Identification | More | [Name]
2-Hydroxy-1-naphthaldehyde | [CAS]
708-06-5 | [Synonyms]
2-HYDROXY-1-NAPHTHALDEHYDE 2-hydroxy-1-naphthalenecarboxaldehyde 2-HYDROXY-NAPHTHALDEHYDE 2-NAPHTHOL-1-ALDEHYDE AKOS 90775 AKOS BBS-00003198 LABOTEST-BB LT00942158 TIMTEC-BB SBB003835 1-formyl-2-hydroxynaphthalene 1-Formyl-2-hydroxy-naphthalene 1-Formyl-2-naphthol 1-Hydroxy-2-naphthalenecarboxaldehyde 1-Naphthaldehyde, 2-hydroxy- 2-Hydroxy-1-naphthalaldehyde 2-hydroxy-1-naphthaldehyd 2-Hydroxy-1-naphthalenealdehyde 2-hydroxy-1-naphthalenecarboxaldehyd 2-Hydroxy-1-naphthylaldehyde 2-Hydroxy-1-napthaldehyde 2-Hydroxy-alpha-naphthaldehyde | [EINECS(EC#)]
211-902-0 | [Molecular Formula]
C11H8O2 | [MDL Number]
MFCD00004005 | [Molecular Weight]
172.18 | [MOL File]
708-06-5.mol |
Chemical Properties | Back Directory | [Appearance]
Powder | [Melting point ]
76-80 °C (lit.) | [Boiling point ]
192 °C/27 mmHg (lit.) | [density ]
1.1153 (rough estimate) | [vapor pressure ]
0.002Pa at 20℃ | [refractive index ]
1.5500 (estimate) | [Fp ]
191-193°C/27mm | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Chloroform, Methanol | [form ]
Crystalline Moist Powder | [pka]
8.27±0.50(Predicted) | [color ]
Yellow | [Water Solubility ]
Soluble in water (40 g/L at 20°C). | [Sensitive ]
Air Sensitive | [BRN ]
742777 | [LogP]
6 at 23℃ and pH8 | [CAS DataBase Reference]
708-06-5(CAS DataBase Reference) | [NIST Chemistry Reference]
1-Naphthalenecarboxaldehyde, 2-hydroxy-(708-06-5) | [EPA Substance Registry System]
708-06-5(EPA Substance) |
Safety Data | Back Directory | [Hazard Codes ]
Xi,N | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . S60:This material and/or its container must be disposed of as hazardous waste . S61:Avoid release to the environment. Refer to special instructions safety data sheet . S24/25:Avoid contact with skin and eyes . S37:Wear suitable gloves . | [RIDADR ]
UN 3077 9/PG 3
| [WGK Germany ]
2
| [RTECS ]
QJ0300000
| [TSCA ]
Yes | [HazardClass ]
9 | [HS Code ]
29124990 |
Hazard Information | Back Directory | [Chemical Properties]
Powder | [Uses]
2-Hydroxy-1-naphthaldehyde is used in Merrified-type synthesis to deterime free amino acid groups in polymers. | [Definition]
ChEBI: 2-hydroxy-1-naphthaldehyde is a member of the class of naphthaldehydes that is naphthalene-1-carbaldehyde substituted by a hydroxy group at position 2. Active core of sirtinol (CHEBI:73158). It is a member of naphthaldehydes and a member of naphthols. | [Purification Methods]
Crystallise the aldehyde from EtOH (1.5mL/g), aqueous EtOH, aqueous AcOH (m 84o), EtOAc or H2O. [Russell & Lockhart Org Synth Coll Vol III 463 1955, Beilstein 8 H 143, 8 I 564, 8 II 171, 8 III 1108, 8 IV 1160.] |
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