Identification | Back Directory | [Name]
(R)-DIFLUORPHOS(TM) | [CAS]
503538-70-3 | [Synonyms]
(S)-DIFLUORPHOS(TM) (R)-DIFLUORPHOS(TM) R-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-2,2,2',2'-TETRAFLUORO-4,4'-BI-1,3-BENZODIOXOLE S-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-2,2,2',2'-TETRAFLUORO-4,4'-BI-1,3-BENZODIOXOLE S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct, min. 97% S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloroMethane adduct (S)-DIFLUORPHOS S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole,dichloromethaneadduct,min.97%(S)-DIFLUORPHOS S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct, min. 97% (S)-DIFLUORPHOS(TM) | [Molecular Formula]
C38H24F4O4P2 | [MDL Number]
MFCD05861607 | [MOL File]
503538-70-3.mol | [Molecular Weight]
682.54 |
Questions And Answer | Back Directory | [Reaction]
- Ligand used for the enantioselective hydrogenation of olefins, and especially electron-poor ketones.
- Ligand used for the enantioselective α-arylation of ketones.
- Ligand used for enantioselective alkylative aldol reactions.
- Nickel-catalyzed asymmetric α-heteroarylation of ketones with chloroarenes.
- Palladium-catalyzed asymmetric intramolecular arylation of α-keto amides.
|
Hazard Information | Back Directory | [Uses]
(S)-DIFLUORPHOS is an electron-poor diphosphane, and can also be used as a chiral supporting ligand.Also, used in preparation of chiral Amino Acid Esters and deuterated Amino Acid Esters. |
|
Company Name: |
Energy Chemical
|
Tel: |
021-021-58432009 400-005-6266 |
Website: |
http://www.energy-chemical.com |
|