at pressures exceeding 15 psig (103 kPa), as noted by the red line on acetylene pressure gauges.
With its intense heat and controllability, the oxyacetylene flame can be used for many different welding and cutting operations including hardfacing, brazing, beveling, gouging, and scarfing. The heating capability of acetylene also can be utilized in the bending, straightening, forming, hardening, softening, and strengthening of metals. | [Purification Methods]
If very impure, acetylene should be purified by successive passage through spiral wash bottles containing, in this order, saturated aqueous NaHSO4, H2O, 0.2M iodine in aqueous KI (two bottles), sodium thiosulfate solution (two bottles), alkaline sodium hydrosulfite with sodium anthraquinone-2-sulfonate as indicator (two bottles), and 10% aqueous KOH solution (two bottles). The gas is then passed through a Dry-Ice trap and two drying tubes, the first containing CaCl2, and the second, Dehydrite [Mg(ClO4)2] [Conn et al. J Am Chem Soc 61 1868 1939]. Acetone vapour can be removed from acetylene by passage through H2O, then conc H2SO4, or by passage through two gas traps at -65o and -80o, conc H2SO4 and a soda lime tower, a tower of 1-mesh Al2O3 then through H2SO4 [Reichert & Nieuwland Org Synth Coll Vol I 229 1941, Wiley Org Synth Coll Vol III 853 1955, Jones & Whiting Org Synth Coll Vol IV 793 1963]. Sometimes it contains acetone and air. These can be removed by a series of bulb-to-bulb distillations, e.g. a train consisting of a conc H2SO4 trap and a cold EtOH trap (-73o), or passage through H2O and H2SO4, then over KOH and CaCl2. [See Brandsma Preparative Acetylenic Chemistry, 1st Edn Elsevier 1971 p15, for pK, ISBN 0444409475, 2nd Edn Elsevier 1988, ISBN 0444429603, and below for sodium acetylide.] It is also available commercially as 10ppm in helium, and several concentrations in N2 for instrument calibration. [Beilstein 1 IV 939.] Sodium acetylide [1066-26-8] M 48.0, is prepared by dissolving Na (23g) in liquid NH3 (1L) and bubbling acetylene until the blue color is discharged (ca 30minutes) and evaporated to dryness [Saunders Org Synth Coll Vol III 416 1955], and is available commercially as a suspension in xylene/light mineral oil. [See entry in “Metal-organic Compounds”, Chapter 5.] | [Toxicity evaluation]
Acetylene is released to the environment through various
industrial waste streams of industries. Because of the vapor
pressure of acetylene (4.04×104mmHg at 25°C), it exists
in the environment exclusively in the form of gas. The
gaseous phase of acetylene is degraded in the environment
with photochemically induced hydroxyl radicals; the halflife
for this photochemical degradation is approximately
20 days. The estimated Koc of acetylene is 38, and based
upon this Koc value, acetylene is expected to possess high mobility if released to soil. Based on the Henry’s law
constant of 0.022 atm-m3mol-1, derived from vapor pressure
4.04×104mmHg and water solubility 1200 mg l1,
volatilization from moist soil is the major fate process for
acetylene. In soil, biodegradation is not expected to be an
important fate process for acetylene, as suggested by 0%
biochemical oxygen demand (BOD) in 28 days. Acetylene is
not anticipated to be adsorbed by suspended solids and
sediments if released to water because of its Koc value.
Removal of acetylene from water is expected to be through
the volatilization process. The estimated bioconcentration
factor (BCF) of 3 for acetylene suggests that the potential
for bioaccumulation of acetylene in aquatic organism
is low. |
| Safety Data | Back Directory | [Hazard Codes ]
F+ | [Risk Statements ]
R5:Heating may cause an explosion.
R6:Explosive with or without contact with air.
R12:Extremely Flammable. | [Safety Statements ]
S9:Keep container in a well-ventilated place .
S16:Keep away from sources of ignition-No smoking .
S33:Take precautionary measures against static discharges . | [RIDADR ]
UN 1001 | [Autoignition Temperature]
305 °C | [HazardClass ]
2.1 | [storage]
Acetylene should be kept stored in a cool, dry place in a tightly sealed container, and
should only be used in a well-ventilated area. Cylinders should be separated from
oxygen and other oxidizers by a minimum of 20 ft or by a barrier of non-combustible material at least 5 ft high, having a fi re resistance rating of at least 30 min. Storage in
excess of 2500 cu ft is prohibited in buildings with other occupancies. Cylinders should
be stored upright with a valve protection cap in place and fi rmly secured to prevent
falling or being knocked over. The cylinders should be protected from physical damage
and avoid dragging, rolling, sliding, or dropping the cylinder. During transport, workers
should use a suitable hand truck for cylinder movement. Care should be taken to
label “No Smoking” or “Open Flames” signs in the storage or use areas. There should
be no sources of ignition. All electrical equipment should be explosion-proof in the storage
and use areas. | [Safety Profile]
Mtldly toxic by inhalation. Human systemic effects by inhalation: headache and dyspnea. Narcotic in high concentration. In general industrial practice, acetylene does not constitute a serious toxic hazard. It is a very dangerous fire hazard when exposed to heat, flame, or oxidizers. Moderate explosion hazard when exposed to heat or flame or by spontaneous chemical reaction. At high pressures and moderate temperatures, and in the absence of air, acetylene has been known to decompose explosively. Reacts with copper to form the explosive copper acetylide. Incompatible with brass, copper salts, copper carbide, powdered Co, Hg, Hg salts, K, Ag and Ag salts, RbH, CsH, halogens, HNO3, NaH, oxidants. Acetylene + halide + UV can explode. Molten Kignites in C2H2 and then explodes. C2H2 reacts vigorously with trifluoromethyl hypo fluorite. With O2, C2H2 can detonate very powerfully. See ACETYLIDES. When ignited, it burns with an intensely hot flame; can react vigorously with oxidizing materials. When mixed with O2 in proportions of 40% or more, acetylene acts as a narcotic and has been used in anesthesia. Acetylene O2 in the air to a level that wd not support life. However, the presence of impurities in commercial acetylene may result in the production of symptoms before an asphyxiant concentration is reached. Thus: 10% in air produces a slight intoxication, 20% produces a staggering gait, 30% produces general incoordination, 33% leads to unconsciousness in 7 minutes, up to 80% produces complete anesthesia, increased blood pressure, narcosis, and stimulated respiration.
symptoms, and (in hgh concentration) semi-asphyxia and brief loss of consciousness have all been reported. See ARGON for a dmussion of simple asphyxiants. To fight fire, use CO2, water spray, or dry chemical. Stop flow of gas | [Hazardous Substances Data]
74-86-2(Hazardous Substances Data) | [Toxicity]
LC in rats: 900000 ppm (Riggs) |
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