| Identification | More | [Name]
Fluorobenzene | [CAS]
462-06-6 | [Synonyms]
AKOS BBS-00004456
FLUOROBENZENE
benzene,fluoro-
fluoro-benzen
Fluorobenzenes
Fluorylfluoride
Monofluorobenzene
Phenyl fluoride
Phenylfluoride
FLUOROBENZENE 1X1 ML METHANOL 1000 UG/ML
FLUOROBENZENE, 1 GRAM, NEAT
FLUOROBENZENE, 1X1ML, MEOH, 2000UG/ML
FluorobenzeneForSynthesis
Fluorobenzene99.9%
Fluorobenzene,99%
Fluorobenzene-13C6
Fluorobenzene,min.97%
48943
fluorobenzene solution
Fluorbenzol | [EINECS(EC#)]
207-321-7 | [Molecular Formula]
C6H5F | [MDL Number]
MFCD00000280 | [Molecular Weight]
96.1 | [MOL File]
462-06-6.mol |
| Chemical Properties | Back Directory | [Description]
Fluorobenzene is a colourless, highly flammable liquid, stable and incompatible with oxidising
agents. It is not compatible with oxidising agents such as perchlorates, peroxides,
permanganates, chlorates, nitrates, chlorine, bromine and fluorine, ammonium nitrate,
chromic acid, halogens, and nitric acid. It is used as an insecticide and as a reagent for
plastic and resin polymers. | [Appearance]
Fluorobenzene is a colorless liquid. | [Melting point ]
-42 °C | [Boiling point ]
85 °C(lit.)
| [density ]
1.024 g/mL at 25 °C(lit.)
| [vapor density ]
3.31 (vs air)
| [vapor pressure ]
81hPa at 20℃ | [refractive index ]
n20/D 1.465(lit.)
| [Fp ]
9 °F
| [storage temp. ]
0-6°C
| [solubility ]
1.54g/l | [form ]
Liquid | [color ]
Clear colorless | [Specific Gravity]
1.024 | [Relative polarity]
3.3 | [Stability:]
Stable. Incompatible with oxidizing agents. Highly flammable-note low flash point. | [explosive limit]
1.3-8.9%(V) | [Water Solubility ]
INSOLUBLE | [Merck ]
14,4170 | [BRN ]
1236623 | [Dielectric constant]
4.7（60℃） | [InChIKey]
PYLWMHQQBFSUBP-UHFFFAOYSA-N | [LogP]
2.27 at 25℃ | [Uses]
Insecticide and larvicide intermediate, identification reagent for plastic or resin polymers. | [CAS DataBase Reference]
462-06-6(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzene, fluoro-(462-06-6) | [EPA Substance Registry System]
462-06-6(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xi,T | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R11:Highly Flammable.
R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R36:Irritating to the eyes. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S7:Keep container tightly closed .
S33:Take precautionary measures against static discharges .
S29:Do not empty into drains .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S7/9:Keep container tightly closed and in a well-ventilated place . | [RIDADR ]
UN 2387 3/PG 2
| [WGK Germany ]
2
| [RTECS ]
DA0800000
| [Hazard Note ]
Flammable | [TSCA ]
T | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29039900 | [Safety Profile]
: Mddly toxic by
ingestion and inhalation. A very dangerous
fire hazard when exposed to heat, flame, or
oxidizers. To fight fire, use water spray,
mist, foam, dry chemical, CO2. When heated
to decomposition it emits toxic fumes of F- |
| Hazard Information | Back Directory | [General Description]
A clear, colorless liquid with a characteristic aromatic odor. About the same density as water. Flash point 5°F. Vapors heavier than air. May irritate the skin, eyes, and mucous membranes. Used as an insecticide, larvacide and as a reagent for plastic or resin polymers. | [Reactivity Profile]
Incompatible with strong oxidizing agents. | [Air & Water Reactions]
Highly flammable. Slightly soluble in water. | [Hazard]
Flammable, dangerous fire risk. Irritant. | [Health Hazard]
Irritating to skin, eyes and mucous membranes. Repeated exposure of skin may cause dermatitis due to defatting action. Chronic inhalation of vapors or mist may result to damage to lungs, liver and kidneys. Acute vapor exposures can cause symptoms ranging from coughing to transient anesthesia and central nervous system depression. | [Potential Exposure]
Fluorobenzene is used as an insecti cide and as a reagent for plastic or resin polymers. | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. If this chemical contacts the
skin, remove contaminated clothing and wash immediately
with soap and water. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions, includ ing resuscitation mask) if breathing has stopped and CPR if
heart action has stopped. Transfer promptly to a medical
facility. When this chemical has been swallowed, get medi cal attention. Give large quantities of water and induce
vomiting. Do not make an unconscious person vomit. | [Shipping]
UN2387 Fluorobenzene, Hazard Class: 3;
Labels: 3-Flammable liquid. | [Incompatibilities]
Vapor may form explosive mixture with
air. Incompatible with oxidizers (chlorates, nitrates, perox ides, permanganates, perchlorates, chlorine, bromine, fluo rine, etc.); contact may cause fires or explosions. Keep
away from alkaline materials, strong bases, strong acids,
oxoacids, epoxides. | [Chemical Properties]
colourless liquid | [Chemical Properties]
Fluorobenzene is a colorless liquid. | [Definition]
ChEBI: The simplest member of the class of monofluorobenzenes that is benzene carrying a single fluoro substituent. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 106, p. 452, 1984 DOI: 10.1021/ja00314a050
The Journal of Organic Chemistry, 30, p. 3170, 1965 DOI: 10.1021/jo01020a073 | [Flammability and Explosibility]
Highlyflammable | [storage]
Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Fluorobenzene must be stored to avoid contact with oxidizers since violent reactions occur. Store in tightly closedcontainers in a cool, well-ventilated area. Sources of ignition, such as smoking and open flames, are prohibitedwhere fluorobenzene is handled, used, or stored. Metal containers involving the transfer of=gallons or more of fluorobenzene should be grounded and bonded. Drums must beequipped with self-closing valves, pressure vacuum bungs,and flame arresters. Use only nonsparking tools and equipment, especially when opening and closing containers offluorobenzene. | [Purification Methods]
Dry fluorobenzene for several days with P2O5, then fractionally distil it. [Beilstein 5 H 198, 5 IV 632.] |
|
|