Identification | More | [Name]
4-Vinyl-1,3-dioxolan-2-one | [CAS]
4427-96-7 | [Synonyms]
4-Ethenyl-1,3-dioxolan-2-one 4-VINYL-1 3-DIOXOLAN-2-ONE 99 Vinyl ethylene carbonate (4-ethenyl-1,3-dioxolan-2-one) 4-VINYL-1,3-DIOXOLAN-2-ONE 99% 4-Vinyl-1,3-dioxolan-2-one Vinyl Ethylene Carbonate | [Molecular Formula]
C5H6O3 | [MDL Number]
MFCD00143315 | [Molecular Weight]
114.1 | [MOL File]
4427-96-7.mol |
Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
R25:Toxic if swallowed. | [Safety Statements ]
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2810 6.1/PG 3
| [WGK Germany ]
1
| [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29209090 |
Hazard Information | Back Directory | [Chemical Properties]
Colorless liquid | [Uses]
It is used to synthesize functional polymers. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 69, p. 2955, 1947 DOI: 10.1021/ja01204a008 | [General Description]
4-Vinyl-1,3-dioxolan-2-one (VEC) is a cyclic carbonate, that can be synthesized from acrolein by reacting with sulfur ylide and CO2. The ruthenium-catalyzed transfer hydrogenation (TH) of VEC in the presence of 2-propanol forms 1,2-butanediol. Indolines and indoles undergo selective C-H allylation with VEC in the presence of rhodium(III) catalyst. |
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