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ChemicalBook--->CAS DataBase List--->3504-40-3

3504-40-3

3504-40-3 Structure

3504-40-3 Structure
IdentificationMore
[Name]

SAMARIUM(III) ISOPROPOXIDE
[CAS]

3504-40-3
[Synonyms]

SAMARIUM (III) I-PROPOXIDE
SAMARIUM(III) ISOPROPOXIDE
Samarium(III) isopropoxide in ampoules
SAMARIUM I-PROPOXIDE
SAMARIUM ISOPROPOXIDE
SAMARIUM TRI-I-PROPOXIDE
SAMARIUM(III) ISOPROPOXIDE, 99.9%
SAMARIUM (III) I-PROPOXIDE, MIN. 97% (99.9%-SM) (REO)
SAMARIUM (III) ISOPROPOXIDE, 5% W/V IN TOLUENE-ISOPROPANOL,
5%w/vintoluene-isopropanol(REO)
SAMARIUM(III) ISOPROPOXIDE (99.9% SM) (REO)
Samarium tetraisopropoxide
Samarium(III) isopropoxide, 5% w/v in toluene-isopropanol, 99% (REO)
[Molecular Formula]

C9H21O3Sm
[MDL Number]

MFCD00058820
[Molecular Weight]

327.62
[MOL File]

3504-40-3.mol
Chemical PropertiesBack Directory
[Boiling point ]

210-30°C/0.01mmHg
[form ]

Powder
[color ]

cream colored
[Water Solubility ]

Hydrolyzes with water.
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[Sensitive ]

Moisture Sensitive
[Exposure limits]

ACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3)
[CAS DataBase Reference]

3504-40-3(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

F,Xi
[Risk Statements ]

R11:Highly Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S33:Take precautionary measures against static discharges .
[RIDADR ]

UN 1325 4.1/PG 3
[WGK Germany ]

3
[TSCA ]

No
[HazardClass ]

3
[PackingGroup ]

II
Hazard InformationBack Directory
[Uses]

Used with a dinucleating Schiff base ligand in a catalytic asymmetric nitro-Mannich reaction.
[reaction suitability]

core: samarium
reagent type: catalyst
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Samarium(III) isopropoxide, 99% (REO), 5% w/v in toluene/isopropanol(3504-40-3)
[Sigma Aldrich]

3504-40-3(sigmaaldrich)
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