| Identification | More | [Name]
2-Nitrobenzyl bromide | [CAS]
3958-60-9 | [Synonyms]
2-(BROMOMETHYL)NITROBENZENE
2-NITROBENZYL BROMIDE
A-BROMO-O-NITROTOLUENE
ALPHA-BROMO-2-NITROTOLUENE
ALPHA-BROMO-O-NITROTOLUENE
NITROBENZYL-2 BROMIDE
O-NITROBENZYL BROMIDE
1-(Bromomethyl)-2-nitrobenzene
1-Bromomethyl-2-nitro-benzene
Benzene, 1-(bromomethyl)-2-nitro-
-Bromo-2-mitrotoluene
o-Nitrobenaylbromide
α-Bromo-2-nitrotoluene
a-Bromo-2-nitrotoluene
2-Nitrobenzyl bromide, 98+%
2-Nitrobenzyl
à-bromo-2-nitrotoluene
2-Benzyl bromide
1-Nitro-2-(bromomethyl)benzene | [EINECS(EC#)]
223-558-9 | [Molecular Formula]
C7H6BrNO2 | [MDL Number]
MFCD00007184 | [Molecular Weight]
216.03 | [MOL File]
3958-60-9.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
44-46 °C (lit.) | [Boiling point ]
265.51°C (rough estimate) | [density ]
1.6841 (rough estimate) | [refractive index ]
1.6120 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
2-8°C
| [solubility ]
Chloroform (Slightly), DMSO (Slightly), Ethyl Acetate (Slightly) | [form ]
Crystals or Crystalline Powder | [color ]
Yellow to light brown | [Water Solubility ]
insoluble | [Detection Methods]
GC | [BRN ]
638991 | [CAS DataBase Reference]
3958-60-9(CAS DataBase Reference) | [NIST Chemistry Reference]
2-Nitrobenzyl bromide(3958-60-9) | [Storage Precautions]
Moisture sensitive |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
4.8-19-21 | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29049085 |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
2-Nitrobenzyl bromide is used in the preparation of S-2-nitrobenzyl-cysteine by reaction with L-cysteine. It is also used for the introduction of the 2-nitrobenzyl protecting group in organic synthesis. It plays an important role in the production of expectorant agent. Further, it is employed for caging unprotected cysteine-containing or thiophosphorylated peptides in aqueous solution. In addition to this, it is used in the preparation of (R)- and (S)-3-amino-3,4-dihydro-1H-quinolin-2-one. | [Biochem/physiol Actions]
2-Nitrobenzyl bromide reacts with L-cysteine to form S-2-nitrobenzyl-cysteine which was used for modification of ultra-low-gelling-temperature (ULGT) agarose. |
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