| Identification | More | [Name]
4-Bromomethyl-3-nitrobenzoic acid | [CAS]
55715-03-2 | [Synonyms]
3-NITRO-4-BROMOMETHYLBENZOIC ACID
4-(BROMOETHYL)-3-NITROBENZOIC ACID
4-(BROMOMETHYL)-3-NITROBENZOIC ACID
4-CARBOXY-2-NITROBENZYLBROMID
TIMTEC-BB SBB003091
4-(BROMOMETHYL)-3-NITROBENZOIC ACID 97% | [EINECS(EC#)]
205-516-1 | [Molecular Formula]
C8H6BrNO4 | [MDL Number]
MFCD00216575 | [Molecular Weight]
260.04 | [MOL File]
55715-03-2.mol |
| Chemical Properties | Back Directory | [Appearance]
pale yellow to pink crystalline powder | [Melting point ]
127-130 °C (lit.) | [Boiling point ]
392°C | [density ]
1.814 | [refractive index ]
1.6500 (estimate) | [Fp ]
191°C | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
DMF: soluble(lit.) | [form ]
solid | [pka]
3.42±0.10(Predicted) | [Water Solubility ]
Soluble in DMF and dichloromethane. Insoluble in water. | [BRN ]
1970939 | [CAS DataBase Reference]
55715-03-2(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S25:Avoid contact with eyes . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
19 | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29163990 |
| Hazard Information | Back Directory | [Chemical Properties]
pale yellow to pink crystalline powder | [Uses]
4-Bromomethyl-3-nitrobenzoic acid is used as a reactant in the synthesis of 4-bromomethyl-3-nitrobenzoic acid succinimide ester, 4-((2-(hydroxymethyl)phenyl amino)methyl)-3-nitrobenzoic acid, 4-(2-hydroxyethylmercaptylmethyl)-3-nitrobenzoic acid. It is also used as a thiol photo-deprotection reagent, a starting material in the synthesis of 2H-indazole based library using parallel solution-phase methods. | [Uses]
Photolabile Nbb handle employed in solid-phase peptide synthesis: | [General Description]
4-Bromomethyl-3-nitrobenzoic acid (BNBA) is a benzoic acid derivative. It has been synthesized by the nitration of 4-bromomethylbenzoic acid using fuming nitric acid. It participates in the synthesis of 3,4-dihydro-2(1H)-quinazolinones and 3,4-dihydro-1H-quinazolin-2-thiones. |
|
|